Overcharging: The crucial role of excluded volume

Europhysics Letters

Volumn 60, Issue 3, 2002, Pages 383-389

  Messina, R ^a   Gonzalez Tovar E ^b,c,d   Lozada Cassou, M ^b,d   Holm, C ^a  

^a MAX PLANCK INSTITUTE FOR POLYMER RESEARCH   (Germany)

^b DEPARTAMENTO DE QUÍMICA   (Mexico)

^c UNIVERSIDAD AUTÓNOMA DE SAN LUIS POTOSÍ   (Mexico)

^d INSTITUTO MEXICANO DEL PETRÓLEO   (Mexico)

Author keywords

[No Author keywords available]

Indexed keywords

EID: 0036850048     PISSN: 02955075     EISSN: None     Source Type: Journal    
DOI: 10.1209/epl/i2002-00275-y     Document Type: Article

References (40)

1. Van Megen W. and Snook I., J. Chem. Phys., 73 (1980) 4656; TORRIE G.M. and VALLEAU J.P., 73 (1980) 5807.
2. Van Megen W. and Snook I., J. Chem. Phys., 73 (1980) 4656; Torrie G.M. and Valleau J.P., 73 (1980) 5807.
3. Lozada-Cassou M., Saavedra-Barrera R. and Henderson H., J. Chem. Phys., 77 (1982) 5150.
4. Gonzales-Tovar E., Lozada-Cassou M. and Henderson D., J. Chem. Phys., 83 (1985) 361.
5. Galisteo F., De Las Nieves López F.J., Cabrerizo M. and Hidalgo-Alvarez R., Prog. Colloid Polym. Sci., 82 (1990) 313; Elimelech M. and O'melia C.R., Colloids Surf., 44 (1990) 165; Walker H.W. and Grant S.B., Colloids Surf. A, 119 (1996) 229; Götting N., Fritz H., Maier M., Von Stamm J., Schooes T. and Bayer E., Colloid Polym. Sci., 277 (1999) 145.
6. Galisteo F., De Las Nieves LÓPEZ F.J., Cabrerizo M. and Hidalgo-Alvarez R., Prog. Colloid Polym. Sci., 82 (1990) 313; Elimelech M. and O'melia C.R., Colloids Surf., 44 (1990) 165; Walker H.W. and Grant S.B., Colloids Surf. A, 119 (1996) 229; Götting N., Fritz H., Maier M., Von Stamm J., Schooes T. and Bayer E., Colloid Polym. Sci., 277 (1999) 145.
7. Galisteo F., De Las Nieves López F.J., Cabrerizo M. and Hidalgo-Alvarez R., Prog. Colloid Polym. Sci., 82 (1990) 313; Elimelech M. and O'melia C.R., Colloids Surf., 44 (1990) 165; Walker H.W. and Grant S.B., Colloids Surf. A, 119 (1996) 229; Götting N., Fritz H., Maier M., Von Stamm J., Schooes T. and Bayer E., Colloid Polym. Sci., 277 (1999) 145.
8. Galisteo F., De Las Nieves López F.J., Cabrerizo M. and Hidalgo-alvarez R., Prog. Colloid Polym. Sci., 82 (1990) 313; Elimelech M. and O'melia C.R., Colloids Surf., 44 (1990) 165; Walker H.W. and Grant S.B., Colloids Surf. A, 119 (1996) 229; Götting N., Fritz H., Maier M., Von Stamm J., SCHOOES T. and BAYER E., Colloid Polym. Sci., 277 (1999) 145.
9. Tanaka M. and Grosberg A.Y., Eur. Phys. J. E, 7 (2002) 371.
10. Shklovskii B.I., Phys. Rev. Lett., 82 (1999) 3268.
11. Shklovskii B.I., Phys. Rev. E, 60 (1999) 5802.
12. Nguyen T.T., Grosberg A.Y. and Shklovskii B.I., Phys. Rev. Lett., 85 (2000) 1568; J. Chem. Phys., 113 (2000) 1110.
13. Nguyen T.T., Grosberg A.Y. and Shklovskii B.I., Phys. Rev. Lett., 85 (2000) 1568; J. Chem. Phys., 113 (2000) 1110.
14. Lozada-Cassou M., González-Tovar E. and Olivares W., Phys. Rev. E, 60 (1999) R17.
