Characterization of differential ebulliometers for measuring activity coefficients

AIChE Journal

Volumn 46, Issue 1, 2000, Pages 210-220

  Raal, J David ^a  

^a UNIVERSITY OF KWAZULU NATAL   (South Africa)

Author keywords

[No Author keywords available]

Indexed keywords

CALCULATIONS; COMPOSITION; EQUATIONS OF STATE; ETHANOL; MOLECULES; SOLUTIONS; TEMPERATURE MEASUREMENT; THERMODYNAMICS; TOLUENE;

DIFFERENTIAL EBULLIOMETERS; DILUTE ACTIVITY COEFFICIENTS;

PHASE EQUILIBRIA;

ACCURACY; ARTICLE; CALCULATION; CHEMICAL ANALYSIS; CHEMICAL COMPOSITION; CHEMICAL PARAMETERS; DEVICE; EVALUATION; PHASE TRANSITION; REACTION ANALYSIS; VALIDATION PROCESS;

EID: 0033627193     PISSN: 00011541     EISSN: None     Source Type: Journal    
DOI: 10.1002/aic.690460121     Document Type: Article

References (25)

1. Alessi, P., M. Fermeglia, and I. Kikic, "A Differential Static Apparatus for the Investigation of the Infinitely Dilute Region," Fluid Phase Equil., 29, 249 (1986).
2. Alessi, P., I. Kikic, Aa. Fredenslund, and P. Rasmussen, "UNIFAC and Infinite Dilution Activity Coefficients," Can. J. Chem. Eng., 60, 300 (1982).
3. Ambrose, D., Experimental Thermodynamics, Vol. II, Experimental Thermodynamics of Non-Reacting Fluids, Butterworths, London, Chap. 13 (1975).
4. Dallinga, L., M. Schiller, and J. Gmehling, "Measurement of Activity Coefficients at Infinite Dilution Using Differential Ebulliometry and Non-Steady-State Gas-Liquid Chromatography," J. Chem. Eng. Data, 38, 147 (1993).
5. Delcros, S., J.-P. Grolier, V. Dohnal, and D. Fenclova, "Infinite Dilution Activity Coefficients by Comparative Ebulliometry: Measurements and Group Contribution Calculations for Some Binary Mixtures of Ether and n-Alkane and Ether and Alcohol," Chem. Eng. Sci., 50, 2957 (1995).
6. Dohnal, V., and M. Novotna, "Infinite-Dilution Activity Coefficients by Comparative Ebulliometry: A Model of Ebulliometer and the Experimental Equipment and Procedure," Collect. Czech. Chem. Commun., 51, 1393 (1986).
7. Dohnal, V., and M. Novotna, "Infinite-Dilution Activity Coefficients by Comparative Ebulliometry: The Mixtures of Freon 112 with Oxygenated Solvents and Hydrocarbons," Fluid Phase Equil., 23, 303 (1985).
8. Dutt, N. V. K., and D. H. L. Prasad, "Estimation of Infinite Dilution Activity Coefficients of Hydrocarbons in Water from Molar Refraction," Fluid Phase Equil., 45, 1 (1989).
9. Eckert, C. A., B. A. Newman, C. L. Nicolaides, and T. C. Long, "Measurement and Application of Limiting Activity Coefficients," AIChE J., 27, 33 (1981).
10. Gautreaux, M. F., and J. Coates, "Activity Coefficients at Infinite Dilution," AIChE J., 1, 496 (1955).
11. Goncalves, A. S., and E. A. Macedo, "Infinite-Dilution Activity Coefficients by Comparative Ebulliometry: Five Systems Containing Ethyl Formate," Fluid Phase Equil., 85, 171 (1993).
12. Hradetzky, G., M. Wobst, A. Vopel, and H.-J. Bittrich, "Measurement of Activity Coefficients in Highly Dilute Solutions: I," Fluid Phase Equil., 54, 133 (1990).
13. King, C. J., Separation Processes, McGraw-Hill, New York (1971).
14. Kneisl, P., J. W. Zondlo, and W. B. Whiting, "The Effect of Fluid Properties on Ebulliometer Operation," Fluid Phase Equil., 46, 85 (1989).
15. Lobien, G. M., and J. M. Prausnitz, "Infinite-Dilution Activity Coefficients from Differential Ebulliometry," Ind. Eng. Chem. Fundam., 21, 109 (1982).
16. Malanowski, S., "Experimental Methods for Vapour-Liquid Equilibria: I. Circulation Methods," Fluid Phase Equil., 8, 197 (1982).
17. Olson, J. D., "Measurement of Vapor-Liquid Equilibria by Ebulliometry," Fluid Phase Equil., 53, 209 (1989).
18. Pividal, K. A., A. Birtigh, and S. I. Sandler, "Infinite Dilution Activity Coefficients for Oxygenate Systems Determined Using a Differential Static Cell," J. Chem. Eng. Data., 37, 484 (1992).
19. Raal, J. D., and A. L. Mühlbauer, Phase Equilibria: Measurement and Computation, Taylor & Francis, Bristol, PA (1998).
20. Reid, R., J. M. Prausnitz, and T. K. Sherwood, The Properties of Gases and Liquids, McGraw-Hill, New York (1977).
21. Suleiman, D., and C. A. Eckert, "Limiting Activity Coefficients of Diols in Water by a Dew Point Method," J. Chem. Eng. Data, 39, 692 (1994).
22. Thomas, E. R., B. A. Newman, G. L. Nicolaides, and C. A. Eckert, "Limiting Activity Coefficients from Differential Ebulliometry," J. Chem. Eng. Data, 27, 233 (1982).
23. Trampe, D. M., and C. A. Eckert, "Limiting Activity Coefficients from an Improved Differential Boiling Technique," J. Chem. Eng. Data, 35, 156 (1990).
24. Vrbka, P., and V. Dohnal, "Infinite Dilution Activity Coefficients by Comparative Ebulliometry Binary Systems of Chloroethenes with Chloromethanes, Chlorethanes and 1,1,2-Trichlorotrifluoroethane," Fluid Phase Equil., 78, 29 (1992).
25. Wobst, M., G. Hradetzky, and H.-J. Bittrich, "Measurement of Activity Coefficients in Highly Dilute Solutions: II," Fluid Phase Equil., 77, 297 (1992).