Solute transport in solvent-resistant nanofiltration membranes for non-aqueous systems: Experimental results and the role of solute-solvent coupling

Journal of Membrane Science

Volumn 208, Issue 1-2, 2002, Pages 343-359

  Bhanushali, D ^a   Kloos, S ^b   Bhattacharyya, D ^a  

^a UNIVERSITY OF KENTUCKY   (United States)

^b Osmonics Inc   (United States)

Author keywords

Convective coupling; Diffusion cell; Hydrophilic; Hydrophobic; Nanofiltration; Non aqueous; Polymer solute interactions; Polymer solvent interactions; Pore model; Reverse osmosis; Solute transport; Spiegler kedem model

Indexed keywords

DRUG PRODUCTS PLANTS; FOOD PRODUCTS PLANTS; HYDROPHILICITY; HYDROPHOBICITY; NANOFILTRATION; REVERSE OSMOSIS;

PERMEATION;

OSMOSIS MEMBRANES;

DYE; HEXANE; METHANOL; POLYAMIDE; POLYMER; SCARLET RED; SOLVENT; TRIACYLGLYCEROL;

COUPLING; MEMBRANE; NANOFILTRATION; SOLUTE TRANSPORT; SOLVENT;

AQUEOUS SOLUTION; ARTICLE; ARTIFICIAL MEMBRANE; CALCULATION; CHEMICAL BINDING; CONFORMATION; DIFFUSION; HYDROPHILICITY; HYDROPHOBICITY; MOLECULAR INTERACTION; NANOFILTRATION; PERMEABILITY; POROSITY; PRIORITY JOURNAL; REVERSE OSMOSIS; SOLUBILITY; SOLUTE; THEORY;

EID: 0036809664     PISSN: 03767388     EISSN: None     Source Type: Journal    
DOI: 10.1016/S0376-7388(02)00315-0     Document Type: Article

References (39)

