Thermodynamic Behavior of Reactive Azeotropes

AIChE Journal

Volumn 43, Issue 9, 1997, Pages 2227-2238

  Okasinski, Matthew J ^a   Doherty, Michael F ^a  

^a University of Massachusetts   (United States)

Author keywords

[No Author keywords available]

Indexed keywords

ACETIC ACID; BIFURCATION (MATHEMATICS); DISTILLATION; ESTERIFICATION; ETHANOL; PHASE EQUILIBRIA; REACTION KINETICS; THERMODYNAMIC PROPERTIES;

QUATERNARY SADDLE REACTIVE AZEOTROPES; REACTIVE DISTILLATION SYSTEMS;

AZEOTROPES;

EID: 0031232933     PISSN: 00011541     EISSN: None     Source Type: Journal    
DOI: 10.1002/aic.690430909     Document Type: Article

References (26)

1. Albert, M., I. Hahnenstein, H. Hasse, and G. Maurer, "Vapor-Liquid Equilibrium of Formaldehyde Mixtures," AIChE J., 42, 1741 (1996).
2. Barbosa, D., and M. F. Doherty, "Theory of Phase Diagrams and Azeotropic Conditions for Two-Phase Reactive Systems," Proc. Roy. Soc. (London), A413, 443 (1987).
3. Barbosa, D., and M. F. Doherty, "The Influence of Equilibrium Chemical Reactions on Vapor-Liquid Phase Diagrams," Chem. Eng. Sci., 43, 529 (1988a).
4. Barbosa, D., and M. F. Doherty, "The Simple Distillation of Homogeneous Reactive Mixtures," Chem. Eng. Sci., 43, 541 (1988b).
5. Brandani, V., G. Di Giacomo, and P. U. Foscolo, "Isothermal Vapor-Liquid Equilibria for the Water-Formaldehyde System," Ind. Eng. Chem. Proc. Des. Dev., 19, 179 (1980).
6. Columbo, F., L. Cori, L. Dalloro, and P. Delogu, "Equilibrium Constant for the Methyl tert-Butyl Ether Liquid-Phase Synthesis by Use of UNIFAC," Ind. Eng. Chem. Fundam., 22, 219 (1983).
7. Dean, J. A., Lange's Handbook of Chemistry, 12th ed., McGraw-Hill, New York (1979).
8. Doedel, E., AUTO: Software for Continuation and Bifurcation Problems in Ordinary Differential Equations, Dept. of Mathematics, Cal. Inst. of Technol., Pasadena (1986).
9. Espinosa, J., P. Aguirre, and G. Perez, "Product Composition Regions of Single-Feed Reactive Distillation Columns," Ind. Eng. Chem. Res., 34, 853 (1995).
10. Fidkowski, Z. T., M. F. Malone, and M. F. Doherty, "Computing Azeotropes in Multicomponent Mixtures," Comput. Chem. Eng., 17, 1141 (1993).
11. Gmehling, J., and U. Onken, "Vapor-Liquid Equilibrium Data Collection, Aqueous-Organic Systems,"DECHEMA, Chem. Data. Ser., 1(Part 1), 2; (Part 1a), 7; (Part 1b), 10 (1977).
12. Gmehling, J., and U. Onken, "Vapor-Liquid Equilibrium Data Collection, Aqueous-Organic Systems,"DECHEMA, Chem. Data. Ser., 1(Part 1), 2; (Part 1a), 7; (Part 1b), 10 (1977).
13. Gmehling, J., and U. Onken, "Vapor-Liquid Equilibrium Data Collection, Aqueous-Organic Systems,"DECHEMA, Chem. Data. Ser., 1(Part 1), 2; (Part 1a), 7; (Part 1b), 10 (1977).
14. Kang, Y., Y. Y. Lee, and W. K. Lee, "Vapor-Liquid Equilibria with Chemical Reaction Equilibrium - Systems Containing Acetic Acid, Ethyl Alcohol, Water and Ethyl Acetate," J. Chem. Eng. Jpn., 25, 649 (1992).
15. Keller, H. B., "Numerical Solution of Bifurcation and Nonlinear Eigenvalue Problems," Applications of Bifurcation Theory, P. H. Rabinowitz, ed., Academic Press, New York (1977).
16. Lee, L., and M. Kuo, "Phase and Reaction Equilibria of the Acetic Acid-Isopropanol-Isopropyl Acetate-Water System at 760 mm Hg," Fluid Phase Equilibria, 123, 147 (1996).
17. Lin, W. J., J. D. Seader, and T. L. Wayburn, "Computing Multiple Solutions to Systems of Interlinked Separation Columns," AIChE J., 33, 886 (1987).
18. Maurer, G., "Vapor-Liquid Equilibrium of Formaldehyde and Water-Containing Multicomponent Mixtures," AIChE J., 32, 932 (1986).
19. Rehfinger, A., and U. Hoffmann, "Kinetics of Methyl Tertiary Butyl Ether Liquid Phase Synthesis Catalyzed by Ion Exchange Resin," Chem. Eng. Sci., 45, 1605 (1990).
20. Rhim, J. K., S. Y. Bae, and H. T. Lee, "Isothermal Vapor-Liquid Equilibrium Accompanied by Esterification: Ethanol-Formic Acid System," Int. ChemEng., 25, 551 (1985).
21. Seydel, R., Practical Bifurcation and Stability Analysis - From Equilibrium to Chaos, 2nd ed., Springer-Verlag, New York (1994).
22. Smith, J. M., and H. C. Van Ness, Introduction to Chemical Engineering Thermodynamics, 3rd ed., McGraw-Hill, New York (1975).
23. Ung, S., and M. F. Doherty, "Vapor-Liquid Phase Equilibrium in Systems with Multiple Chemical Reactions," Chem. Eng. Sci., 50, 23 (1995a).
24. Ung, S., and M. F. Doherty, "Necessary and Sufficient Conditions for Reactive Azeotropes in Multi-Reaction Mixtures," AIChE J., 41, 2383 (1995b).
25. Venimadhavan, G., G. Buzad, M. F. Doherty, and M. F. Malone, "Effect of Kinetics on Residue Curve Maps for Reactive Distillation," AIChE J., 40, 1814 (1994).
26. Venimadhavan, G., G. Buzad, M. F. Doherty, and M. F. Malone, "Correction," AIChE J., 41, 2613 (1995).