Dynamics of electron transfers between electrodes and monolayers of nanoparticles

Journal of Physical Chemistry B

Volumn 106, Issue 32, 2002, Pages 7751-7757

  Hicks, Jocelyn F ^a   Zamborini, Francis P ^a   Murray, Royce W ^a  

^a University of North Carolina at Chapel Hill   (United States)

Author keywords

[No Author keywords available]

Indexed keywords

NANOPARTICLES;

CYCLIC VOLTAMMETRY; ELECTRIC IMPEDANCE; ELECTRODES; GOLD; INORGANIC ACIDS; MONOLAYERS; NANOSTRUCTURED MATERIALS; SELF ASSEMBLY;

ELECTROCHEMISTRY;

EID: 0037104793     PISSN: 10895647     EISSN: None     Source Type: Journal    
DOI: 10.1021/jp025663c     Document Type: Article

References (50)

1. Templeton, A.C.; Wuelfing, W.P.; Murray, R.W. Acc. Chem. Res. 2000, 33, 27-36.
2. (b) Green, S.J.; Pietron, J.J.; Stokes, J.J.; Hostetler, M.J.; Vu, H.; Wuelfing, W.P.; Murray, R.W. Langmuir 1998, 14, 5612.
3. Ingram, R.S.; Hostetler, M.J.; Pietron, J.J.; Murray, R.W.; Schaaff, T.G.; Khoury, J.; Whetten, R.L.; Bigioni, T.P.; Guthrie, D.K.; First, P.N. J. Am. Chem. Soc. 1997, 119, 9279.
4. Chen, S.; Ingram, R.S.; Hostetler, M.J.; Pietron, J.J.; Murray, R.W.; Schaaff, T.G.; Khoury, J.; Alvarez, M.M.; Whetten, R.L. Science 1998, 280, 2098.
5. Hicks, J.F.; Templeton, A.C.; Chen, S.; Sheran, K.M.; Jasti, R.; Murray, R.W.; Debord, J.; Schaaff, T.G.; Whetten, R.L. Anal. Chem. 1999, 71, 3703.
6. Chen, S.; Murray, R.W. J. Phys. Chem. B 1999, 103, 682.
7. (b) Chen, S.; Murray, R.W. J. Phys. Chem. B 1999, 103, 9996.
8. Chen, S. J. Phys. Chem. 2000, 104, 663.
9. Zamborini, F.P.; Hicks, J.F.; Murray, R.W. J. Am Chem. Soc. 2000, 122, 4515.
10. Hicks, J.F.; Zamborini, F.P.; Osisek, A.J.; Murray, R.W. J. Am. Chem. Soc. 2001, 123, 7048.
11. (b) Riemers, J.R.; Hush, N.S. J. Phys. Chem. 2001, 105, 8979.
12. (a) Wuelfing, W.P.; Green, J.J.; Cliffel, D.E.; Pietron, J.P.; Murray, R.W. J. Am. Chem. Soc. 2000, 122, 11465.
13. (b) Wuelfing, W.P.; Murray, R.W. J. Phys. Chem., in press.
14. (a) Haag, R.; Rampi, M.A.; Holmlin, R.E.; Whitesides, G.M. J. Am. Chem. Soc. 1999, 121, 7895.
15. (b) Holmlin, R.E.; Haag, R.; Chabincy, M.L.; Ismagilov, R.F.; Cohen, A.E.; Terfort, A.; Rampi, M.A.; Whitesides, G.M. J. Am. Chem. Soc. 2001, 123, 5075.
16. (a) Zhou, C.; Deshpande, M.R.; Reed, M.A.; Jones, L.; Tour, J.M. Appl. Phys. Lett. 1997, 71, 611.
17. (b) Reed, M.A.; Zhou, C.; Muller, C.J.; Burgin, T.P.; Tour, J.M. Science 1997, 278, 252.
18. (a) Slowinski, K.; Fong, H.K.Y.; Majda, M.J. Am. Chem. Soc. 1999, 121, 7257.
19. (a) Slowinski, K.; Fong, H.K.Y.; Majda, M.J. Am. Chem. Soc. 1999, 121, 7257.
20. (b) Slowinski, K.; Chamberlain, R.V.; Miller, C.J.; Majda, M. J. Am. Chem. Soc. 1997, 119, 11910.
21. (c) Slowinski, K.; Slowinski, K.; Majda, M. J. Phys. Chem. B 1999, 103, 8544.
