Dissociative CO photosubstitution in M(CO)4(1,4-diazabutadiene) complexes (M = W, Mo) by an olefin affording novel fac-M(CO)3(1,4-diazabutadiene)(η2-olefin) derivatives

Organometallics

Volumn 20, Issue 23, 2001, Pages 4775-4792

  Grevels, Friedrich Wilhelm ^a   Kerpen, Klaus ^a   Klotzbücher, Werner E ^a   Schaffner, Kurt ^a   Goddard, Richard ^b   Weimann, Bruno ^b   Kayran, Ceyhan ^c   Özkar, Saim ^c  

^a MAX PLANCK INSTITUTE FOR CHEMICAL ENERGY CONVERSION   (Germany)

^b MAX PLANCK INSTITUT FÜR KOHLENFORSCHUNG   (Germany)

^c MIDDLE EAST TECHNICAL UNIVERSITY   (Turkey)

Author keywords

[No Author keywords available]

Indexed keywords

DIAZABUTADIENE; PHOTOSUBSTITUTION; X RAY DIFFRACTION STRUCTURE ANALYSIS;

CARBON MONOXIDE; COMPLEXATION; DISSOCIATION; INFRARED SPECTROSCOPY; MOLYBDENUM COMPOUNDS; NUCLEAR MAGNETIC RESONANCE SPECTROSCOPY; OLEFINS; PHOTOLYSIS; SUBSTITUTION REACTIONS; TUNGSTEN COMPOUNDS; ULTRAVIOLET SPECTROSCOPY; X RAY DIFFRACTION ANALYSIS;

ORGANOMETALLICS;

EID: 0035851949     PISSN: 02767333     EISSN: None     Source Type: Journal    
DOI: 10.1021/om010410b     Document Type: Article

References (112)

