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Methyldiopium derived from DIOP was also considered, but the corresponding ylide turned out to be unstable.
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2542581389
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2Rh). For an analogous phosphino-iminophosphorane rhodium complex displaying similar NMR characteristics, see: Reed, R. W.; Santarsiero, B.; Cavell, R. G. Inorg. Chem. 1996, 35, 4292.
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0011390403
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note
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2). Np = naphthylene substituent.
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19
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0011483008
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0011390188
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note
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a); 120-143 (m, aromatic C).
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22
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24
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0011444424
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note
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2 bite angles, ca. 88 and 95°, indicate an approximate square-planar crystal field around the rhodium atom in both the conformers.
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25
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11744305193
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note
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The NMR spectra were calculated at the B3PW91/6-31G:*/LANL2DZ(Rh) level within the framework of the GIAO formalism implemented in Gaussian98 Wolinski, K.; Hinton, J. F.; Pulay, P. J. Am. Chem. Soc. 1990, 112, 8251.
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