Alkyne adducts of [W2(OCH2tBu)8]n (M = M): Comparisons of bridging and terminal addition products

Journal of the American Chemical Society

Volumn 124, Issue 49, 2002, Pages 14518-14519

  Chisholm, Malcolm H ^a   Click, Damon R ^a   Gallucci, Judith C ^a   Hadad, Christopher M ^a   Wilson, Paul J ^b  

^a OHIO STATE UNIVERSITY   (United States)

^b University of Bath Claverton Down   (United Kingdom)

Author keywords

[No Author keywords available]

Indexed keywords

ALKYNE DERIVATIVE;

ARTICLE; CHEMICAL BINDING; CRYSTAL STRUCTURE; DISSOCIATION; ISOMER; NUCLEAR MAGNETIC RESONANCE SPECTROSCOPY; SOLID STATE; STEREOCHEMISTRY;

EID: 0037065348     PISSN: 00027863     EISSN: None     Source Type: Journal    
DOI: 10.1021/ja027478i     Document Type: Article

References (16)

1. Hoffmann, D. M.; Hoffmann, R.; Fisel, C. R. J. Am. Chem. Soc. 1982, 104, 3858-3875.
2. Sly, W. G.; J. Am. Chem. Soc. 1959, 81, 18.
3. Burke, M. R.; Takats, J. J. Organomet. Chem. 1986, 302, C25.
4. (a) Calhorda, M. J.; Hoffman, R. Organometallics 1986, 5, 2187.
5. (b) Cotton, F. A.; Feng, X. Inorg. Chem. 1990, 29, 3187-3192.
6. (c) Chisholm, M. H.; Lynn, M. A. J. Organomet. Chem. 1998, 550, 141-150.
7. (a) Casey, C. P.; Carino, R. S.; Hayashi, R. K.; Schladetzky, K. D. J. Am. Chem. Soc. 1996, 118, 1617-1623.
8. (b) Casey, C. P.; Carino, R. S.; Sakaba, H. Organometallics 1997, 16, 419-426.
9. Chisholm, M. H.; Streib, W. E. Tiedtke, D. B.; Wu, De-Dong. Chem. Eur. J. 1998, 4, 1470-1479.
10. Please see Supporting Information for Experimental section.
11. Chisholm, M. H.; Clark, D. L.; Hampden-Smith, M. J.; Hoffman, D. H. Angew. Chem., Int. Ed. Engl. 1989, 28, 432-444.
12. Hoffmann, R. Angew. Chem., Int. Ed. Engl. 1982, 21, 142.
13. Xie, Y.; Schaefer, H. F., III; King, B. R. J. Am. Chem. Soc. 2000, 122, 8746-8761 and references therein.
14. Grevels, F.-W.; Klotzbücher, Schrickel, J.; Schaffner, K. J. Am. Chem. Soc. 1994, 116, 6229-6237.
15. Electronic structure calculations were carried out using [B3LYP(SDD,6-31G*)] basis sets. Please see Supporting Information for references.
16. Crystal Stucture data has been deposited with the Cambridge Crystallographic Data Center, Figure 1: CCDC No. 188146; Figure 2: CCDC No. 187844; and Figure 3: CCDC No. 187843.