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Volumn 6, Issue 11, 2000, Pages 2011-2015

Steel-promoted oxidation of olefins in supercritical carbon dioxide using dioxygen in the presence of aldehydes

Author keywords

Catalysis; Epoxidation; Oxygen; Supercritical carbon dioxide; Wall effect

Indexed keywords

ALKENE DERIVATIVE; CARBON DIOXIDE; CYCLOHEXENE DERIVATIVE; CYCLOOCTENE; ISOPHORONE; LIMONENE; OXYGEN; UNCLASSIFIED DRUG;

EID: 0034595987     PISSN: 09476539     EISSN: None     Source Type: Journal    
DOI: 10.1002/1521-3765(20000602)6:11<2011::AID-CHEM2011>3.0.CO;2-L     Document Type: Article
Times cited : (73)

References (26)
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    • d) R. Noyori (Guest-Editor), Chem. Rev. 1999, 99, issue 2.
    • (1999) Chem. Rev. , vol.99 , Issue.2
    • Noyori, R.1
  • 8
    • 0031471863 scopus 로고    scopus 로고
    • A. Fürstner, D. Koch, K. Langemann, W. Leitner, C. Six, Angew. Chem. 1997, 109, 2562-2565; Angew. Chem. Int. Ed. Engl. 1997, 36, 2466-2469.
    • (1997) Angew. Chem. Int. Ed. Engl. , vol.36 , pp. 2466-2469
  • 16
  • 21
    • 85007648432 scopus 로고    scopus 로고
    • note
    • To exclude the possibility of catalysis by trace amounts of metals remaining in the autoclave from previous experiments, the reactor was washed extensively with acids, bases, and various organic solvents but no significant change in epoxidation rate was observed. Finally, we decided to manifacture a new autoclave from austenitic steel (material number 1.4571). Again almost quantitative epoxidation of cis-cyclo-octene occurred in the first run.
  • 24
    • 85007646219 scopus 로고    scopus 로고
    • note
    • This induction period shows some variation, see Table 1, entry 3.


* 이 정보는 Elsevier사의 SCOPUS DB에서 KISTI가 분석하여 추출한 것입니다.