Regioreversed thermal and photochemical reduction of 10-methylacridinium and 1-methylquinolinium ions by organosilanes and oraganostannanes

Journal of Physical Chemistry A

Volumn 105, Issue 10, 2001, Pages 1857-1868

  Fukuzumi, Shunichi ^a   Fujita, Morifumi ^a,c   Noura, Souta ^a   Ohkubo, Kei ^a   Suenobu, Tomoyoshi ^a   Araki, Yasuyuki ^b   Ito, Osamu ^b  

^a OSAKA UNIVERSITY   (Japan)

^b TOHOKU UNIVERSITY   (Japan)

^c UNIVERSITY OF HYOGO   (Japan)

Author keywords

[No Author keywords available]

Indexed keywords

MARCUS THEORY; PHOTOCHEMICAL REDUCTIONS; PHOTOINDUCED ELECTRON TRANSFER;

ABSORPTION; ACETONITRILE; ELECTRON TRANSITIONS; FLUORESCENCE; GROUND STATE; PHOTOCHEMICAL REACTIONS; PHOTOLYSIS; QUENCHING; RATE CONSTANTS; REDUCTION;

SILANES;

EID: 0035868868     PISSN: 10895639     EISSN: None     Source Type: Journal    
DOI: 10.1021/jp003518y     Document Type: Article

References (121)

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118. 47
119. bet > -λ), which is inconsistent with the results on the forward electron transfer reactions in Figure 3.
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121. + is greatest at the C-2 position (0.18) as compared to the value at the C-4 position (0.098).