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(a) Metal-carbene insertions serve as successful examples of this concept: Taber, D. F.; Stribia, S.-E. Chem.-Eur. J. 1998, 4, 990-992 and references therein.
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(a) Teleocidin structure: Hitotsuyanagi, Y.; Fujiki, H.; Suganuma, M.; Aimi, N.; Sakai, S.; Endo, Y.; Shudo, K.; Sugimura, T. Chem. Pharm. Bull. 1984, 32, 4233-4236 and references therein.
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(b) Previous synthesis: Nakatsuka, S.; Masuda, T.; Goto, T. Tetrahedron Lett. 1986, 27, 6245-6248. Nakatsuka, S.; Masuda, T.; Goto, T. Tetrahedron Lett. 1987, 28, 3671-3674. Okabe, K.; Muratake, H.; Natsume, M. Tetrahedron 1991, 47, 8559-8572 and references therein.
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0023183272
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(b) Previous synthesis: Nakatsuka, S.; Masuda, T.; Goto, T. Tetrahedron Lett. 1986, 27, 6245-6248. Nakatsuka, S.; Masuda, T.; Goto, T. Tetrahedron Lett. 1987, 28, 3671-3674. Okabe, K.; Muratake, H.; Natsume, M. Tetrahedron 1991, 47, 8559-8572 and references therein.
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Nakatsuka, S.1
Masuda, T.2
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13
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0025947033
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and references therein
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(b) Previous synthesis: Nakatsuka, S.; Masuda, T.; Goto, T. Tetrahedron Lett. 1986, 27, 6245-6248. Nakatsuka, S.; Masuda, T.; Goto, T. Tetrahedron Lett. 1987, 28, 3671-3674. Okabe, K.; Muratake, H.; Natsume, M. Tetrahedron 1991, 47, 8559-8572 and references therein.
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(a) Dunina, V. V.; Zalevskaya, O. A.; Potapov, V. M. Russ. Chem. Rev. 1988, 57, 250-269.
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Arylation of the Herrmann palladacycle with phenylstannane has been reported: Louie, J.; Hartwig, J. F. Angew. Chem., Int. Ed. Engl. 1996, 35, 2359-2361.
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note
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The catalytic arylation and alkenylation of tert-butyl aniline have been achieved in our laboratory. Exploration and optimization of this reaction will be the subject of a separate communication.
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Hennings, D. D.; Iwasa, S.; Rawal, V. H. Tetrahedron Lett. 1997, 38, 6379-6382.
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