Synthesis and structure of a 1,1′-diphospha[2]ferrocenophane

Organometallics

Volumn 20, Issue 8, 2001, Pages 1499-1500

  Deschamps, Eliane ^a   Ricard, Louis ^a   Mathey, François ^a  

^a LABORATOIRE HÉTÉROÉLÉMENTS ET COORDINATION   (France)

Author keywords

[No Author keywords available]

Indexed keywords

BISPHOSPHOLIDE; DIPHOSPHAFERROCENOPHANE;

CARBON; CATALYSIS; CHEMICAL BONDS; LITHIUM; STRUCTURE (COMPOSITION); SYNTHESIS (CHEMICAL);

ORGANOMETALLICS;

EID: 0035897460     PISSN: 02767333     EISSN: None     Source Type: Journal    
DOI: 10.1021/om000919r     Document Type: Article

References (21)

1. For a general review on this class of compounds, see: Dillon, K. B.; Mathey, F.; Nixon, J. F. Phosphorus: The Carbon Copy; Wiley: Chichester, U.K., 1998.
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3. (b) Breit, B.; Winde, R.; Harms, K. J. Chem. Soc., Perkin Trans. 1 1997, 2681.
4. (c) Knoch, F.; Kramer, F.; Schmidt, U.; Zenneck, U.; Le Floch, P.; Mathey, F. Organometallics 1996, 15, 831.
5. (d) Le Floch, P.; Knoch, F.; Kramer, F.; Mathey, F.; Scholz, J.; Scholz, W.: Thiele K.-H.; Zenneck, U. Eur. J. Inorg. Chem. 1998, 119.
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7. (b) Ganter, C.; Brassat, L.; Ganter, B. Chem. Ber./Recl. 1997, 130, 1771.
8. (c) Ganter, C.; Brassat, L.; Ganter, B. Tetrahedron: Asymmetry 1997, 8, 2607.
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11. (f) Qiao, S.; Hoic, D. A.; Fu, G. C. Organometallics 1998, 17, 773.
12. (g) Qiao, S.; Fu, G. C. J. Org. Chem. 1998, 63, 4168.
13. Manners, I. Angew. Chem., Int. Ed. Engl. 1996, 35, 1603.
14. A low-yield synthesis of a 1,3,1′3′-tetraphospha[3]ferrocenophane has been previously described: Sierra, M. L.; Maigrot, N.; Charrier, C.; Ricard, L.; Mathey, F. Organometallics 1992, 11, 459.
15. Deschamps, E.; Mathey, F. Bull. Soc. Chim. Fr. 1992, 129, 486.
16. While C-C coupling of organic halides by magnesium in THF is not a classical reaction, it has some precedent in the literature, for example, with halo sugars: Ariatti, M.; Zemlicka, J. J. Org. Chem. 1981, 46, 5204.
17. Abstract
18. Mathey, F.; de Lauzon, G. Organometallic Synthesis 1986, 3, 256.
19. 2: C, 55.30; H, 5.97. Found: C, 55.42; H, 6.06.
20. -3. Data were collected on a Nonius CAD4 diffractometer with graphite-monochromated Mo Kα radiation (λ = 0.710 73 Å). Full details of the crystallographic analysis are described in the Supporting Information.
21. Nelson, J. M.; Rengel, H.; Manners, I. J. Am. Chem. Soc. 1993, 115, 7035.