Chemoselective allylation of aldimine with allyltriethylgermane by the combined use of BF3·OEt2 and AcOH

Chemical Communications

Volumn , Issue 21, 1999, Pages 2191-2192

  Akiyama, Takahiko ^a   Iwai, Junko ^a   Onuma, Yuji ^a   Kagoshima, Hirotaka ^a  

^a GAKUSHUIN UNIVERSITY   (Japan)

Author keywords

[No Author keywords available]

Indexed keywords

ACETIC ACID DERIVATIVE; ALDEHYDE; ALLYL COMPOUND; AMINE; ANILINE; GERMANIUM DERIVATIVE; IMINE; METAL COMPLEX;

ARTICLE; CATALYST; CHEMICAL MODIFICATION; CHEMICAL REACTION KINETICS; REACTION ANALYSIS; SYNTHESIS;

EID: 0033533930     PISSN: 13597345     EISSN: None     Source Type: Journal    
DOI: 10.1039/a907538k     Document Type: Article

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19. 3·2AcOH gave comparable results.
20. 2 and 0.5 equiv. of AcOH, may be the active species. For examples of the intramolecular allylation of imines with allylstannanes wherein protic acids have been employed, see: I. Kadota, J.-Y. Park and Y. Yamamoto, Chem. Commun., 1996, 841; J.-Y. Park, I. Kadota and Y. Yamamoto, J. Org. Chem., 1999, 64, 4901.
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