The pyridyl-tag strategy applied to the hydrocarbon/perfluorocarbon phase-switching of a porphyrin and a fullerene

Journal of the American Chemical Society

Volumn 124, Issue 44, 2002, Pages 12942-12943

  El Bakkari, Mounir ^a   McClenaghan, Nathan ^a   Vincent, Jean Marc ^a  

^a CNRS   (France)

Author keywords

[No Author keywords available]

Indexed keywords

COPPER DERIVATIVE; FLUOROCARBON; FULLERENE; HYDROCARBON; METAL COMPLEX; PORPHYRIN;

ARTICLE; CATALYSIS; PHASE TRANSITION; PURIFICATION; REACTION ANALYSIS; SOLUBILIZATION; SYNTHESIS;

EID: 0037032213     PISSN: 00027863     EISSN: None     Source Type: Journal    
DOI: 10.1021/ja027815n     Document Type: Article

References (28)

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24. UV-vis spectra given in Supporting Information.
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26. By comparison, the releasing of the bipyridyl tag of the copper-carboxylate resin reported by Ley and co-workers requires 8 h of stirring in the presence of a strongly coordinating ligand (N,N,N′,N′-tetramethylethyl-enediamine). This could be attributed to the chelating effect of the bidentate bipyridyl coordination as compared to a monodentate pyridyl coordination in our case. Moreover, the problem of the recovery of the copper- carboxylate resin has not been addressed.
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28. UV-vis spectra given in Supporting Information.