Surface complexation of Pb(II) at oxide-water interfaces: III. XAFS determination of Pb(II) and Pb(II)-chloro adsorption complexes on goethite and alumina

Geochimica et Cosmochimica Acta

Volumn 62, Issue 2, 1998, Pages 193-207

  Bargar, J R ^a,b   Brown Jr , G E ^a,b   Parks, G A ^a  

^a STANFORD UNIVERSITY   (United States)

^b SLAC NATIONAL ACCELERATOR LABORATORY   (United States)

Author keywords

[No Author keywords available]

Indexed keywords

ADSORPTION; ALUMINA; GOETHITE; LEAD;

EID: 0031688854     PISSN: 00167037     EISSN: None     Source Type: Journal    
DOI: 10.1016/S0016-7037(97)00334-7     Document Type: Article

References (38)

1. Baes C. F. and Mesmer R. E. (1976) The Hydrolysis of Cations. Wiley.
2. Balistrieri L. S. and Murray J. W. (1982) The adsorption of copper, lead, zinc, and cadmium on goethite from major ion seawater. Geochim. Cosmochim. Acta 46, 1253-1265.
3. Bargar J. R., Brown G. E., Jr., and Parks G. A. (1997a) Surface complexation of Pb(II) at oxide-water interfaces: I. XAFS and bond-valence determination of mononuclear and polynuclear Pb(II) sorption products on aluminum oxides. Geochim. Cosmochim. Acta 61, 2617-2638.
4. Bargar J. R., Brown G. E., Jr., and Parks G. A. (1997b) Surface complexation of Pb(II) at oxide-water interfaces: II. XAFS and bond-valence determination of mononuclear Pb(II) sorption products and surface functional groups on iron oxides. Geochim. Cosmochim. Acta 61, 2639-2652.
5. 3. J. Coll. Interface Sci. 185, 473-492.
6. Bargar J. R., Towle S. N., Brown G. E., Jr., and Parks G. A. (1996) Outer-sphere lead(II) adsorbed at specific surface sites on single crystal α = alumina. Geochim. Cosmochim. Acta 60, 3541-3548.
7. Barrow N. J., Bowden J. W., Posner A. M., and Quirk J. P. (1981) Describing the adsorption of copper, zinc, and lead on a variable charge mineral surface. Australian J. Soil Res. 19, 309-321.
8. Benjamin M. M. and Leckie J. O. (1981) Conceptual model for metal-ligand-surface interactions during adsorption. Environ. Sci. Technol. 15, 1050-1057.
9. Cheah S.-F., Brown G. E., Jr., and Parks G. A. (1997) XAS study of the effect of substrate type and 2,2′-bipyridine on the sorption of copper(II) on silica and alumina. In Aqueous Chemistry and Geochmistry of Oxides, Oxyhydroxides, and Related Materials ed. J. A. Voigt et al.; pp. 231-236. Mater. Res. Soc. Symp. Proc. 432.
10. 3/water interface. Geochim. Cosmochim. Acta 54, 1897-1909.
11. Davis J. A. and Leckie J. O. (1978) Effect of adsorbed complexing ligands on trace metal uptake by hydrous oxides. Environ. Sci. Technol. 12, 1309-1315.
12. Farges F., Brown G. E., Jr., and Rehr J. J. (1996) Coordination chemistry of Ti(IV) in silicate glasses and melts. I. XAFS study of titanium coordination in oxide model compounds. Geochim. Cosmochim. Acta 60, 3023-3038.
13. George G. N. (1993) EXAFSPAK. Stanford Synchrotron Radiation Laboratory.
14. Ghoneimy H. F., Shafik S. S., Mikhail E. M., and Misak N. Z. (1993) On the sorption of anions by ferric oxide gel. 1. Aqueous medium. Coll. Surf. A 71, 91-97.
15. Gunneriusson L., Lovgren L., and Sjöberg S. (1994) Complexation of Pb(II) at the goethite (α-FeOOH)/water interface: The influence of chloride. Geochim. Cosmochim. Acta 58, 4973-4983.
16. 3. J. Coll. Interface Sci. 55, 281-288.
17. 2O. J. Chem. Phys. 47, 990-993.