22. Chen, J.; Reed, M.A.; Asplund, C.L.; Cassell, A.M.; Myrick, M.L.; Rawlett, A.M.; Tour, J.M.; Van Patten, P.G. Appl. Phys. Lett. 1999, 75, 624.
23. Bigioni, T.P.; Harrell, L.E.; Guthrie, D.K.; Cullen, W.G.; Whetten, R.L.; First, P.N. Eur. Phys. J. 1999, D6, 355.
24. (b) Fan, F.F.; Yang, J.; Dirk, S.M.; Price, D.W.; Kosynkin, D.; Tour, J.M.; Bard, A.J. J. Am. Chem. Soc. 2001, 123, 2454.
25. (a) Chidsey, C.E.D. Science 1991, 251, 919.
26. (b) Smalley, J.F.; Feldberg, S.W.; Chidsey, C.E.D.; Linford, M.R.; Newton, M.D.; Liu, Y.-P. J. Phys. Chem. 1995, 99, 13141.
27. (c) Forster, R.J.; Faulkner, L.R. J. Am. Chem. Soc. 1994, 116, 5455.
28. (a) Finklea, H.O. Electrochemistry of Organized Monolayers of Thiols and Related Molecules on Electrodes. In Electroanalyrical Chemistry; Bard, A.J., Rubinstein, I., Eds.; Marcel Dekker: New York, 1996; pp 109-135, and references therein.
29. (b) Hanshaw, D.D.; Finklea, H.O. J. Am. Chem. Soc. 1992, 114, 3173.
30. (c) Finklea, H.O.; Liu, L.; Ravenscroft, M.S.; Punturi, S. J. Phys. Chem. 1996, 100, 18852.
31. (d) Weber, K.; Creager, S.E. Anal Chem. 1994, 66, 3164.
32. (e) Tender, L.; Carter, M.T.; Murray, R.W. Anal. Chem. 1994, 66, 3171.
33. (f) Nahir, T.M.; Clark, R.A.; Bowden, E.F. Anal. Chem. 1994, 66, 2595.
34. (a) Moses, P.R.; Murray, R.W. J. Am. Chem. Soc. 1976, 98, 7435.
35. (b) Moses, P.R.; Murray, R.W. J. Electroanal. Chem. 1977, 77, 393.
36. (c) Murray, R.W. Acc. Chem. Res. 1980, 13, 135.
37. Brust, M.; Walker, M.; Bethell, D.; Schiffrin, D.J.; Whyman, R. Chem. Commun. 1994, 801.
38. Hostetler, M.J.; Templeton, A.C.; Murray, R.W. Langmuir 1999, 15, 3782.
39. Hostetler, M.J.; Wingate, J.E.; Zhong, C.-J.; Harris, J.E.; Vachet, R.W.; Clark, M.R.; Londono, J.D.; Green, S.J.; Stokes, J.J.; Wignall, G.D.; Glish, G.L.; Porter, M.D.; Evans, N.D.; Murray, R.W. Langmuir 1998, 14, 17.
40. Bard, A.J.; Faulkner, L.R. Electrochemical Methods; Wiley: New York, 2000.
41. The coverage of a monolayer of MPC was determined via quartz crystal microbalance: Cliffel, D.E.; Murray, R.W., unpublished results, UNC-Ch, 2000.
42. Laviron, E. J. Electroanal. Chem. 1979, 101, 19.
43. Values for the graph inset in Figure 2 were extrapolated from a plot generated using data listed in Table 1 of ref 24, which were calculated for α = 0.5.
44. (a) Creager, S.E.; Wooster, T.T. Anal. Chem. 1998, 70, 4257.
45. (b) Brevnov, D.A.; Finklea, H.O. Langmuir2000, 16, 5973.
46. Nahir, T.M.; Bowden, E.F. J. Electroanal. Chem. 1996, 410, 9.
47. Experimental data were simulated using the Z-plot ® for windows program.
48. Zamborini, F.P.; Leopold, M.C.; Hicks, J.F.; Kuleza, P.; Malik, M.A.; Murray, R.W. J. Am. Chem. Soc. 2002, in press.
49. 3 units in the tunneling pathway. The estimate ignores the carboxylate groups and any effects of non trans orientations in the thiolate ligand chains.
50. DeLevie, R.D. J. Electroanal. Chem. 1989, 261, 1.