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0011358870
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note
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For immobilization of rigid-rod polypeptide molecules, such as poly(γ-benzyl-L-glutamate), in a homeotropic orientation on the surface, the required fraction of active functional groups in the layer is ca. 8 mol %. Thus, even with a relatively low yield of activation of ester groups in the mixed silane layer, the concentration of F-Si in the layer of ca. 15 mol % should be sufficient for polypeptide attachment.
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32
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0000721037
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0011288884
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note
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The signal of the C(1s) peak was not reliable because of the unavoidable carbon contaminations.
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35
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0001270867
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39
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0011296070
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note
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The value of λ = 3.75 ± 0.25 nm was found for pure hydrocarbons. We assumed that the same λ can be used for C-8 molecules composed of a relatively long hydrocarbon tail and a single functional silane group.
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41
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33751131313
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0011323752
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note
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11a However, the value of λ = 2.1-2.2 nm agrees well with the theoretical estimate of λ = 2.15 nm for K(2p) (ref 29).
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