메뉴 건너뛰기




Volumn 20, Issue 25, 2001, Pages 5419-5424

Iron aminocarbene complexes containing a double C=C bond in the N-substituent: Preparation and reactivity

Author keywords

[No Author keywords available]

Indexed keywords

BUTENYL METHYLBENZAMIDE; DIALLYLBENZAMIDE; IRON AMINOCARBENE; TRICARBONYL ALLYL ALLYLAMINO PHENYL CARBENE IRON;

EID: 0035843062     PISSN: 02767333     EISSN: None     Source Type: Journal    
DOI: 10.1021/om010533w     Document Type: Article
Times cited : (19)

References (35)
  • 1
    • 0000786682 scopus 로고    scopus 로고
    • For a recent review of a chelated metal-carbene-alkene complexes see: Schobert, R. J. Organomet. Chem. 2001, 617-618, 346.
    • (2001) J. Organomet. Chem. , vol.617-618 , pp. 346
    • Schobert, R.1
  • 10
    • 0001761231 scopus 로고    scopus 로고
    • For review of carbene-alkyne-alkene cyclization reactions see: Harvey, D. F.; Sigano, D. M. Chem. Rev. 1996, 96, 271.
    • (1996) Chem. Rev. , vol.96 , pp. 271
    • Harvey, D.F.1    Sigano, D.M.2
  • 18
    • 0011518163 scopus 로고    scopus 로고
    • See also references cited in ref 1.
    • (b) Förtsch, W.; Hampel, F.; Schoberg, R. Chem. Ber. 1997, 130, 863. See also references cited in ref 1.
    • (1997) Chem. Ber. , vol.130 , pp. 863
    • Förtsch, W.1    Hampel, F.2    Schoberg, R.3
  • 26
    • 0011460752 scopus 로고    scopus 로고
    • note
    • For discussion of another possible reason of hindered rotation of an aromatic ring see ref 2f.
  • 29
    • 0001632467 scopus 로고
    • note
    • 9 in THF solution at 40°C. The conditions are similar to those reported for isomerization of N,N-diallybenzamide (1a) to N-vinylbenzamide: Murai, T.; Kasai, Z.; Ishihara, H.; Kato, S. J. Org. Chem. 1992, 57, 5542. However, the isomerization leading to carbenes 6 and 7 is much faster even at -78°C.
    • (1992) J. Org. Chem. , vol.57 , pp. 5542
    • Murai, T.1    Kasai, Z.2    Ishihara, H.3    Kato, S.4
  • 31
    • 0342451810 scopus 로고
    • note; J. Wiley: New York
    • Hydrochloride of 1-amino-3-butene was prepared in 81% yield by Curtius reaction of 4-pentenoyl chloride with inactivated sodium azide and subsequent hydrolysis by 36% hydrochloric acid analogously as described in: Smith, P. A. S. Organic Reactions, III; J. Wiley: New York, 1946; p 387, for the preparation of benzylamine hydrochloride. Mp: 167-173°C.
    • (1946) Organic Reactions, III , pp. 387
    • Smith, P.A.S.1
  • 34
    • 0011419969 scopus 로고    scopus 로고
    • note
    • 3).


* 이 정보는 Elsevier사의 SCOPUS DB에서 KISTI가 분석하여 추출한 것입니다.