15. Nguyen T.T. and Shklovskii B.I., Phys. Rev. E, 64 (2001) 041407.
16. Messina R., Holm C. and Kremer K., Phys. Rev. Lett., 85 (2000) 872; Europhys. Lett., 51 (2000) 461; Phys. Rev. E, 64 (2001) 021405.
17. Messina R., Holm C. and Kremer K., Phys. Rev. Lett., 85 (2000) 872; Europhys. Lett., 51 (2000) 461; Phys. Rev. E, 64 (2001) 021405.
18. Messina R., Holm C. and Kremer K., Phys. Rev. Lett., 85 (2000) 872; Europhys. Lett., 51 (2000) 461; Phys. Rev. E, 64 (2001) 021405.
19. Messina R., Holm C. and Kremer K., Eur. Phys. J. E, 4 (2001) 363; Messina R., Physica A, 308 (2002) 59.
20. Messina R., Holm C. and Kremer K., Eur. Phys. J. E, 4 (2001) 363; Messina R., Physica A, 308 (2002) 59.
21. Tanaka M. and Grosberg A.Y., J. Chem. Phys., 115 (2001) 567.
22. Greberg H. and Kjellander R., J. Chem. Phys., 108 (1998) 2940.
23. Deserno M., Jiménez-ángeles F., Holm C. and Lozada-Cassou M., J. Phys. Chem. B, 105 (2001) 10983.
24. Lozada-Cassou M. and Jiménez-Ángeles F., arXiv:physics/0105043 v2 (2001).
25. Deserno M., May S. and Holm C., Macromolecules, 33 (2000) 199.
26. This argument holds far enough from the solid-liquid transition as in the present study (i.e. the highest fluid volume fraction f we consider is 0.23). Indeed entropy alone can drive crystallization as in hard-sphere systems.
27. Allahyarov E. and Löwen H., J. Phys. Condens. Matter, 13 (2001) L277; Phys. Rev. E, 63 (2001) 041403.
28. Allahyarov E. and Löwen H., J. Phys. Condens. Matter, 13 (2001) L277; Phys. Rev. E, 63 (2001) 041403.
29. The LJ potential is, rigorously speaking, not a hard-core one, but can be considered in practice as such.
30. Hansen J.-P. and McDonald I., Theory of Simple Liquids (Academic, London) 1990.
31. This feature holds only if the fixed particle (here the colloid) is larger than the fluid particles.
32. Courtemanche D.J. and Van Swol F., Phys. Rev. Lett., 69 (1992) 2078; Götzelmann B., Haase A. and Dietrich S., Phys. Rev. E, 53 (1996) 3456; Kegel W.K., J. Chem. Phys., 115 (2001) 6538.
33. Courtemanche D.J. and Van Swol F., Phys. Rev. Lett., 69 (1992) 2078; Götzelmann B., Haase A. and Dietrich S., Phys. Rev. E, 53 (1996) 3456; Kegel W.K., J. Chem. Phys., 115 (2001) 6538.
34. Courtemanche D.J. and Van Swol F., Phys. Rev. Lett., 69 (1992) 2078; Götzelmann B., Haase A. and Dietrich S., Phys. Rev. E, 53 (1996) 3456; Kegel W.K., J. Chem. Phys., 115 (2001) 6538.
35. cc cannot be smaller than σ.
36. Rouzina I. and Bloomfield V., J. Chem. Phys., 100 (1996) 9977.
37. Allahyarov E., Löwen H., Louis A.A. and Hansen J.P., Europhys. Lett., 57 (2002) 731.
38. Messina R., Image charges in spherical geometry: Application to colloidal systems, e-print:condmat/0204550.
39. Eisenberg H. And Mohan G.R., J. Phys. Chem., 63 (1959) 671; Eisenberg H. and Casassa E.F., J. Polym. Sci., 47 (1960) 29.
40. Eisenberg H. and Mohan G.R., J. Phys. Chem., 63 (1959) 671; Eisenberg H. and Casassa E.F., J. Polym. Sci., 47 (1960) 29.