1. Bock, H.; tom Dieck, H. Chem. Ber. 1967, 100, 228-246.
2. tom Dieck, H.; Renk, I. W. Angew. Chem. 1970, 82, 805-807.
3. tom Dieck, H.; Renk, I. W. Angew. Chem., Int. Ed. Engl. 1970, 9, 805-807.
4. tom Dieck, H.; Renk, I. W. Chem. Ber. 1971, 104, 110-130.
5. Brunner, H.; Herrmann, W. A. Chem. Ber. 1972, 105, 770-783.
6. Renk, I. W.; tom Dieck, H. Chem. Ber. 1972, 105, 1403-1418.
7. tom Dieck, H.; Franz, K.-D.; Hohmann, F. Chem. Ber. 1975, 108, 163-173.
8. Wrighton, M. S.; Morse, D. L. J. Organomet. Chem. 1975, 97, 405-420.
9. Balk, R. W.; Stufkens, D. J.; Oskam, A. J. Chem. Soc., Chem. Commun. 1978, 1016-1017.
10. Staal, L. H.; Stufkens, D. J.; Oskam, A. Inorg. Chim. Acta 1978, 26, 255-262.
11. Balk, R. W.; Stufkens, D. J.; Oskam, A. Inorg. Chim. Acta 1978, 28, 133-143.
12. Balk, R. W.; Stufkens, D. J.; Oskam, A. Inorg. Chim. Acta 1979, 34, 267-274.
13. Balk, R. W.; Stufkens, D. J.; Oskam, A. J. Chem. Soc., Chem. Commun. 1979, 604-605.
14. Balk, R. W.; Snoeck, T.; Stufkens, D. J.; Oskam, A. Inorg. Chem. 1980, 19, 3015-3021.
15. Stufkens, D. J. J. Mol. Struct. 1982, 79, 67-82.
16. Manuta, D. M.; Lees, A. J. Inorg. Chem. 1983, 22, 3825-3828.
17. Servaas, P. C.; van Dijk, H. K.; Snoeck, T. L.; Stufkens, D. J.; Oskam, A. Inorg. Chem. 1985, 24, 4494-4498.
18. Macholdt, H.-T.; van Eldik, R.; Kelm, H.; Elias, H. Inorg. Chim. Acta 1985, 104, 115-118.
19. Manuta, D. M.; Lees, A. J. Inorg. Chem. 1986, 25, 1354-1359.
20. Manuta, D. M.; Lees, A. J. Inorg. Chem. 1986, 25, 3212-3218.
21. Ernst, S.; Kurth, Y.; Kaim, W. J. Organomet. Chem. 1986, 302, 211-215.
22. Kaim, W.; Kohlmann, S. Inorg. Chem. 1986, 25, 3306-3310.
23. Rawlins, K. A.; Lees, A. J. Inorg. Chem. 1989, 28, 2154-2160.
24. Stufkens, D. J. Coord. Chem. Rev. 1990, 104, 39-112.
25. Kaim, W.; Kohlmann, S.; Lees, A. J.; Snoeck, T. L.; Stufkens, D. J.; Zulu, M. M. Inorg. Chim. Acta 1993, 210, 159-165.
26. van Dijk, H. K.; Servaas, P. C.; Stufkens, D. J.; Oskam, A. Inorg. Chim. Acta 1985, 104, 179-183.
27. Wieland, S.; van Eldik, R. J. Chem. Soc., Chem. Commun. 1989, 367-369.
28. Wieland, K.; Reddy, K. B.; van Eldik, R. Organometallics 1990, 9, 1802-1806.
29. Víchová, J.; Hartl, F.; Vlček, A., Jr. J. Am. Chem. Soc. 1992, 114, 10903-10910.
30. Lindsay, E.; Vlček, A., Jr.; Langford, C. H. Inorg. Chem. 1993, 32, 2269-2275.
31. Fu, W.-F.; van Eldik, R. Inorg. Chim. Acta 1996, 251, 341-346.
32. Fu, W.-F.; van Eldik, R. Organometallics 1997, 16, 572-578.
33. Fu, W.-F.; van Eldik, R. Inorg. Chem. 1998, 37, 1044-1050.
34. Vlček, A., Jr. Coord. Chem. Rev. 1998, 177, 219-256.
35. Schaper, H.; Behrens, H. J. Organomet. Chem. 1976, 113, 377-386.
36. Lai, C.-H.; Cheng, C.-H.; Chou, W.-C.; Wang, S.-L. Organometallics 1993, 12, 1105-1112.
37. Lai, C.-H.; Cheng, C.-H.; Chou, W.-C.; Wang, S.-L. Organometallics 1993, 12, 3418-3425.
38. Lai, C.-H.; Cheng, C.-H. Organometallics 1993, 12, 3561-3564.
39. Lai, C.-H.; Cheng, C.-H.; Liao, F.-L.; Wang, S.-L. Inorg. Chem. 1993, 32, 5658-5664.
40. Zanello, P.; Laschi, F.; Fontani, M.; Mealli, C.; Ienco, A.; Tang, K.; Jin, X.; Li, L. J. Chem. Soc., Dalton Trans. 1999, 965-970.
41. Grevels, F.-W.; Lindemann, M.; Benn, R.; Goddard, R.; Krüger, C. Z. Naturforsch., B 1980, 35, 1298-1303.
42. Grevels, F.-W.; Skibbe, V. J. Chem. Soc., Chem. Commun. 1984, 681-683.
