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Volumn 20, Issue 16, 2001, Pages 3472-3477

Catalytic fluorination by halide exchange with 16-electron ruthenium(II) complexes. X-ray structure of [Tl(μ-F)2Ru(dppe)2]PF6

Author keywords

[No Author keywords available]

Indexed keywords

CATALYTIC FLUORINATION; CYCLOPROPANATION; EPOXIDATION; HALIDE EXCHANGE; RUTHENIUM COMPLEXES; X RAY STRUCTURE;

EID: 0035817676     PISSN: 02767333     EISSN: None     Source Type: Journal    
DOI: 10.1021/om010288g     Document Type: Article
Times cited : (58)

References (46)
  • 2
    • 0011526496 scopus 로고    scopus 로고
    • Ramachandran, P. V., Ed.; ACS Symposium Series 746; American Chemical Society: Washington, DC
    • (b) Hoffman, R. V.; Tao, J. In Asymmetric Fluoroorganic Chemistry; Ramachandran, P. V., Ed.; ACS Symposium Series 746; American Chemical Society: Washington, DC, 2000; p. 52.
    • (2000) Asymmetric Fluoroorganic Chemistry , pp. 52
    • Hoffman, R.V.1    Tao, J.2
  • 3
    • 0000082777 scopus 로고    scopus 로고
    • Yamamoto, H., Ed.; Springer: Berlin
    • (c) Hiyama, T. In Organofluorine Compounds; Yamamoto, H., Ed.; Springer: Berlin, 2000, p 137.
    • (2000) Organofluorine Compounds , pp. 137
    • Hiyama, T.1
  • 31
    • 0011587974 scopus 로고    scopus 로고
    • note
    • + (X = Br, I), avoiding anion metathesis (often an untidy reaction). For an application, see ref 17.
  • 32
    • 0034300072 scopus 로고    scopus 로고
    • For examples of complexes containing coordinated chloro alkanes that are not stabilized by the chelate effects, see: (a) Fang, X. G.; Scott, B. L.; John, K. D.; Kubas, G. J. Organometallics 2000, 19, 4141.
    • (2000) Organometallics , vol.19 , Issue.4141
    • Fang, X.G.1    Scott, B.L.2    John, K.D.3    Kubas, G.J.4
  • 37
    • 0011528270 scopus 로고    scopus 로고
    • note
    • t-X in view of its high basicity. However, we expect that the coordination to thallium strongly decreases the basicity of fluoride, which also explains the stability of the thallium adduct itself.


* 이 정보는 Elsevier사의 SCOPUS DB에서 KISTI가 분석하여 추출한 것입니다.