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Volumn 134, Issue , 2001, Pages 3-40

Defect structure and acid catalysis of high silica, FAU-framework zeolites: Effects of aluminum removal and of basic metal oxide addition

Author keywords

[No Author keywords available]

Indexed keywords

ALKALI METAL; ALUMINUM; BRONSTED ACID; BUTANE; CALCIUM ION; LEWIS ACID; METAL OXIDE; METHANE; POTASSIUM ION; SILICON DIOXIDE; SODIUM ION; UNCLASSIFIED DRUG; ZEOLITE;

EID: 0035784667     PISSN: 01672991     EISSN: None     Source Type: Journal    
DOI: 10.1016/S0167-2991(01)82308-9     Document Type: Chapter
Times cited : (12)

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    • Carbonium ion selectivities were estimated with the molar product ratio (n-butane + propane + isopentane)/ total conversion products. This ratio accounts for the major carbonium ion based products arising from isomerization and chain-cracking sequences. Carbonium ion activity was defined as the product of carbonium ion selectivity and total rate (See Ref. 12).
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    • note
    • 2. In each case, hydrated zeolite was combined with a properly diluted reagent solution. In order to ensure equilibrium distribution of the added cations, this wet impregnation step was followed by a programmed calcination with slow nitrite/nitrate decomposition and a final calcination temperature of 475 °C. For a series of materials covering the range - 2.5% to 60% cation exchange - good agreement was obtained between nominal and analyzed exchange levels.


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