43. Angermund, K.; Grevels, F.-W.; Krüger, C.; Skibbe, V. Angew. Chem. 1984, 96, 911-913
44. Angew. Chem., Int. Ed. Engl. 1984, 23, 904-905.
45. Grevels, F.-W.; Jacke, J.; Özkar, S. J. Am. Chem. Soc. 1987, 109, 7536-7537.
46. Grevels, F.-W.; Jacke, J.; Klotzbücher, W. E.; Özkar, S.; Skibbe, V. Pure Appl. Chem. 1988, 60, 1017-1024.
47. Grevels, F.-W.; Jacke, J.; Betz, P.; Krüger, C.; Tsay, Y.-H. Organometallics 1989, 8, 293-298.
48. Chmielewski, D.; Grevels, F.-W.; Jacke, J.; Schaffner, K. Angew. Chem. 1991, 103, 1361-1363
49. Angew. Chem., Int. Ed. Engl. 1991, 30, 1343-1345.
50. Grevels, F.-W. In Photoprocesses in Transition Metal Complexes, Biosystems and other Molecules: Experiments and Theory; Kochanski, E., Ed.; Kluwer: Dordrecht, The Netherlands, 1992; pp. 141-171.
51. Grevels, F.-W.; Jacke, J.; Klotzbücher, W. E.; Mark, F.; Skibbe, V.; Schaffner, K.; Angermund, K.; Krüger, C.; Lehmann, C. W.; Özkar, S. Organometallics 1999, 18, 3278-3293.
52. Ball, R. G.; Kiel, G.-Y.; Takats, J.; Krüger, C.; Raabe, E.; Grevels, F.-W.; Moser, R. Organometallics 1987, 6, 2260-2261.
53. Angermund, H.; Grevels, F.-W.; Moser, R.; Benn, R.; Krüger, C.; Romão, M. J. Organometallics 1988, 7, 1994-2004.
54. Angermund, H.; Bandyopadhyay, A. K.; Grevels, F.-W.; Mark, F. J. Am. Chem. Soc. 1989, 111, 4656-4661.
55. Klassen, J. K.; Yang, G. K. Organometallics 1990, 9, 874-876.
56. 13CO in the various stereoisotopomers (a = axial, e = equatorial position). The symbol # denotes mixtures of isotopomers.
57. For the sake of accuracy, the positions of closely spaced bands have been assessed by means of computer-assisted curve fitting using the appropriate options of the GRAMS/32 (V4.0) software package; Galactic Industries Corp. 395 Main Street, Salem, NH 03079.
58. Braterman, P. S. Metal Carbonyl Spectra; Academic Press: London, 1975.
59. Cotton, F. A.; Kraihanzel, C. S. J. Am. Chem. Soc. 1962, 84, 4432-4438.
60. Haas, H.; Sheline, R. K. J. Phys. Chem. 1967, 47, 2996-3021.
61. Bor, G. Inorg. Chim. Acta 1967, 1, 81-92.
62. Bor, G. J. Organomet. Chem. 1967, 10, 343-359.
63. CO, connect the internal CO stretching coordinates with the normal coordinates Q, r = NQ and *r = N*Q. The program is available on request from B.W.
64. tom Dieck, H.; Mack, T.; Peters, K.; von Schnering, H.-G. Z. Naturforsch., B 1983, 38, 568-579.
65. Schenk, W. A.; Müller, H. Chem. Ber. 1982, 115, 3618-3630.
66. Özkar, S.; Kreiter, C. G. J. Organomet. Chem. 1986, 303, 367-374.
67. Darensbourg, D. J.; Zalewski, D. J.; Plepys, C.; Campana, C. Inorg. Chem. 1987, 26, 3727-3732.
68. Wink, D. J.; Oh, C. K. Organometallics 1990, 9, 2403-2406.
69. Grevels, F.-W.; Jacke, J.; Klotzbücher, W. E.; Schaffner, K.; Hooker, R. H.; Rest, A. J. J. Organomet. Chem. 1990, 382, 201-224.
70. Berke, H.; Sontag, C. Z. Naturforsch., B 1985, 40, 794-798.
71. Lai, C.-H.; Cheng, C.-H.; Cheng, M.-C.; Peng, S.-M. J. Chin. Chem. Soc. 1993, 40, 445-450.
72. Tang, K.; Zheng, S.; Jin, X.; Zeng, H.; Gu, Z.; Zhou, X.; Tang, Y. J. Chem. Soc., Dalton Trans. 1997, 3585-3587.
73. Majunke, W.; Leibfritz, D.; Mack, T.; tom Dieck, H. Chem. Ber. 1975, 108, 3025-3029.
74. Timney, J. A. Inorg. Chem. 1979, 9, 2502-2506.
75. Grevels, F.-W. Unpublished material.
76. Hessen, B.; Bol, J. E.; de Boer, J. L.; Meetsma, A.; Teuben, J. H. J. Chem. Soc., Chem. Commun. 1989, 1276-1277.
