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(o,w) was then calculated at each potential for the conditions specified in the caption of Figure 2. Because we scan E and then take a potential slice rather than just holding constant potential it is possible that there are some kinetic effects in our measurement. The slow scan rate 0.1 mV/s minimizes these, although the FDLD measurements are made under an identical potential program such that kinetic effects present in the electrocapillary measurement are relevant to the observed FDLD response.
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Protonation or aggregation of I results in a strongly blue-shifted absorption band (roughly from 460 to 350 nm); therefore, these species are not accessed by the 457.9 nm excitation line.
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2 =1.28 ns.
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