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Volumn 102, Issue 49, 1998, Pages 9928-9933

Toward infinite-dilution voltammetry

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Indexed keywords


EID: 0001489598     PISSN: 15206106     EISSN: None     Source Type: Journal    
DOI: 10.1021/jp982827+     Document Type: Article
Times cited : (24)

References (33)
  • 3
    • 2742579355 scopus 로고    scopus 로고
    • For a listing of experimental studies in this area, see the following: Xie, Y.; Liu, T. Z.; Osteryoung, J. G. Anal. Chem. 1996, 68, 4124-4129.
    • (1996) Anal. Chem. , vol.68 , pp. 4124-4129
    • Xie, Y.1    Liu, T.Z.2    Osteryoung, J.G.3
  • 8
    • 11744377903 scopus 로고    scopus 로고
    • note
    • 8b
  • 27
    • 11744286316 scopus 로고    scopus 로고
    • note
    • Interestingly, in cases where the second wave of TCNQ departs from the reversible shape, not only does the wave become more drawn-out along the potential axis but it also becomes distinctly asymmetric. This asymmetric shape can be seen in Figure 3 of ref 12b. Digital simulations qualitatively reproduce this shape so long as the comproportionation reaction (dianion + neutral → 2 radical anion) is included in the model. Without it, the second wave retains its symmetrical sigmoid shape as it is caused to become more and more irreversible.


* 이 정보는 Elsevier사의 SCOPUS DB에서 KISTI가 분석하여 추출한 것입니다.