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Volumn 12, Issue 4, 2001, Pages 405-410

Herringbone Infinite Networks Formed by Terpyridine and Haloperfluoroarene Modules

Author keywords

Fluorine; Molecular recognition; Noncovalent interactions; Pyridine; Supramolecular chemistry

Indexed keywords


EID: 0035589256     PISSN: 10610278     EISSN: None     Source Type: Journal    
DOI: 10.1080/10610270108027472     Document Type: Article
Times cited : (27)

References (37)
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    • note
    • F = + 0.42 and Δδ = + 0.14, respectively.
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    • note
    • 1a and 2a-c melt at 173-175°C, 108-110°C, 78-80°C, and 113-115°C, respectively, and halogen bonded co-crystals 3a-c melt at 210°C, 160°C, and 105°C, respectively.
  • 15
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    • note
    • -1) 3049, 3015; 2a: 1468, 944, 761; 2b: 1497, 956, 789; 2c 1492, 995, 721; 3a: 3053, 3015, 1464, 943, 760; 3b: 3052, 3017, 1481, 955, 788; 3c: 3050, 3015, 994, 721;.
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    • note
    • 13.
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    • note
    • 2) were 0.043 and 0.069, respectively. 1 lies on a C2 crystallographic axis, so the methyl group C9 is disordered, 2a lies on a centre of symmetry.
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    • note
    • (1-x,1-y,1-z) and F2···H7, 2.51(3) and 2.64(4) Å, respectively). These contacts are more responsible for keeping the tolyl, pyridyl, and tetrafluorobenzene rings in a nearly coplanar arrangement rather than for driving the self-assembly of the HC and PFC modules into 3a.
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