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2 (32 mg) and Ind*Li (40 mg) in benzene at 120°C for 8 h. The presence of the tmeda ligand is a result of its use in the preparation Ind*Li. See reference 12.
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2 is 2.58 Å. Gradoz, P.; Baudry, D.; Ephritikhine, M.; Lance, M.; Nierlich, M.; Vigner, J. J. Organomet. Chem. 1994, 466, 107-118.
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77
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0001411951
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For a caution concerning the use of IR spectroscopy to identify borohydride coordination modes, see: Corey, E. J.; Cooper, N. J.; Canning, W. M.; Lipscomb, W. N.; Koetzle, T. F. Inorg. Chem. 1982, 21, 192-199.
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Nakamoto, K.1
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0011400660
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note
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83
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0011400661
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86
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0033303413
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Cadierno, V.; Diez, J.; Gamasa, M. P.; Gimeno, J.; Lastra, E. Coord. Chem. Rev. 1999, 193-195, 147-205.
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Cadierno, V.1
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Lastra, E.5
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87
-
-
0001345217
-
-
note
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It should be noted that other definitions for defining cyclopentadienyl and indenyl distortions have been introduced. (a) Faller, J. W.; Crabtree, R. H.; Habib, A. Organometallics 1985, 4, 929-935.
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Faller, J.W.1
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0001457916
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(b) Grimmond, B. J.; Corey, J. Y.; Rath, N. P. Organometallics 1999, 18, 404-412.
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Grimmond, B.J.1
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89
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0031515116
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note
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Herrmann, W.A.1
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Herdtweck, E.5
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91
-
-
0002113389
-
-
note
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2 complexes has been discussed previously in the literature, but the existence of only three conformers was considered. (a) Krüger, C.; Lutz, F.; Nolte, M.; Erker, G.; Aulbach, M. J. Organomet. Chem. 1993, 452, 79-86.
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Krüger, C.1
Lutz, F.2
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92
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0030577121
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(b) Knickmeier, M.; Erker, G.; Fox, T. J. Am. Chem. Soc. 1996, 118, 9623-9630.
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Knickmeier, M.1
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93
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0001187565
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(c) Erker, G.; Aulbach, M.; Knickmeier, M.; Wingbermühle, D.; Krüger, C.; Nolte, M.; Werner, S. J. Am. Chem. Soc. 1993, 115, 4590-4601.
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Erker, G.1
Aulbach, M.2
Knickmeier, M.3
Wingbermühle, D.4
Krüger, C.5
Nolte, M.6
Werner, S.7
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94
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0000157209
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-
(d) Dreier, T.; Unger, G.; Erker, G.; Wibbeling, B.; Fröhlich, R. J. Organomet. Chem. 2001, 622, 143-148.
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Dreier, T.1
Unger, G.2
Erker, G.3
Wibbeling, B.4
Fröhlich, R.5
-
95
-
-
0011452232
-
-
note
-
It should be noted that when TA = 180°, two values of OA in the range 0-180° exist, which sum to 180°. For convenience, we adopt the smaller value as OA.
-
-
-
-
96
-
-
0011449326
-
-
note
-
cent-cent}, to the metal.
-
-
-
-
97
-
-
0011401059
-
-
note
-
cent′]. This procedure for calculating OA requires due consideration of the signs of the individual orientation angles: i.e., whether the individual rotation vectors are clockwise or counterclockwise from the metallocene vector.
-
-
-
-
98
-
-
0011493508
-
-
note
-
2.
-
-
-
-
99
-
-
0001406192
-
-
note
-
2. Atwood, J. L.; Hunter, W. E.; Hrncir, D. C.; Samuel, E.; Alt, H.; Rausch, M. Inorg. Chem. 1975, 14, 1757-1762.
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Atwood, J.L.1
Hunter, W.E.2
Hrncir, D.C.3
Samuel, E.4
Alt, H.5
Rausch, M.6
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100
-
-
0004150157
-
-
University of Göettngen, Göettingen, Federal Republic of Germany
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Sheldrick, G. M. SHELXTL, An Integrated System for Solving, Refining and Displaying Crystal Structures from Diffraction Data; University of Göettngen, Göettingen, Federal Republic of Germany, 1981.
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Sheldrick, G.M.1
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