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Volumn 43, Issue 19, 2002, Pages 3455-3457

An allosteric crown ether-induced activity control for the cleavage of a phosphodiester bond

Author keywords

Allosteric control; Crown compounds; Phosphodiester cleavage; Supramolecular chemistry

Indexed keywords

2 HYDROXYPROPYL 4 NITROPHENYLPHOSPHATE; CROWN ETHER; ESTER DERIVATIVE; PHOSPHATE; RNA; THIOUREA; UNCLASSIFIED DRUG;

EID: 0037029915     PISSN: 00404039     EISSN: None     Source Type: Journal    
DOI: 10.1016/S0040-4039(02)00601-9     Document Type: Article
Times cited : (25)

References (28)
  • 18
    • 0008917012 scopus 로고    scopus 로고
    • 1H NMR experiment.
  • 19
    • 0008945967 scopus 로고    scopus 로고
    • -1) values were estimated from initial rates (
  • 20
    • 0008938137 scopus 로고    scopus 로고
    • note
  • 21
    • 0008958629 scopus 로고    scopus 로고
    • The cleavage reaction was too slow to estimate the pseudo-first order rate constants accurately.
  • 22
    • 0008891453 scopus 로고    scopus 로고
    • 10b
  • 23
    • 0008938138 scopus 로고    scopus 로고
    • + (4.5 mM) and 1 (4.5 mM) in MeCN at 25°C.
  • 24
    • 0008886852 scopus 로고    scopus 로고
    • -1.
  • 25
    • 0008954421 scopus 로고    scopus 로고
    • The energy minimization (ESFF force field) with the Quasi Newton-Rapton algorithm was performed using InsightII version 2000/Discover Release 3.0.0 version 98.0 (Accelrys) on a Silcon Graphics COMTEC 4D O2 workstation.
  • 26
    • 0008891454 scopus 로고    scopus 로고
    • 3CN.
  • 27
    • 0008943454 scopus 로고    scopus 로고
    • +]=4.5 mM was 78%. However, at higher concentrations (≥9.0 mM), the estimations were failed because of the solubility of 1.


* 이 정보는 Elsevier사의 SCOPUS DB에서 KISTI가 분석하여 추출한 것입니다.