Heats of K/Ca and K/Pb exchange in two tropical soils as measured by flow calorimetry

Soil Science

Volumn 167, Issue 12, 2002, Pages 773-781

  Appel, Chip ^a   Rhue, Dean ^b   Ma, Lena ^b   Reve, Bill ^b  

^a CALIFORNIA POLYTECHNIC STATE UNIVERSITY   (United States)

^b UNIVERSITY OF FLORIDA   (United States)

Author keywords

Enthalpy; Ion exchange; Surface heterogeneity

Indexed keywords

CALORIMETRY; ENTHALPY; ION EXCHANGE; TROPICAL SOIL;

PUERTO RICO;

EID: 0036915004     PISSN: 0038075X     EISSN: None     Source Type: Journal    
DOI: 10.1097/00010694-200212000-00001     Document Type: Article

References (52)

1. Airoldi, C., and S. A. M. Critter. 1997. Brazilian red Latosol a typic soil as an exchanger: A thermodynamic study involving Cu, Zn, Cd, Hg, Pb, Ca and Na. Clays Clay Miner. 45:125-131.
2. Appel, C., and L. Ma. 2002. Concentration, pH, and surface charge effects on Cd and Pb sorption in three tropical soils. J. Environ. Qual. 31:581-589.
3. Bargar, J. R., G. E. Brown, and G. A. Parks. 1997a. Surface complexation of Pb (II) at oxide-water interfaces: I. XAFS and bond-valence determination of mononuclear and polynuclear Pb (II) sorption products on aluminum oxides. Geochim. Cosmochim. Acta 61:2617-2637.
4. Bargar, J. R., G. E. Brown, and G. A. Parks. 1997b. Surface complexation of Pb (II) at oxide-water interfaces: II. XAFS and bond-valence determination of mononuclear Pb (II) sorption products and surface functional groups on iron oxides. Geochim. Cosmochim. Acta 61:2639-2652.
5. Bargar, J. R., G. E. Brown, and G. A. Parks. 1998. Surface complexation of Pb(II) at oxide-water interfaces: III. XAFS determination of Pb(II) and Pb(II)-chloro complexes on goethite and alumina. Geochim. Cosmochim. Acta 62:193-207.
6. Barrer, R. M., D. J. Ward, and L. V. C. Rees. 1963. Thermochemistry and thermodynamics of ion exchange in a crystalline exchange medium. Proc. R. Soc. London Ser. A-Math. 273:180-197.
7. Braggs, B., D. Fornasiero, J. Ralston, and R. S. Smart. 1994. The effect of surface modification by an organosilane on the electrochemical properties of kaolinite. Clays Clay Miner. 42:123-136.
8. Bruemmer, G. W., J. Gerth, and U. Herms. 1986. Heavy metal species, mobility, and availability in soils. Z. Pflanzenernaegr. Bodenk. 149:382-398.
9. Brown, G. E., A. L. Foster, and J. D. Ostergren. 1999. Mineral surfaces and bioavailability of heavy metals: A molecular-scale perspective. Proc. Natl. Acad. Sci. USA 96:3388-3395.
10. Davis, J. A., and J. O. Leckie. 1978. Surface ionization and complexation at the oxide/water interface. II. Surface properties of amorphous iron oxyhydroxide and adsorption of metals. J. Colloid Interface Sci. 67:90-107.
11. Deist, J., and O. Talibudeen. 1967. Thermodynamics of K-Ca exchange in soils. J. Soil Sci. 18:138-148.
12. Eick, M. J., J. D. Peak, P. V. Brady, and J. D. Pesek. 1999. Kinetics of lead adsorption/desorption on goethite: Residence time effect. Soil Sci. 164:28-39.
13. Elkhatib, E. A., G. M. Elshebiny, G. M. Elsubruiti, and A. M. Balba. 1993. Thermodynamics of lead sorption and desorption in soils. Z. Pflanzenernaegr. Bodenk. 156:461-465.
14. Ferris, A. P., and W. B. Jepson. 1975. The exchange capacities of kaolinite and the preparation of homoionic clays. J. Colloid Interface Sci. 51:245-259.
15. Forbes, E. A., A. M. Posner, and J. P. Quirk. 1976. The specific adsorption of divalent Cd, Co, Cu, Pb, and Zn on goethite. J. Soil Sci. 27:154-166.
16. Gao, S. A., W. J. Walker, R. A. Dahlgren, and J. Bold. 1997. Simultaneous sorption of Cd, Cu, Ni, Zn, Pb, and Cr on soils treated with sewage sludge supernatant. Water Air Soil Pollut. 93:331-345.
17. Gast, R. G. 1972. Alkali metal cation exchange on Chambers montmorillonite. Soil Sci. Soc. Am. Proc. 36:14-19.
18. Gast, R. G., R. V. Bladel, and K. B. Deshpande. 1969. Standard heats and entropies of exchange for alkali metal cations on Wyoming bentonite. Soil Sci. Soc. Am. Proc. 33:661-664.
19. Gong, C. R., and R. J. Donahoe. 1997. An experimental study of heavy metal attenuation and mobility in sandy loam soils. Appl. Geochem. 12:243-254.
20. Goulding, K. 1983. Thermodynamics and potassium exchange in soils and clay minerals. In Advances in Agronomy, vol. 36. N.C. Brady (ed.). Academic Press, New York, pp. 215-264.
21. Goulding, K. W. T., and O. Talibudeen. 1984. Thermodynamics of K-Ca exchange in soils. II. Effects of mineralogy, residual K and pH in soils from long-term ADAS experiments. J. Soil Sci. 35:409-420.
22. Gustafsson, J. P. 2002. Visual Minteq [Online]. Available at http://www.lwr.kth. se/english/OurSoftware/Vminteq/#download (verified 6 Aug. 2002).
