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Volumn 124, Issue 49, 2002, Pages 14526-14527

A chlorine isotope effect for enzyme-catalyzed chlorination

Author keywords

[No Author keywords available]

Indexed keywords

CHLORINE DERIVATIVE; ISOTOPE;

EID: 0037065345     PISSN: 00027863     EISSN: None     Source Type: Journal    
DOI: 10.1021/ja0284097     Document Type: Article
Times cited : (56)

References (33)
  • 14
  • 20
    • 0011976723 scopus 로고    scopus 로고
    • note
    • 18
  • 23
    • 0011921392 scopus 로고    scopus 로고
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    • 20
  • 27
    • 0011948655 scopus 로고    scopus 로고
    • note
    • 2 was 1.38 mM. For the nonenzymatic chlorination, 0.4 mM TMB or DMP were treated in 50 mL of 0.12 M citrate phosphate buffer, pH 3 with 3 mL of 0.353 M NaOCl added by syringe pump over a 100-min interval. The total added NaOCl was 20 mM. The solution was stirred overnight before extraction. Each experiment was performed in triplicate. In the CPO-catalyzed reactions, the KCl was the reagent in excess, and in the noncatalyzed reaction, the NaOCl was the reagent in excess. The chlorinated compounds were extracted into pentane and analyzed by GC-MS.
  • 28
    • 0011947576 scopus 로고    scopus 로고
    • note
    • 37Cl of the sample.
  • 30
    • 0011976724 scopus 로고    scopus 로고
    • note
    • - was then analyzed as described in ref 26.


* 이 정보는 Elsevier사의 SCOPUS DB에서 KISTI가 분석하여 추출한 것입니다.