EPR and NMR spectroscopic studies of [MoL2(MeC≡CMe)Cp]z (L = P-donor ligand, z = 0 and 1): Fluxionality in a metal–alkyne redox pair

Chemical Communications

Volumn 1, Issue 23, 2001, Pages 2458-2459

  Adams, Christopher J ^a   Connelly, Neil G ^a   Rieger, Philip H ^b  

^a UNIVERSITY OF BRISTOL   (United Kingdom)

^b BROWN UNIVERSITY   (United States)

Author keywords

[No Author keywords available]

Indexed keywords

ALKYNE; METAL DERIVATIVE; MOLYBDENUM;

ARTICLE; CALCULATION; CHEMICAL ANALYSIS; COMPLEX FORMATION; CYCLIC POTENTIOMETRY; ELECTRON SPIN RESONANCE; NUCLEAR MAGNETIC RESONANCE SPECTROSCOPY; OSCILLATION; OXIDATION REDUCTION REACTION; PROTON NUCLEAR MAGNETIC RESONANCE; REACTION ANALYSIS; TEMPERATURE DEPENDENCE;

EID: 0035824308     PISSN: 13597345     EISSN: 1364548X     Source Type: Journal    
DOI: 10.1039/b108561c     Document Type: Article

References (16)

1. J. A. Segal, M. L. H. Green, J.-C. Daran and K. Prout, J. Chem Soc., Chem. Commun., 1976, 766.
2. M. L. H. Green, J. Knight and J. A. Segal, J. Chem. Soc., Dalton Trans., 1977, 2189.
3. M. Bottrill and M. Green, J. Chem. Soc., Dalton Trans., 1977, 2365.
4. S. R. Allen, P. K. Baker, S. G. Barnes, M. Green, L. Trollope, L. Manojlovic-Muir and K. W. Muir, J. Chem. Soc., Dalton Trans., 1981, 873.
5. J. L. Templeton and B. C. Ward, J. Am. Chem. Soc., 1980, 102, 3288.
6. J. L. Templeton, Adv. Organomet. Chem., 1989, 29, 1.
7. S. R. Allen, R. G. Beevor, M. Green, A. G. Orpen, K. E. Paddick and I. D. Williams, J. Chem. Soc., Dalton Trans., 1987, 591.
8. G. Brauers, F. J. Feher, M. Green, J. K. Hogg and A. G. Orpen, J. Chem. Soc., Dalton Trans., 1996, 3387.
9. F. R. Kreissl, W. J. Sieber, P. Hofmann, J. Riede and M. Wolfgruber, Organometallics, 1985, 4, 788.
10. B. Hessen, A. Meetsma, F. van Bolhuis, J. H. Teuben, G. Helgesson and S. Jagner, Organometallics, 1990, 9, 1925.
11. I. M. Bartlett, N. G. Connelly, A. G. Orpen, M. J. Quayle and J. C. Rankin, Chem. Commun., 1996, 2583.
12. I. M. Bartlett, S. Carlton, N. G. Connelly, D. J. Harding, O. D. Hayward, A. G. Orpen, C. D. Ray and P. H. Rieger, Chem. Commun., 1999, 2403.
13. J. A. Pople, W. G. Schneider and H. J. Bernstein, High-resolution Nuclear Magnetic Resonance, McGraw-Hill, New York, 1959, pp. 218-224.
14. N. G. Connelly and W. E. Geiger, Chem. Rev., 1996, 96, 877.
15. N. W. Duffy, R. R. Nelson, M. G. Richmond, A. L. Rieger, P. H. Rieger, B. H. Robinson, D. R. Tyler, J. C. Wang and K. Wang, Inorg. Chem., 1998, 37, 4849.
16. S. D. Ittel, P. J. Krusic and P. Meakin, J. Am. Chem. Soc., 1978, 100, 3264.