23. Huheey, J. E. 1983. Inorganic Chemistry: Principles of Structure and Reactivity, 3rd Ed. Harper and Row, San Francisco, CA.
24. Jenne, E. A. 1968. Controls on Mn, Fe, Co, Ni, Cu, and Zn concentrations in soils and waters - The dominant role of hydrous manganese and iron oxides. Adv. Chem. Ser. 73:337-387.
25. Kinniburgh, D. G., M. L. Jackson, and J. K. Sayers. 1976. Adsorption of alkaline earth, transition and heavy metal cations by hydrous oxide gels of iron and aluminum. Soil Sci. Soc. Am. J. 40:796-799.
26. Laudelot, H., R. V. Bladel, G. H. Bolt, and A. L. Page. 1968. Thermodynamics of heterovalent cation exchange reactions in a montmorillonite clay. Trans. Faraday Soc. 64:1477-1488.
27. Lopez, F. A., C. Perez, E. Sainz, and M. Alonso. 1995. Adsorption of Pb2+ on blast-furnace sludge. J. Chem. Technol. Biotechnol. 62:200-206.
28. Lopez-Delgado, A., C. Perez, and F. A. Lopez. 1998. Sorption of heavy metals on blast furnace sludge. Water Res. 32:989-996.
29. Maes, A., and A. Cremers. 1977. Charge density effects in ion exchange. Part 1. Heterovalent exchange equilibria. J. Chem. Soc. Faraday Trans. 1. 73:1807-1814.
30. McBride, M. B. 1994. Environmental Chemistry in Soils. Oxford University Press, Oxford, UK.
31. Nriagu, J. O. 1998. Paleoenvironmental research - Tales told in lead. Science 281:1622-1623.
32. Ogwada, R. A., and D. L. Sparks. 1986. A critical-evaluation on the use of kinetics for determining thermodynamics of ion-exchange in soils. Soil Sci. Soc. Am. J. 50:300-305.
33. Pardo, M. T. 2000. Sorption of lead, copper, zinc, and cadmium by soils: Effect of nitriloacetic acid on metal retention. Commun. Soil Sci. Plant Anal. 31:31-40.
34. Parida, K., P. K. Satapathy, and N. Das. 1996. Studies on Indian Ocean manganese nodules. 4. Adsorption of some bivalent heavy metal ions onto ferromanganese nodules. J. Colloid Interface Sci. 181:456-462.
35. Phillips, I. R. 1999. Copper, lead, cadmium, and zinc sorption by waterlogged and air-dry soil. J. Soil Contam. 8:343-364.
36. Rhue, R. D., C. Appel, and N. Kabengi. 2002. Measuring surface chemical properties of soil using flow calorimetry. Soil Sci.(in press).
37. Rhue, R. D., and R. S. Mansell. 1988. The effect of pH on sodium-calcium and potassium-calcium exchange selectivity for Cecil soil. Soil Sci. Soc. Am. J. 52:641-647.
38. Rodda, D. P., B. B. Johnson, and J. D. Wells. 1996. Modeling the effect of temperature on adsorption of lead(II) and zinc(II) onto goethite at constant pH. J. Colloid Interface Sci. 184:365-377.
39. 2+) by pedogenic oxides, ferrihydrite, and leaf compost. Soil Sci. Soc. Am. J. 64:595-599.
40. Sauve, S., M. McBride, and W. H. Hendershot. 1998. Soil solution speciation of lead (II): Effects of organic matter and pH. Soil Sci. Soc. Am. J. 62:618-621.
41. Scheinost, A. C., S. Abend, K. I. Pandya, and D. L. Sparks. 2001. Kinetic controls on Cu and Pb sorption by ferrihydrite. Environ. Sci. Technol. 35:1090-1096.
42. Sparks, D. L. 1995. Environmental Soil Chemistry. Academic Press, New York.
43. Sparks, D. L., and P. M. Jardine. 1981. Thermodynamics of potassium exchange in soil using a kinetics approach. Soil Sci. Soc. Am. J. 45:1094-1099.
44. Strawn, D. G., A. M. Scheidegger, and D. L. Sparks. 1998. Kinetics and mechanisms of Pb(II) sorption and desorption at the aluminum oxide water interface. Environ. Sci. Technol. 32:2596-2601.
45. Strawn, D. G., and D. L. Sparks. 1999. The use of XAFS to distinguish between inner- and outer-sphere lead adsorption complexes on montmorillonite. J. Colloid Interface Sci. 216:257-269.
46. Su, C. M., and D. L. Suarez. 1997. In situ infrared speciation of absorbed carbonate on aluminum and iron oxide. Clays Clay Miner. 45:814-825.
47. Udo, E. J. 1978. Thermodynamics of potassium-calcium and magnesium-calcium exchange reactions on kaolinitic soil clay. Soil Sci. Soc. Am. J. 42:556-560.
48. Uehara, G., and G. P. Gillman. 1981. The Mineralogy, Chemistry and Physics of Tropical Soils with Variable Charge Clays. Westview Press, Boulder, CO.
49. U.S. Environmental Protection Agency. USEPA. 1996. Soil Screening Guidance: Technical Background Document. EPA/540/R-95/128. U.S. Govt. Print. Office, Washington, DC.
50. van Olphen, H. 1977. An Introduction to Clay Colloid Chemistry, 2nd Ed. John Wiley & Sons, New York.
51. 2+ binding sites in soil humic substances using X-ray absorption spectroscopy. Geochim. Cosmochim. Acta 61:2211-2221.
52. Zhang, M., A. K. Alva, Y. C. Li, and D. V. Calvert. 1997. Chemical association of Cu, Zn, Mn, and Pb in selected sandy citrus soils. Soil Sci. 162:181-188.