18. Manceau A., Charlet L., Boisset M. C., Didier B., and Spadini L. (1992) Sorption and speciation of heavy metals on hydrous iron and manganese oxides. From microscopic to macroscopic. Appli. Clay Sci. 7, 201-203.
19. Mikhail E. M., Ghoneimy H. F., and Misak N. M. (1994) On the sorption of anions by ferric oxide gel. 3. Rate-controlling mechanism and effect of organic solvents in chloride ion exchange. Collo. Surf. A 92, 209-220.
20. 2 determined more precisely by application of the deutron diffraction method. Sov. Phys. Crystallog. 21, 38-40.
21. O'Day P. A., Rehr J. J., Zabinsky S. I., and Brown G. E., Jr. (1994) Extended x-ray absorption fine structure (EXAFS) analysis of disorder and multiple-scattering in complex crystalline solids. J. Amer. Chem. Soc. 116, 2938-2948.
22. Peterson M., Brown G. E., Jr., and Parks G. A. (1996) Direct XAFS evidence for heterogeneous redox reactions at the aqueous chromium/magnetite interface. Coll. Surf. A 107, 77-88.
23. Rehr J. J. and Albers R. C. (1990) Scattering-matrix formulation of curved-wave multiple-scattering calculations of X-ray absorption fine structure. Phys. Rev. B 41, 8139-8149.
24. Rehr J. J., Mustre de Leon J., Zabinsky S. I., and Albers R. C. (1991) Theoretical x-ray absorption fine structure standards. J. Amer. Chem. Soc. 113, 5135-5140.
25. Rehr J. J., Zabinsky S. I., and Albers R. C. (1992) High-order multiple scattering calculations of x-ray absorption fine structure. Phys. Rev. Lett. 69, 3397.
26. Roe A. L., et al. (1991) In-situ X-ray absorption study of lead ion surface complexes at the goethite-water interface. Langmuir 7, 367-373.
27. Rose A. W. and Bianchi-Mosquera G. C. (1993) Adsorption of Cu, Pb, Zn, Co, Ni, and Ag on goethite and hematite: A control on metal mobilization from red beds into stratiform copper deposits. Econ. Geol. 88, 1226-1236.
28. Schindler P. W. (1990) Cobalt adsorption of metal ions and organic ligands: Formation of ternary surface complexes. In Mineral-Water Interface Geochemistry (ed. M. F. Hochella and A. F. White), Vol. 23, pp. 281-307. MSA.
29. Sillén L. G., Martell A. E., and Bjerrum J. (1964) Stability Constants. 1. Metal-Ion Complexes 2nd Ed. London Chem. Soc.
30. Smith R. M. and Martell A. E. (1976) Critical Stability Constants Volume 4: Inorganic Complexes. Okenum Press.
31. 3/water interface. 213th Mg. of Amer. Chem. Soc. Abstr. Div. Geol Chem. 65, ACS.
32. Szymanski J. T. (1979) The crystal structure of tetraaqua-cis-dichloroiron(III) tetrachloroferrate(III) mono-hydrate (ferric chloide 21/2-hydrate). Acta Cryst. B35, 1958-1963.
33. Szytula A. et al. (1968) Neutron diffraction studies of α-FeOOH. Phys. Stat. Sol. 26, 429-434.
34. Teo B. K. (1986) EXAFS: Basic Principles and Data Analysis. Springer-Verlag.
35. Thompson H. A., Brown G. E., Jr., and Parks G. A. (1997) XAFS spectroscopic study of uranyl coordination in solids and aqueous solution. Amer. Mienral. 82, 483-496.
36. Van Geen A., Robertson A. P., and Leckie J. O. (1994) Complexation of carbonate species at the goethite surface: Implications for adsorption of metal ions in natural waters. Geochim. Cosmochim. Acta 58, 2073-2086.
37. Venetopoulos C. C. and Rentzeperis P. J. (1975) The crystal structure of laurionite, Pb(OH)Cl. Z. Kristallogr. 141, 246-259.
38. 2 Organic Substances in SI Units. Nat. Bur. Stand.