Computer-aided measurement of vapour-liquid equilibria in a dynamic still at sub-atmospheric pressures

Developments in Chemical Engineering and Mineral Processing

Volumn 10, Issue 5-6, 2002, Pages 615-637

  Joseph, M A ^a   Ramjugernath, D ^a   Raal, J D ^a  

^a UNIVERSITY OF KWAZULU NATAL   (South Africa)

Author keywords

[No Author keywords available]

Indexed keywords

ATMOSPHERIC PRESSURE; COMPUTER CONTROL SYSTEMS; ETHANOL; PARAFFINS; THERMODYNAMICS; VAPORIZATION; VISCOSITY;

COMPUTER-AIDED MEASUREMENT;

PHASE EQUILIBRIA;

EID: 0036378942     PISSN: 09691855     EISSN: None     Source Type: Journal    
DOI: 10.1002/apj.5500100612     Document Type: Article

References (35)

1. Yerazunis, S.; Plowright, J.D. and Smola, F.M. 1964. Vapor-Liquid Equilibrium Determination by a New Apparatus. AIChE Journal, 10, 660-665.
2. Morachevsky, A.G. and Zharov, V.T. 1963. Vapour-Liquid Equilibrium Data Collection, Organic Hydroxy Compounds: Alcohols. Zhurnal Prikladnoi Khimii, 36, 2771 as reported by Gmehling, J. and Onken, U. 1977, Vol. 1, Part 2a, 429, DECHEMA, Frankfurt/Main.
3. Maher, P.J. and Smith, B.D. 1979. Infinite Dilution Activity Coefficient Values from Total Pressure VLE data. Effect of equation of state used. Industrial and Engineering Chemistry Fundamentals, 18(4), 354-357.
4. Wilson, G.M. 1964. Vapor-Liquid Equilibrium. XI: A New Expression for the Excess Free Energy of Mixing. Journal of the American Chemical Society, 86, 127-130.
5. Moon, H.M.; Ochi, K. and Kojima, K. 1991. Thermodynamic Consistency Test of Vapour-Liquid Equilibrium Data-Alcohol-Hydrocarbon Systems. Fluid Phase Equilibria, 62, 29-40.
6. Ellis, S.R.M. and Jonah, D.A. 1962. Prediction of activity coefficients at infinite dilution. Chemical Engineering Science, 17, 971-976.
7. nd Ed. CRC Press, Boca Raton, FL.
8. Raal, J.D. and Ramjugernath, D. 2001. Rigorous Characterization of Static and Dynamic Apparatuses for Measuring Limiting Activity Coefficients. Fluid Phase Equilibria, 187-188, 473-487.
9. Raal, J.D. and Brouckaert, C.J. 1992. Vapour-Liquid and Liquid-Liquid Equilibria in the System Methyl Butenol-Water. Fluid Phase Equilibria, 74, 253-270.
10. th ed. McGraw-Hill, New York.
11. Raal, J.D. and Mühlbauer, A.L. 1998. Phase Equilibria: Measurement and Computation. Taylor and Francis, Bristol PA.
12. Gmehling, J. and Onken, U. 1977. Vapour Liquid Equilibrium Data Collection, Organic Hydroxy Compounds: Alcohols. DECHEMA, Frankfurt.
13. Scatchard, G. and Satkiewicz, F.G. 1964. Vapour-Liquid Equilibrium. XII. The System Ethanol-Cyclohexane from 5-65°C. Journal of the American Chemical Society, 86, 130-133.
14. Walas, S.M. 1985. Phase Equilibrium in Chemical Engineering. Butterworth, Boston.
15. Marquardt, D.W. 1963. An Algorithm for least-squares estimation of non-linear parameters. Journal. Society of Industrial and Applied Mathematics, 11, 431-441.
16. Hayden, J.G. and O'Connel, J.P. 1975. A Generalized Method for Predicting Second Vidal Coefficients. Industrial and Engineering Chemistry. Process Design and Development, 14, 209-216.
17. Rackett,H.G. 1970. Equation of State for Saturated Liquids. Journal of Chemical and Engineering Data, 15, 514-517.
18. Herington, E.F.G. 1947. A Thermodynamic Consistency Test for the Internal Consistency of Experimental Data of Volatility Ratios. Nature, 160, 610-611.
19. Redlich, O. and Kister, A.T. 1948. Algebraic Representation of Thermodynamic Properties and the Classification of Solutions. Industrial Engineering Chemistry, 40, 345-348.
20. Van Ness, H.C.; Byer, S.M. and Gibbs, R.E. 1973. Vapor-Liquid Equilibrium: Part I. An Appraisal of Data Reduction Methods. AIChE Journal, 19, 238-244.
21. Van Ness, H.C. 1995. Thermodynamics in the Treatment of Vapor/Liquid Equilibrium (VLE) Data. Pure and Applied Chemistry, 67(6), 859-872.
22. Van Ness, H.C. 1959. Exact Forms of the Unrestricted Gibbs-Duhem Equation. Chem. Eng. Sci., 10, 225-228.
23. Fredunslund, A.; Gmehling, J. and Rasmussen, P. 1977. Vapour-Liquid Equilibria using UNIFAC. Elsevier, Amsterdam.
24. Danner, R.P. and Gess, M.A. 1990. A Data Base Standard for the Evaluation of Vapour-Liquid Equilibrium Models. Fluid Phase Equilibria, 56, 285-301.
25. Hartwick, R.P. and Howat, C.S. 1995. Infinite Dilution Activity Coefficients of Acetone in Water. A New Experimental Method and Verification. J. Chem. Eng. Data, 40, 738-745.
26. Gautreaux, M.F. and Coates, J. 1955. Activity Coefficients at Infinite Dilution. AIChE Journal, 1, 496-500.
27. Pividal, K.A.; Britigh, A. and Sandler, S.I. 1992. Infinite Dilution Activity Coefficients for Oxygenated Systems Determined using a Static Differential Cell. J. Chem. Eng. Data, 37, 484-487.
28. Trampe, D.M. and Eckert, C.A. 1990. Limiting Activity Coefficients from an Improved Differential Boiling Point Technique. J. Chem. Eng. Data, 35, 156-162.
29. Tiegs, D.; Gmehling, J.; Medina, A.; Soares, M.; Bastros, J.; Alessi, P. and Kikic, I. 1986. Activity Coefficients at Infinite Dilution. DECHEMA Chemistry Data Series, DECHEMA, Frankfurt.
30. Dohnal, V. and Horáková, I. 1991. A new variant of the Rayleigh distillation method for the determination of limiting activity coefficients. Fluid Phase Equilibria, 68, 173-185.
31. Klesper, I. 1966. Z. Phys. Chem., 51, 1-12. As given by Christensen, J.J.; Rowley, R.L. and Izatt, R.M. 1982. Handbook of Heats-of-Mixing. John Wiley, New York.
32. Klesper, I. 1966. Z. Phys. Chem., 51, 1-12. As given by Christensen, J.J.; Rowley, R.L. and Izatt, R.M. 1982. Handbook of Heats-of-Mixing. John Wiley, New York.
33. 6 Hydrocarbons and for Hydrocarbon Mixtures. Fluid Phase Equilibria, 119, 113-130.
34. Gierycz, P.; Rogalski, M. and Malanowski, S. 1985. Vapour-Liquid Equilibria in Binary Systems formed by N-methyl pyrrolidone with Hydrocarbons and Hydroxyl Derivatives. Fluid Phase Equilibria, 22, 107.
35. Raal, J.D. 2000. Characterization of Differential Ebulliometers for Measuring Activity Coefficients. AIChE Journal, 46, 210-220.