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Volumn 43, Issue 33, 2002, Pages 5841-5843

Generation of sulfenylnitrenes by N-sulfenylation of triphenyl-λ6-sulfanenitrile

Author keywords

6 sulfanenitrile; Aziridines; Sulfenylation; Sulfenylnitrene; Thiazyl chloride

Indexed keywords

ALKENE DERIVATIVE; AZIRIDINE DERIVATIVE; CHLORIDE; FURAN DERIVATIVE; ISOTHIAZOLE DERIVATIVE; NITRILE; SULFONIUM DERIVATIVE; TRIPHENYL LAMBDA 6 SULFANENITRILE; UNCLASSIFIED DRUG;

EID: 0037068156     PISSN: 00404039     EISSN: None     Source Type: Journal    
DOI: 10.1016/S0040-4039(02)01170-X     Document Type: Article
Times cited : (5)

References (23)
  • 11
    • 0010009017 scopus 로고    scopus 로고
    • The sulfenylation reagent used is 2,4-dinitrobenzenesulfenyl chlorides, which is relatively stable and commercially available
  • 12
    • 0009970536 scopus 로고    scopus 로고
    • 2, -80°C) δ 121.1, 124.7, 125.4, 127.6, 129.6, 131.3, 137.6, 140.4, 143.9, 148.9
  • 13
    • 0009999408 scopus 로고    scopus 로고
    • All aziridines gave satisfactory spectral data (NMR, IR, and MS). The side products were mainly 2,4-dinitrobenzenesulfenamide (5-18% yields) and a complex mixture including some unidentified products
  • 14
    • 0010044159 scopus 로고    scopus 로고
    • The aziridination of trans- and cis-1-phenylpropene (3b and 3c) proceeded stereospecifically to give the corresponding aziridine 4b and 4c, but the yield of the cis-aziridine 4c was very low. On the other hand, the addition of 2,4-dinitrophenylsulfenylnitrene from the oxidation and thermolysis of sulfenamides to cis-1-phenylpropene gave a mixture of cis- and trans-aziridine in the ratio of ca. 3:1 (see Refs. 1c,1e)
  • 16
    • 0010040269 scopus 로고    scopus 로고
    • No azridination products were obtained using alkyl substituted alkenes such as cyclohexene and 1-decene


* 이 정보는 Elsevier사의 SCOPUS DB에서 KISTI가 분석하여 추출한 것입니다.