77. Bachmann, C.; Demuynck, J.; Veillard, A. J. Am. Chem. Soc. 1978, 100, 2366-2369.
78. Albright, T. A.; Hoffmann, R.; Thibeault, J. C.; Thorn, D. L. J. Am. Chem. Soc. 1979, 101, 3801-3812.
79. Pidun, U.; Frenking, G. Organometallics 1995, 14, 5325-5336.
80. Szymańska-Buzar, T.; Kern, K.; Downs, A. J.; Greene, T. M.; Morris, L. J.; Parsons, S. New J. Chem. 1999, 23, 407-416.
81. Toma, J. M. D. R.; Toma, P. H.; Fanwick, P. E.; Bergstrom, D. E.; Byrn, S. R. J. Crystallogr. Spectrosc. Res. 1993, 23, 41-47.
82. Butts, M. D.; Bryan, J. C.; Luo, X.-L.; Kubas, G. J. Inorg. Chem. 1997, 36, 3341-3353.
83. Hsu, H.-F.; Du, Y.; Albrecht-Schmidt, T. E.; Wilson, S. R.; Shapley, J. R. Organometallics 1998, 17, 1756-1761.
84. Schadt, M. J.; Lees, A. J. Inorg. Chem. 1986, 25, 672-677.
85. Kling, O.; Nikolaiski, E.; Schläfer, H. L. Ber. Bunsen-Ges. Phys. Chem. 1963, 67, 883-892.
86. AB which gives the best least-squares fit of the computed concentrations to the experimental data. The appropriate program is available on request from B.W.
87. abs dt.
88. Virrels, I. G.; George, M. W.; Turner, J. J.; Peters, J.; Vlček, A. Jr. Organometallics 1996, 15, 4089-4092.
89. Vlček, A., Jr.; Grevels, F.-W.; Snoeck, T. L.; Stufkens, D. J. Inorg. Chim. Acta 1998, 287, 83-90.
90. Elschenbroich, C.; Salzer, A. Organometallchemie; Teubner: Stuttgart, Germany, 1990.
91. Willner, H.; Aubke, F. Angew. Chem. 1997, 109, 2506-2530;
92. Angew. Chem., Int. Ed. Engl. 1997, 36, 2402-2405.
93. Dahlgren, R. M.; Zink, J. I. Inorg. Chem. 1977, 16, 3154-3161.
94. 3(iprop-dab) and related species is in progress (collaboration with G. Olbrich of the MPI für Strahlenchemie) and will be published in a forthcoming paper.
95. Koemm, U.; Kreiter, C. G.; Strack, H. J. Organomet. Chem. 1978, 148, 179-200.
96. Kreiter, C. G.; Koemm, U. Z. Naturforsch., B 1983, 38, 943-952.
97. Kreiter, C. G.; Strack, H. Z. Naturforsch., B 1975, 30, 748-750.
98. Gregory, M. F.; Jackson, S. A.; Poliakoff, M.; Turner, J. J. J. Chem. Soc., Chem. Commun. 1986, 1175-1177.
99. Weiller, B. H.; Grant, G. R. J. Am. Chem. Soc. 1987, 109, 1252-1253.
100. Grevels, F.-W.; Reuvers, J. G. A.; Takats, J. Inorg. Synth. 1986, 24, 176-180.
101. Vedejs, E.; Snoble, K. A. J.; Fuchs, P. L. J. Org. Chem. 1973, 38, 1178-1183.
102. Inoue, Y.; Tsuneishi, H.; Hakushi, T.; Tai, A. In Photochemical Key Steps in Organic Synthesis: An Experimental Course Book; Mattay, J., Griesbeck, A., Eds.; VCH: Weinheim, Germany, 1994; p 207 .
103. Kliegman, J. M.; Barnes, R. K. Tetrahedron 1970, 26, 2555-2560.
104. Svoboda, M.; tom Dieck, H.; Krüger, C.; Tsay, Y.-H. Z. Naturforsch., B 1981, 36, 814-822.
105. Sheldrick, G. M. SHELXL-97; University of Göttingen, Göttingen, Germany, 1997.
106. Amrein, W.; Gloor, J.; Schaffner, K. Chimia 1974, 28, 185-188.
107. Brauer, H. D.; Schmidt, R.; Gauglitz, G.; Hubig, S. Photochem. Photobiol. 1983, 37, 595-598.
108. (a) Hatchard, C. G.; Parker, C. A. Proc. R. Soc. London, Ser. A 1956, 235, 518-536.
109. (b) Murov, S. L. Handbook of Photochemistry; Dekker: New York, 1973; p 119.
110. Gerhartz, W.; Grevels, F.-W.; Klotzbücher, W. E. Organometallics 1987, 6, 1850-1856.
111. Klotzbücher, W. E. Cryogenics 1983, 23, 554-556.
112. Schaffner, K.; Grevels, F.-W. J. Mol. Struct. 1988, 173, 51-65.