Gold complexes with dithiothiophene ligands: A metal based on a neutral molecule

Chemistry - A European Journal

Volumn 7, Issue 2, 2001, Pages 511-519

  Belo, Dulce ^a   Alves, Helena ^a   Branco Lopes, Elsa ^a   Duarte, Maria Teresa ^b   Gama, Vasco ^a   Teives Henriques, Rui ^a,b   Almeida, Manuel ^a   Pérez Benítez, Aarón ^c   Rovira, Concepció ^c   Veciana, Jaume ^c  

^a INSTITUTO TECNOLÓGICO E NUCLEAR   (Portugal)

^b INSTITUTO SUPERIOR TÉCNICO   (Portugal)

^c INSTITUT DE CIÈNCIA DE MATERIALS DE BARCELONA ICMAB CSIC   (Spain)

Author keywords

Conducting materials; Coordination chemistry; Gold; Magnetic properties; S ligands

Indexed keywords

DITHIOTHIOPHENE LIGAND; GOLD BIS(2,3 DIHYDRO 5,6 THIOPHENEDITHIOLATE); GOLD BIS(ALPHA 2,3 THIOPHENEDITHIOLATE); GOLD COMPLEX; IODINE; LIGAND; METAL; N TERT BUTYL NITRIDOGOLD BIS(2,3 DIHYDRO 5,6 THIOPHENEDITHIOLATE); N TERT BUTYL NITRIDOGOLD BIS(2,3 THIOPHENEDITHIOLATE); N TERT BUTYL NITRIDOGOLD BIS(3,4 THIOPHENEDITHIOLATE); THIOPHENE DERIVATIVE; UNCLASSIFIED DRUG;

ARTICLE; COMPLEX FORMATION; ELECTRIC CONDUCTIVITY; MAGNETISM; SYNTHESIS; TEMPERATURE;

EID: 0035910601     PISSN: 09476539     EISSN: None     Source Type: Journal    
DOI: 10.1002/1521-3765(20010119)7:2<511::AID-CHEM511>3.0.CO;2-5     Document Type: Article

References (52)

