Preparation of allylic germanes with tri(2-furyl)germane via π-allylpalladium species

Synlett

Volumn , Issue 11, 2002, Pages 1916-1918

  Kinoshita, Hidenori ^a   Shinokubo, Hiroshi ^a   Oshima, Koichiro ^a  

^a KYOTO UNIVERSITY   (Japan)

Author keywords

Allylgermane; Allylic substitution; Allylpalladium; Germanium; Palladium

Indexed keywords

ALLYL COMPOUND; GERMANIUM DERIVATIVE; PALLADIUM COMPLEX;

ARTICLE; CATALYSIS; REACTION ANALYSIS; REDUCTION; ROOM TEMPERATURE; SYNTHESIS;

EID: 0036428018     PISSN: 09365214     EISSN: None     Source Type: Journal    
DOI: 10.1055/s-2002-34872     Document Type: Article

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35. For examples of allylgermanes in organic synthesis, see: (a) Akiyama, T.; Iwai, J.; Onuma, Y.; Kagoshima, H. Chem. Commun. 1999, 2191. (b) Akiyama, T.; Suzuki, M. Chem. Commun. 1997, 2357. (c) Akiyama, T.; Iwai, J. Synlett 1998, 273. (d) Akiyama, T.; Iwai, J. Tetrahedron Lett. 1997, 38, 853. (e) Mochida, K.; Asami, K. J. Orgmet. Chem. 1982, 232, 13. (f) Mochida, K.; Miyagawa, I. Bull. Chem. Soc. Jpn. 1983, 56, 1875. (g) Sano, H.; Miyazaki, Y.; Okawara, M.; Ueno, Y. Synthesis 1986, 776. (h) Light, J. P. I. I.; Reidenor, M.; Beard, L.; Hershberger, J. W. J. Orgmet. Chem. 1987, 326, 17. (i) Sugawara, M.; Yoshida, J. J. Org. Chem. 2000, 65, 3135.
36. For examples of allylgermanes in organic synthesis, see: (a) Akiyama, T.; Iwai, J.; Onuma, Y.; Kagoshima, H. Chem. Commun. 1999, 2191. (b) Akiyama, T.; Suzuki, M. Chem. Commun. 1997, 2357. (c) Akiyama, T.; Iwai, J. Synlett 1998, 273. (d) Akiyama, T.; Iwai, J. Tetrahedron Lett. 1997, 38, 853. (e) Mochida, K.; Asami, K. J. Orgmet. Chem. 1982, 232, 13. (f) Mochida, K.; Miyagawa, I. Bull. Chem. Soc. Jpn. 1983, 56, 1875. (g) Sano, H.; Miyazaki, Y.; Okawara, M.; Ueno, Y. Synthesis 1986, 776. (h) Light, J. P. I. I.; Reidenor, M.; Beard, L.; Hershberger, J. W. J. Orgmet. Chem. 1987, 326, 17. (i) Sugawara, M.; Yoshida, J. J. Org. Chem. 2000, 65, 3135.
37. For examples of allylgermanes in organic synthesis, see: (a) Akiyama, T.; Iwai, J.; Onuma, Y.; Kagoshima, H. Chem. Commun. 1999, 2191. (b) Akiyama, T.; Suzuki, M. Chem. Commun. 1997, 2357. (c) Akiyama, T.; Iwai, J. Synlett 1998, 273. (d) Akiyama, T.; Iwai, J. Tetrahedron Lett. 1997, 38, 853. (e) Mochida, K.; Asami, K. J. Orgmet. Chem. 1982, 232, 13. (f) Mochida, K.; Miyagawa, I. Bull. Chem. Soc. Jpn. 1983, 56, 1875. (g) Sano, H.; Miyazaki, Y.; Okawara, M.; Ueno, Y. Synthesis 1986, 776. (h) Light, J. P. I. I.; Reidenor, M.; Beard, L.; Hershberger, J. W. J. Orgmet. Chem. 1987, 326, 17. (i) Sugawara, M.; Yoshida, J. J. Org. Chem. 2000, 65, 3135.
