Catalytic Barbier-type reactions of lactones and esters mediated by the Mischmetall/SmI2(cat.) system or the Mischmetall/[SmI2/NiI2(cat'.)](cat.) system

Tetrahedron Letters

Volumn 43, Issue 45, 2002, Pages 8007-8010

  Lannou, Marie Isabelle ^a   Hélion, Florence ^a   Namy, Jean Louis ^a  

^a CNRS   (France)

Author keywords

Barbier reactions; Catalysis; Lactones; Mischmetall; Nickel diiodide; Samarium diiodide

Indexed keywords

ESTER DERIVATIVE; HALIDE; LACTONE DERIVATIVE; NICKEL COMPLEX; SAMARIUM;

ARTICLE; BARBIER TYPE REACTION; CATALYSIS; CHEMICAL REACTION; PROTON NUCLEAR MAGNETIC RESONANCE; ROOM TEMPERATURE; STOICHIOMETRY;

FELIS CATUS;

EID: 0037020585     PISSN: 00404039     EISSN: None     Source Type: Journal    
DOI: 10.1016/S0040-4039(02)01979-2     Document Type: Article

References (8)

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5. Molander G.A., St Jean D.J. Jr. J. Org. Chem. 67:2002;3861-3865.
6. 4, and the solvents were removed under reduced pressure. The crude material was purified by flash chromatography on silica gel.
7. Machrouhi F., Namy J.L. Tetrahedron. 54:1998;11111-11122.