A new methodology for the preparation of cationic organoplatinum(II) complexes with hydrogen-bonding functionality

Organometallics

Volumn 20, Issue 16, 2001, Pages 3373-3382

  Gallasch, David P ^a   Tiekink, Edward R T ^a   Rendina, Louis M ^a  

^a UNIVERSITY OF ADELAIDE   (Australia)

Author keywords

[No Author keywords available]

Indexed keywords

CATIONIC ORGANOPLATINUM COMPLEXES; DYNAMIC INTRAMOLECULAR PROCESS; HYDROGEN BONDING FUNCTIONALITY; MONONUCLEAR COMPLEXES;

ADDITION REACTIONS; HYDROGEN BONDS; MOLECULAR DYNAMICS; MOLECULAR STRUCTURE; NUCLEAR MAGNETIC RESONANCE SPECTROSCOPY; OXIDATION; PLATINUM COMPOUNDS; POSITIVE IONS; THERMAL EFFECTS; X RAY CRYSTALLOGRAPHY;

ORGANOMETALLICS;

EID: 0035817646     PISSN: 02767333     EISSN: None     Source Type: Journal    
DOI: 10.1021/om010127c     Document Type: Article

References (35)

1. (a) Leininger, S.; Olenyuk, B.; Stang, P. J. Chem. Rev. 2000, 100, 853.
2. (b) Stang, P. J. Chem. Eur. J. 1998, 4, 19.
3. (c) Olenyuk, B,; Fechtenkötter, A.; Stang, P. J. J. Chem. Soc., Dalton Trans. 1998, 1707.
4. (d) Fujita, M. Chem. Soc. Rev. 1998, 27, 417.
5. (e) Jones, C. J. Chem. Soc. Rev. 1998, 27, 289.
6. (f) Fujita, M.; Ogura, K. Coord. Chem. Rev. 1996, 148, 249.
7. (g) Stang, P. J.; Olenyuk, B. Acc. Chem. Res. 1997, 30, 502.
8. Cao, D. H.; Chen, K.; Fan, J.; Manna, J.; Olenyuk, B.; Whiteford, J. A.; Stang, P. J. Pure Appl. Chem. 1997, 69, 1979.
9. (a) Ducharme, Y.; Wuest, J. D. J. Org. Chem. 1988, 53, 5787.
10. (b) Gallant, M.; Viet, M. R. P.; Wuest, J. D. J. Org. Chem. 1991, 56, 2284.
11. (a) Metzger, S.; Lippert, B. J. Am. Chem. Soc. 1996, 118, 12467.
12. (b) Sigel, R. K. O.; Freisinger, E.; Metzger, S.; Lippert, B. J. Am. Chem. Soc. 1998, 120, 12000.
13. (a) Gianneschi, N. C.; Tiekink, E. R. T.; Rendina, L. M. J. Am. Chem. Soc. 2000, 122, 8474.
14. (b) Crisp, M. G.; Pyke, S. M.; Rendina, L. M. J. Organomet. Chem. 2000, 607, 222.
15. Manna, J.; Kuehl, C. J.; Whiteford, J. A.; Stang, P. J. Organometallics 1997, 16, 1897.
16. (a) Ladipo, F. T.; Kooti, M.; Merola, J. S. Inorg. Chem. 1993, 32, 1681.
17. (b) Van Doorn, J. A.; Masters, S.; Van der Woude, C. J. Chem. Soc., Dalton Trans. 1978, 1213.
18. (c) Marder, T. B.; Champ, D. M.-T.; Fultz, W. C.; Calabrese, J. C.; Milstein., D. J. Chem. Soc., Chem. Commun. 1987, 1885.
19. Greene, T. W.; Wuts, P. G. M. Protective Groups in Organic Synthesis, 2nd ed.; John Wiley & Sons: New York, 1991.
20. 13C NMR of Transition Metal Complexes; Springer-Verlag: Berlin, 1979.
21. Rendina, L. M.; Puddephatt, R. J. Chem. Rev. 1997, 97, 1735.
22. Pregosin, P. S. Coord. Chem. Rev. 1982, 44, 247.
23. Tomasik, P.; Ratajewicz, Z. Pyridine-Metal Complexes; John Wiley & Sons: New York, 1985; Vol. 14, Part 6B.
24. Note that the cationic charge of complex 5 is expected to diminish the degree of back-bonding.
25. 3OD was used as the solvent.
26. Günther, H. NMR Spectroscopy: Basic Principles, Concepts, and Applications in Chemistry, 2nd ed.; John Wiley & Sons: New York, 1995; p 335.
27. -1. A more detailed study of this phenomenom based on line shape analysis of the spectra is planned.
28. Fuss, M.; Siehl, H.-U.; Olenyuk, B.; Stang, P. J. Organometallics 1999, 18, 758.
29. Ugo, R.; Cariati, F.; La Monica, G. Inorg. Synth. 1990, 28, 123.
30. Fujita, M.; Aoyagi, M.; Ogura, K. Inorg. Chim. Acta 1996, 246, 53.
31. teXsan: Structure Analysis Software; Molecular Structure Corp.: The Woodland, TX, 1997.
32. Walker, N.; Stuart, D. Acta Crystallogr. Sect. A 1983, 39, 158.
33. Beurskens, P. T.; Admiraal, G.; Beurskens, G.; Bosman, W. P.; García-Granda, S.; Smits, J. M. M.; Smykalla, C. The DIRDIF program system, Technical Report of the Crystallography Laboratory; University of Nijmegen: The Netherlands, 1992.
34. Johnson, C. K. ORTEP. Report ORNL-5138; Oak Ridge National Laboratory: TN, 1976.
35. Spek, A. L. PLATON, A Multipurpose Crystallographic Tool; Utrecht University: Utrecht, The Netherlands, 2000; http://www.cryst.chem.uu.nl/platon/.