1. a) The Physics and Chemistry of Organic Superconductors (Eds: G. Saito, S. Kagoshima), Springer, Berlin, 1990;
2. b) J. M. Williams, J. R. Ferraro, R. J. Thorn, K. D. Carlson, U. Geiser, H. H. Wang, A. M. Kini, M.-H. Whangbo, Organic Superconductors, Including Fullerenes: Synthesis, Structure, Properties, and Theory, Prentice-Hall, Englewood Cliffs, NJ, 1992;
3. c) Organic Conductors; Fundamentals and Applications (Ed: J.-P. Farges), Marcel-Dekker, New York, 1994.
4. a) J. A. McLeverty, Prog. Inorg. Chem. 1968, 10, 29;
5. b) D. Coucuvanis, Prog. Inorg. Chem. 1970, 11, 233;
6. c) R. Eisenberg Prog. Inorg. Chem 1970, 12, 295;
7. d) L. Alcácer, H. Novais, Extended Linear Chain Compounds, Vol. 3 (Ed.: J. S. Miller), Plenum, New York, 1983, Chapter 6, p. 319;
8. e) S. Alvarez, V. Ramon, R. Hoffman, J. Am. Chem. Soc. 1985, 107, 6253.
9. a) M. Almeida, V. Gama, R. T. Henriques, L. Alcácer, Inorganic and Organometallic Polymers with Special Properties (Ed.: R. M. Laine), Kluwer Academic, Dordrecht, 1992, p. 163;
10. b) V. Gama, R. T. Henriques, G. Bonfait, M. Almeida, S. Ravy, J. P. Pouget, L. Alcácer, Mol. Cryst. Liq. Cryst. 1993, 234, 171;
11. c) M. Almeida, R. T. Henriques, Organic Conductive Molecules and Polymers, Vol. 1 (Ed.: H. S. Nalwa), Wiley, Chichester, 1997, Chapter 2, p. 87.
12. a) M. Ahamad, A. E. Underhill, J. Chem. Soc. Chem. Commun 1981, 67;
13. b) M. M. Ahamad, D. J. Turner, A. E. Hunderhill, C. S. Jacobsen, K. Mortensen, K. Carneiro, Phys. Rev. B 1984, 29, 4796.
14. P. Cassoux, L. Valade, Inorganic Materials, 2nd ed. (Eds.: D. W. Bruce, D. O'Hare), Wiley, Chichester, 1996, p. 1.
15. P. Cassoux, J. S. Miller, Chemistry of Advanced Materials (Eds.: L. V. Interrante, M. J. Hampden-Smith), Wiley-VCH, New York, 1998, p. 19.
16. J. H. Waters, H. B. Gray, J. Am. Chem. Soc. 1965, 87, 3534.
17. J. G. M. Van Rens, M. A. Viegers, E. De Boer, Chem. Phys. Lett 1974, 28, 104.
18. R. L. Schlup, A. H. Maki, Inorg. Chem 1974, 13, 44.
19. J. Schultz, H. H. Wang, L. C. Soderholm, T. L. Sifter, J. M. Williams, K. Bechgaard, M. H. Whangbo, Inorg. Chem. 1987, 26, 3757.
20. G. Rindhorf, N. Thorup, T. Bjørnholm, K. Bechgaard, Acta Crystallogr. Sect. C 1990, 46, 1437.
21. N. C. Schiodt, T. Bjørnholm, K. Bechgaard, J. J. Neumeier, C. Allgeier, C. S. Jacobsen, N. Thorup, Phys. Rev. B 1996, 53, 17773.
22. E. B. Yagubskii, A. I. Kotov, E. E. Laukhina, A. A. Ignatev, L. I. Buravov, A. G. Khomenko, V. E. Shklover, S. S. Nagapetyan, Yu T. Struchkov, Synth. Met. 1991, 42, 215.
23. H. Fujiwara, E. Ojima, H. Kobayashi, T. Courcet, I. Malfant, P. Cassoux, Eur. J. Inorg. Chem. 1998, 1631.
24. a) J. Tarrés, N. Santaló, M. Mas, E. Molins, J. Veciana, C. Rovira, S. Yang, H. Lee, D. O. Cowan, M.-L. Doublet, E. Canadell, Chem. Mater. 1995, 7, 1558;
25. b) E. Coronado, L. Falvello, J. R. Galán-Mascarós, C. Giménez-Saiz, C. J. Gómez-García, V. Lauhkin, A. Pérez-Benítez, C. Rovira, J. Veciana, Adv. Mater. 1997, 9, 984;
26. c) C. Rovira, J. Veciana, E. Ribera, J. Tarrés, E. Canadell, R. Rousseau, M. Mas, E. Molins, M. Almeida, R. T. Henriques, J. Morgado, J.-P. Schoeffel, J.-P. Pouget, Angew. Chem. 1997, 109, 2417; Angew. Chem. Int. Ed. Engl. 1997, 36, 21, 2324;
27. c) C. Rovira, J. Veciana, E. Ribera, J. Tarrés, E. Canadell, R. Rousseau, M. Mas, E. Molins, M. Almeida, R. T. Henriques, J. Morgado, J.-P. Schoeffel, J.-P. Pouget, Angew. Chem. 1997, 109, 2417; Angew. Chem. Int. Ed. Engl. 1997, 36, 21, 2324;
28. d) C. Rovira, J. Veciana, E. Ribera, J. Tarrés, E. Canadell, R. Rousseau, M. Mas, E. Molins, M. Almeida, R. T. Henriques, J. Morgado, J.-P. Schoeffel, J.-P. Pouget, Chem. Eur. J. 1999, 5, 2025; for a review see
29. e) C. Rovira in Supramolecular Engineering of Synthetic Metallic Materials (Eds.: J. Veciana et al.), Kluwer Academic, 1999, p. 377.
30. a) L. Y. Chiang, P. Shu, D. Holt, D. O. Cowan, J. Org. Chem. 1983, 48, 4713;
31. b) C. Rovira, J. Veciana, N. Santaló, J. Tarrés, J. Cirujeda, E. Molins, J. Llorca, E. Espinoza, J. Org. Chem. 1994, 59, 3307.
32. A. Pérez-Benítez, J. Tarrés, E. Ribera, J. Veciana, C. Rovira, Synthesis 1999, 4, 577.
33. J.-C. Gabriel, I. Johansen, P. Batail, C. Coulon, Acta Crystallogr. Sect. C 1993, 49, 1052.
34. a) J. H. Enemark, J. A. Ibers, Inorg. Chem. 1968, 7, 2636;
35. b) J. Tarres, M. Mas, E. Molins, J. Veciana, C. Rovira, J. Morgado, R. T. Henriques, M. Almeida, J. Mater. Chem. 1995, 5, 1653;
36. c) N. G. Connelly, J. G. Crossley, A. G. Orpen, H. Salter, J. Chem. Soc. Chem. Commun. 1992, 1564;
37. d) J. C. Fitzmaurice, A. M. Z. Slawin, D. J. Williams, J. D. Woollins, Polyhedron 1990, 9, 1561;
38. e) A. Domingos, R. T. Henriques, V. Gama, M. Almeida, A. L. Vieira, L. Alcácer, Synth. Met. 1988, 27, B411;
39. f ) P. Kuppusamy, N. Venkatalakshmi, P. T. Manoharan, J. Crystallogr. Spectrosc. Res. 1985, 15, 629;
40. g) U. Kleinitz, R. Mattes, Chem. Ber. 1994, 127, 60;
41. h) R. J. Staples, J. P. Fackler Junior, Z. Kristallogr. 1995, 210, 696.
42. a) X. Chi, M. E. Itkis, B. O. Patrick, T. M. Barclay, R. W. Reed, R. T. Oakley, A. W. Cordes, R. C. Haddon, J. Am. Chem. Soc. 1999, 121, 10395;
43. b) A. Kobayashi, H. Tanaka, M. Kumasaki, H. Torii, B. Narymbetov, T. Adachi, J. Am. Chem. Soc. 1999, 121, 10763.
44. P. M. Chaikin and J. F. Kwak, Rev. Sci. Instrum. 1975, 46, 218.
45. M. Almeida, S. Oostra, L. Alcácer, Phys. Rev. B 1984, 30, 2839.
46. E. B. Lopes, INETI-Sacavem, internal report, 1991.
47. R. P. Huebner, Phys. Rev. A 1964, 135, 1281.
48. P. McArdle, J. Appl. Crystallogr. 1995, 28, 65.
49. Egbert Keller, Computer Program for the Graphic Representation of Molecular and Cristallographic Models, Krystallographisches Institut der Universitat Freiburg, Hebelstrasse 25, 79104 Freiburg, Germany.
50. G. M. Sheldrick, SHELXL97: Program for the Refinement of Crystal Structures, University of Göttingen, Germany, 1997.
51. G. M. Sheldrick, Acta Crystallogr. Sect. A 1990, 46, 467.
52. G. M. Sheldrick, SHELXL93: Program for the Refinement of Crystal Structures, University of Göttingen, Germany, 1993.