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85033513859
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2O (2).
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2O (2): C, 21.9 (21.8); H, 3.7 (3.6); N, 21.3 (21.5).
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27
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85033519932
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- adduct of the dimer. Mass spectra were recorded on a Finnigan MAT90 spectrometer using an electrospray source (Finnigan) at an acceleration potential of +5000 V and an infusion pump E540101 (TSE) (Harvard Apparatus). The solution of 2 in methanol was infused through a 75 μm fused silica capillary at a flow rate of 0.5 μL/min. 89 scans were recorded in the range of m/z 400-1200 (scan speed 8.27 s/scan).
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- adduct of the dimer. Mass spectra were recorded on a Finnigan MAT90 spectrometer using an electrospray source (Finnigan) at an acceleration potential of +5000 V and an infusion pump E540101 (TSE) (Harvard Apparatus). The solution of 2 in methanol was infused through a 75 μm fused silica capillary at a flow rate of 0.5 μL/min. 89 scans were recorded in the range of m/z 400-1200 (scan speed 8.27 s/scan).
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28
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0019811253
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2O introduced by the complex. Removal of water, e.g. by molecular sieves, represents a problem. See
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85033527947
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2 resonance, and would be sterically unlikely. It would require an intermolecular separation between cytosine C(5) and guanine N(2) of ca. 3 Å.
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2 resonance, and would be sterically unlikely. It would require an intermolecular separation between cytosine C(5) and guanine N(2) of ca. 3 Å.
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34
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33847086520
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85033542556
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6 are similar to those reported previously, e.g. refs 21 and 26. Details will be reported elsewhere.
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6 are similar to those reported previously, e.g. refs 21 and 26. Details will be reported elsewhere.
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37
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0027297046
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a, protonated cytosine should riot exist at physiological pH. As to nucleobase deprotonation, despite the negative charge of the nucleotides in DNA and RNA, it appears not to be impossible. See, e.g.
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a, protonated cytosine should riot exist at physiological pH. As to nucleobase deprotonation, despite the negative charge of the nucleotides in DNA and RNA, it appears not to be impossible. See, e.g.: Yu, H.; Eritja, R.; Bloom, L. B.; Goodman, M. F. J. Biol. Chem. 1993, 268, 15935.
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