1. S. Sourirajan, T. Matsuura, Reverse Osmosis/Ultrafiltration Principles, National Research Council of Canada, Ottawa, Canada, 1985.
2. Niwa M., Ohya H., Kuwahara E., Negishi Y. Reverse osmotic concentration of aqueous 2-butanone (methyl ethyl ketone), tetrahydrofuran and ethyl acetate solutions. J. Chem. Eng. Jpn. 21(2):1988;164-171.
3. Machado D.R., Hasson D., Semiat R. Effect of solvent properties on permeate flow through nanofiltration membranes Part II, Transport model. J. Membr. Sci. 166:1999;63-69.
4. Machado D.R., Hasson D., Semiat R. Effect of solvent properties on permeate flow through nanofiltration membranes. Part 1: investigation of parameters affecting solvent flux. J. Membr. Sci. 163:1999;93-102.
5. Paul D.R., Ebra-Lima O.M. The mechanism of liquid transport through highly swollen polymeric membranes. J. Appl. Polym. Sci. 15:1970;2199-2210.
6. Paul D.R., Paciotti J.D., Ebra-Lima O.M. Hydraulic permeation of liquids through swollen polymeric networks. J. Appl. Polym. Sci. 19:1975;1837-1845.
7. Paul D.R., Paciotti J.D. Driving force for hydraulic and pervaporative transport in homogeneous membranes. J. Polym. Sci. 13:1975;1201-1214.
8. Paul D.R. The solution-diffusion model for swollen membranes. Sep. Purif. Meth. 5(1):1976;33-50.
9. Farnand B.A., Talbot F.D.F., Matsuura T., Sourirajan S. Reverse osmosis separations of some organic and inorganic solutes in methanol solutions using cellulose acetate membranes. Ind. Eng. Chem. Process Design Dev. 22:1983;179-187.
10. Paul D.R., Garcin M., Garmon W.E. Solute diffusion through swollen polymer membranes. J. Appl. Polym. Sci. 20:1976;609-625.
11. Whu J.A., Baltzis B.C., Sirkar K.K. Nanofiltration studies of larger organic microsolutes in methanol solutions. J. Membr. Sci. 170:2000;159-172.
12. Whu J.A., Baltzis B.C., Sirkar K.K. Modeling of nanofiltration - assisted organic synthesis. J. Membr. Sci. 163:1999;319-331.
13. Koops G.H., Yamada S., Nakao S.-I. Separation of linear hydrocarbons and carboxylic acids from ethanol and hexane solutions by reverse osmosis. J. Membr. Sci. 189:2001;241-254.
14. Yang X.J., Livingston A.G., Freitas dos Santos L. Experimental observations of nanofiltration with organic solvents. J. Membr. Sci. 190:2001;45-55.
15. Kopecek J., Sourirajan S. Performance of porous cellulose acetate membranes for the reverse osmosis separation of mixtures of organic liquids. Ind. Eng. Chem. Process Design Dev. 9(1):1970;5-12.
16. Zwijnenberg H.J., Krosse A.M., Ebert K., Peinemann K.-V., Cuperus F.P. Acetone-stable nanofiltration membranes in deacidifying vegetable oil. J. Am. Oil Chemists Soc. 76(1):1999;83-87.
17. Tsuru T., Sudoh T., Yoshioka T., Asaeda M. Nanofiltration in non-aqueous solutions by porous silica-zirconia membranes. J. Membr. Sci. 185:2001;253-261.
18. Ohya H., Okazaki I., Aihara M., Tanisho S., Negishi Y. Study on molecular weight cut-off performance of asymmetric aromatic polyimide membrane. J. Membr. Sci. 123:1997;143-147.
19. White S.L., Nitsch A.R. Solvent recovery from lube oil filtrates with a polyimide membrane. J. Membr. Sci. 179:2000;267-274.
20. Gould R.M., White S.L., Wildemuth C.R. Membrane separation in solvent lube dewaxing. Environ. Progress. 20(1):2001;12-16.
21. Bhanushali D., Bhattacharyya D., Kloos S.D., Kurth C.J. Performance of solvent-resistant membranes for non-aqueous systems: solvent permeation results and modeling. J. Membr. Sci. 189:2001;1-21.
22. Soltanieh M., Gill W. Review of reverse osmosis membranes and transport models. Chem. Eng. Commun. 12:1981;279.
23. Williams M.E., Hestekin J.A., Smothers C.N., Bhattacharyya D. Separation of organic pollutants by reverse osmosis and nanofiltration membranes: mathematical models and experimental verification. Ind. Eng. Chem. Res. 38(10):1999;3683-3695.
24. Matsuura T., Blais P., Dickson J.M., Sourirajan S. Reverse osmosis separations for some alcohols and phenols in aqueous solutions using aromatic polyamide membranes. J. Appl. Polym. Sci. 18:1974;3671-3684.
25. Matsuura T., Sourirajan S. Reverse osmosis separations of hydrocarbons in aqueous solutions using porous cellulose acetate membranes. J. Appl. Polym. Sci. 17:1973;3683-3708.
26. Matsuura T., Sourirajan S. Reverse osmosis separation of phenols in aqueous solutions using porous cellulose acetate membranes. J. Appl. Polym. Sci. 16:1972;2531-2554.
27. Burghoff H.G., Lee K.L., Pusch W. Characterization of transport across cellulose acetate membrane in the presence of strong solute-membrane interactions. J. Appl. Polym. Sci. 25:1980;323-347.
28. Lonsdale H.K., Merten U., Riley R.L. Transport properties of cellulose acetate membranes to selected solutes. J. Appl. Polym. Sci. 9:1965;1341-1362.
29. Wijmans J.G., Baker R.W. The solution-diffusion model: a review. J. Membr. Sci. 107:1995;1-21.
30. Gilron J., Gara N., Kedem O. Experimental analysis of negative salt rejection in nanofiltration membranes. J. Membr. Sci. 185:2001;223-236.
31. Mehdizadeh H., Dickson J.M. Evaluation of surface force-pore flow model and modified surface force-pore flow models for reverse osmosis transport. Chem. Eng. Commun., Membr. Sci. 103:1991;65-82.
32. Mehdizadeh H., Dickson J.M. Modeling of reverse osmosis in the presence of strong solute-membrane affinity. AIChE J. 39(3):1993;434-445.
33. K.S. Sirkar, W.S. Ho, Membrane Handbook, Chapman & Hall, London, 1993.
34. Huang J., Guo Q., Ohya H., Fang J. The characteristics of cross-linked PAA composite membrane for separation of aqueous organic solutions by reverse osmosis. J. Membr. Sci. 144:1998;1-11.
35. Perry M., Linder C. Intermediate reverse osmosis ultrafiltration (RO UF) membranes for concentration and desalting of low molecular weight organic solutes. Desalination. 71:1989;233-245.
36. Bartowiak W., Lipinski J. Conformation and solvent dependence of the first molecular hyperpolarizability of pyridinium-N-phenoxide betaine dyes. Quantum chemical calculations. J. Phys. Chem. A. 102:1998;5236-5240.
37. Ghanadzadeh A., Ghanadzdeh H., Ghasmi G. On the molecular structure and aggregative properties of Sudan dyes in the anisotropic host. J. Mol. Liquids. 88:2000;299-308.
38. Bhattacharyya D., Jevtitch M., Schrodt J.T., Fairweather G. Prediction of membrane separation characteristics by pore distribution measurements and surface force-pore flow model. Chem. Eng. Commun. 42:1986;111-128.
39. Jagur-Grodzinski J., Kedem O. Transport coefficients and salt rejection in hyperfiltration membranes. Desalination. 1:1966;327.