Probability distributions of enantiomeric excess in unstirred and stirred crystallization of 1,1′-binaphthyl melt

Chirality

Volumn 14, Issue 1, 2002, Pages 85-89

  Asakura, Kouichi ^a   Soga, Tomomi ^a   Uchida, Tadashi ^a   Osanai, Shuichi ^a   Kondepudi, Dilip K ^a,b  

^a KEIO UNIVERSITY   (Japan)

^b WAKE FOREST UNIVERSITY   (United States)

Author keywords

1,1 binaphthyl; Chiral asymmetry generation; Chiral autocatalysis; Conglomerate; Crystallization; Supercooling; Total spontaneous resolution

Indexed keywords

1,1' BINAPHTHYL DERIVATIVE; NAPHTHALENE DERIVATIVE;

ARTICLE; CATALYSIS; CRYSTAL STRUCTURE; CRYSTALLIZATION; ENANTIOMER; OPTICAL ROTATION; PRIORITY JOURNAL; STOCHASTIC MODEL; TEMPERATURE;

EID: 0036135286     PISSN: 08990042     EISSN: None     Source Type: Journal    
DOI: 10.1002/chir.10046     Document Type: Article

References (20)

1. Spontaneous formation of optically active substances
2. New procedures for reaction of racemic substances
3. Crystallization and solid-state reaction as a route to asymmetric synthesis from achiral starting materials
4. Formation of optically active compounds under achiral synthetic conditions
5. Probability distribution of enantiomorphous forms in spontaneous generation of optically active substances
6. Optical resolution by direct crystallization of enantiomer mixture
7. Chiral symmetry breaking in sodium chlorate crystallization
8. Kinetics of chiral symmetry breaking in crystallization
9. Chiral symmetry breaking in stirred crystallization of 1,1′-binaphthyl melt
10. Chiral symmetry breaking in crystallization: The role of convection
11. 3
12. A new mechanism for nuclei formation in suspension crystallizers: The role of interparticle forces
13. Resolution of optical isomers by crystallization procedures
14. Ground-state strain and other factors influencing optical stability in the 1,1′-binaphthyl series
15. State selection dynamics in symmetry-breaking transitions
16. Stirring rate as a critical parameter in chiral symmetry breaking crystallization