38. For examples of allylgermanes in organic synthesis, see: (a) Akiyama, T.; Iwai, J.; Onuma, Y.; Kagoshima, H. Chem. Commun. 1999, 2191. (b) Akiyama, T.; Suzuki, M. Chem. Commun. 1997, 2357. (c) Akiyama, T.; Iwai, J. Synlett 1998, 273. (d) Akiyama, T.; Iwai, J. Tetrahedron Lett. 1997, 38, 853. (e) Mochida, K.; Asami, K. J. Orgmet. Chem. 1982, 232, 13. (f) Mochida, K.; Miyagawa, I. Bull. Chem. Soc. Jpn. 1983, 56, 1875. (g) Sano, H.; Miyazaki, Y.; Okawara, M.; Ueno, Y. Synthesis 1986, 776. (h) Light, J. P. I. I.; Reidenor, M.; Beard, L.; Hershberger, J. W. J. Orgmet. Chem. 1987, 326, 17. (i) Sugawara, M.; Yoshida, J. J. Org. Chem. 2000, 65, 3135.
39. For examples of allylgermanes in organic synthesis, see: (a) Akiyama, T.; Iwai, J.; Onuma, Y.; Kagoshima, H. Chem. Commun. 1999, 2191. (b) Akiyama, T.; Suzuki, M. Chem. Commun. 1997, 2357. (c) Akiyama, T.; Iwai, J. Synlett 1998, 273. (d) Akiyama, T.; Iwai, J. Tetrahedron Lett. 1997, 38, 853. (e) Mochida, K.; Asami, K. J. Orgmet. Chem. 1982, 232, 13. (f) Mochida, K.; Miyagawa, I. Bull. Chem. Soc. Jpn. 1983, 56, 1875. (g) Sano, H.; Miyazaki, Y.; Okawara, M.; Ueno, Y. Synthesis 1986, 776. (h) Light, J. P. I. I.; Reidenor, M.; Beard, L.; Hershberger, J. W. J. Orgmet. Chem. 1987, 326, 17. (i) Sugawara, M.; Yoshida, J. J. Org. Chem. 2000, 65, 3135.
40. For examples of allylgermanes in organic synthesis, see: (a) Akiyama, T.; Iwai, J.; Onuma, Y.; Kagoshima, H. Chem. Commun. 1999, 2191. (b) Akiyama, T.; Suzuki, M. Chem. Commun. 1997, 2357. (c) Akiyama, T.; Iwai, J. Synlett 1998, 273. (d) Akiyama, T.; Iwai, J. Tetrahedron Lett. 1997, 38, 853. (e) Mochida, K.; Asami, K. J. Orgmet. Chem. 1982, 232, 13. (f) Mochida, K.; Miyagawa, I. Bull. Chem. Soc. Jpn. 1983, 56, 1875. (g) Sano, H.; Miyazaki, Y.; Okawara, M.; Ueno, Y. Synthesis 1986, 776. (h) Light, J. P. I. I.; Reidenor, M.; Beard, L.; Hershberger, J. W. J. Orgmet. Chem. 1987, 326, 17. (i) Sugawara, M.; Yoshida, J. J. Org. Chem. 2000, 65, 3135.
41. For examples of allylgermanes in organic synthesis, see: (a) Akiyama, T.; Iwai, J.; Onuma, Y.; Kagoshima, H. Chem. Commun. 1999, 2191. (b) Akiyama, T.; Suzuki, M. Chem. Commun. 1997, 2357. (c) Akiyama, T.; Iwai, J. Synlett 1998, 273. (d) Akiyama, T.; Iwai, J. Tetrahedron Lett. 1997, 38, 853. (e) Mochida, K.; Asami, K. J. Orgmet. Chem. 1982, 232, 13. (f) Mochida, K.; Miyagawa, I. Bull. Chem. Soc. Jpn. 1983, 56, 1875. (g) Sano, H.; Miyazaki, Y.; Okawara, M.; Ueno, Y. Synthesis 1986, 776. (h) Light, J. P. I. I.; Reidenor, M.; Beard, L.; Hershberger, J. W. J. Orgmet. Chem. 1987, 326, 17. (i) Sugawara, M.; Yoshida, J. J. Org. Chem. 2000, 65, 3135.
42. 3Ge: C, 57.22; H, 4.48%.
43. 5e