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Volumn 106, Issue 14, 2002, Pages 3538-3542

Direct visualization of the hydrolysis kinetics of titanium(IV) alkoxides on functionalized gold surfaces

Author keywords

[No Author keywords available]

Indexed keywords

HYDROLYSIS KINETICS;

EID: 0037061940     PISSN: 10895647     EISSN: None     Source Type: Journal    
DOI: 10.1021/jp013970x     Document Type: Article
Times cited : (23)

References (50)
  • 7
  • 38
    • 0011245918 scopus 로고    scopus 로고
    • note
    • 3- on DTT-modified gold electrodes is similar to that of a bare gold electrode, indicating that the monolayer is not very compact (figures not shown).
  • 39
    • 0011246360 scopus 로고    scopus 로고
    • note
    • It should be noted that the structure of the DTT monolayer on gold and further coordination of titanium(IV) isopropoxide on the OH-terminated surface (Figure 1) are hypothetical. Further characterization is necessary to confirm the proposed structure. The anchored titanium submonolayer may not be densely packed, as depicted. There is no evidence to exclude the physically adsorbed second or third layer adsorption either. Nevertheless, the uncertainty in the microscopic structure of the system does not interfere with our monitoring and evaluation of the reaction kinetics as described.
  • 40
    • 0011167699 scopus 로고    scopus 로고
    • unpublished result
    • Banks, J.T.; Cappello, M.L.; Hardy, K.A.; MacDairmid, A.R.; Gallagher, M.C. Unpublished results. The presence of DTT on the gold surface was verified by strong peaks at 153 eV (S), 275 eV (C), and 510 eV (O) in the Auger spectrum. After exposure of these SAMs to a dilute solution of TTIP, the peaks for titanium at 390 and 421 eV were evident in the Auger spectrum.
    • Banks, J.T.1    Cappello, M.L.2    Hardy, K.A.3    Macdairmid, A.R.4    Gallagher, M.C.5


* 이 정보는 Elsevier사의 SCOPUS DB에서 KISTI가 분석하여 추출한 것입니다.