A persistent carbenium ion on the methanol-to-olefin catalyst HSAPO-34: Acetone shows the way

Journal of Physical Chemistry B

Volumn 105, Issue 19, 2001, Pages 4317-4323

  Song, Weiguo ^a   Nicholas, John B ^b,c   Haw, James F ^a  

^a UNIVERSITY OF SOUTHERN CALIFORNIA   (United States)

^b PACIFIC NORTHWEST NATIONAL LABORATORY   (United States)

^c GENENTECH INC   (United States)

Author keywords

[No Author keywords available]

Indexed keywords

ALUMINOSILICATE ZEOLITES; CARBENIUM ION; SILICO AMINOPHOSPHATE CATALYST;

ACETONE; CATALYSTS; DEHYDRATION; DIMERS; HIGH TEMPERATURE EFFECTS; IONS; METHANOL; NUCLEAR MAGNETIC RESONANCE SPECTROSCOPY; NUMERICAL ANALYSIS; OLEFINS; SPECTROSCOPIC ANALYSIS; ZEOLITES;

HYDROCARBONS;

EID: 0035902392     PISSN: 10895647     EISSN: None     Source Type: Journal    
DOI: 10.1021/jp0041407     Document Type: Article

References (23)

1. Stöcker, M. Microporous Mesoporous Mater. 1999, 29, 3-48.
2. Wilson, S.; Barger, P. Microporous Mesoporous Mater. 1999, 29, 117-126.
3. Song, W.; Haw, J. F.; Nicholas, J. B.; Heneghan, K. J. Am. Chem. Soc. 2000, 122, 10726-10727.
4. Haw, J. F.; Nicholas, J. B.; Song, W. G.; Deng, F.; Wang, Z. K.; Xu, T.; Heneghan, C. S. J. Am. Chem. Soc. 2000, 122, 4763-4775.
5. Xu, T.; Barich, D. H.; Goguen, P. W.; Song, W.; Wang, Z.; Nicholas, J. B.; Haw, J. F. J. Am. Chem. Soc. 1998, 120, 4025-4026.
6. Haw, J. F.; Richardson, B. R.; Oshiro, I. S.; Lazo, N. L.; Speed, J. J. Am. Chem. Soc. 1989, 111, 2052-2058.
7. Goguen, P. W.; Xu, T.; Barich, D. H.; Skloss, T. W.; Song, W.; Wang, Z.; Nicholas, J. B.; Haw, J. F. J. Am. Chem. Soc. 1998, 120, 2651-2652.
8. Xu, T.; Munson, E. J.; Haw, J. F. J. Am. Chem. Soc. 1994, 116, 1962-1972.
9. Gauss, J. Chem. Phys. Lett. 1992, 191, 614-620.
10. Lok, B. M.; Messina, C. A.; Patton, R. L.; Gajek, R. T.; Cannan, T. R.; Flanigen, E. M. U.S. Patent 4,440,871, 1984.
11. Munson, E. J.; Murray, D. K.; Haw, J. F. J. Catal. 1993, 141, 733-736.
12. Xu, T.; Haw, J. F. Top. Catal. 1997, 4, 109-118.
13. Haw, J. F.; Goguen, P. W.; Xu, T.; Skloss, T. W.; Song, W.; Wang,Z. Angew. Chem. 1998, 37, 948-949.
14. Becke, A. D. J. Chem. Phys. 1993, 98, 5648-5652.
15. Schafer, A.; Horn, H.; Ahlrichs, R. J. Chem. Phys. 1992, 97, 2571-2577.
16. Frisch, M. J.; Trucks, G. W.; Schlegal, H. B.; Gill, P. M. W.; Johnson, B. G.; Robb, M. A.; Cheeseman, J. R.; Keith T.; Petersson, G.A.; Montgomery, J. A.; Raghavachari, K.; Al-Laham, M. A.; Zakrzewski, V. G.; Ortiz, J. V.; Foresman, J. B.; Cioslowski, J.; Stefanov, B. B.; Nanayakkara, A.; Challacombe, M.; Peng, C. Y.; Ayala, P. Y.; Chen, W.; Wong, M. W.; Andres, J. L.; Replogle, E. S.; Baker, J.; Stewart, J. P.; Head-Gordon, M.; Gonzalez, C.; Pople, J. A. Gaussian 94, Revision B.2.; Gaussian, Inc.: Pittsburgh, PA, 1995.
17. Barich, D. H.; Nicholas, J. B.; Xu, T.; Haw, J. F. J. Am. Chem. Soc. 1998, 120, 12342-12350.
18. Weight hourly space velocity (WHSV) formally has units of grams of reactant per gram of catalyst per hour.
19. Haw, J. F.; Nicholas, J. B.; Xu, T.; Beck, L. W.; Ferguson, D. B. Acc. Chem. Res. 1996, 29, 259-267.
20. Nicholas, J. B.; Xu, T.; Barich, D. H.; Torres, P. D.; Haw, J. F. J. Am. Chem. Soc. 1996, 118, 4202-4203.
21. Xu, T.; Barich, D. H.; Torres, P. D.; Haw, J. F. J. Am. Chem. Soc. 1997, 119, 406-414.
22. Xu, T.; Barich, D. H.; Torres, P. D.; Nicholas, J. B.; Haw, J. F. J. Am. Chem. Soc. 1997, 119, 396-405.
23. Nicholas, J. B.; Haw, J. F. J. Am. Chem. Soc. 1998, 120, 11804-11805.