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Volumn 40, Issue 11, 2001, Pages 2085-2087

Alkylative Preparation of α-Silylalkyl-magnesium from R3SiCHBr2 Using a Magnesate Reagent

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EID: 0001253905     PISSN: 14337851     EISSN: None     Source Type: Journal    
DOI: 10.1002/1521-3773(20010601)40:11<2085::aid-anie2085>3.0.co;2-k     Document Type: Article
Times cited : (42)

References (42)
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    • For an elegant reaction of magnesium carbenoid with Grignard reagents, see a) R. W. Hoffmann, O. Knopff, A. Kusche, Angew. Chem. 2000, 112, 1521; Angew. chem. Int. Ed. 2000, 39, 1462; b) R. W. Hoffmann, B. Hölzer, O. Knopff, K. Harms, Angew. Chem. 2000, 112, 3206; Angew. Chem. Int. Ed. 2000, 39, 3072; for the use of iodomethylzinc compounds for a homologation reaction, see a) A. Sidduri, M. J. Rozema, P. Knochel, J. Org. Chem. 1993, 58, 2694-2713; b) A. Sidduri, P. Knochel, J. Am. Chem. Soc. 1992, 114, 7579-7581.
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    • The reaction of 5 with aldehydes resulted in the formation of the reduced alcohols and 1-alkenylsilanes.
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    • For the reaction of α-silylalkylmetals with acyl chloride, see a) F. C. Whitmore, L. H. Sommer, J. Gold. R. E. V. Strien. J. Am. Chem. Soc. 1947, 69, 1551; b) T. H. Chan, E. Chang, E. Vinokur, Tetrahedron Lett. 1970, 1137; c) D. E. Seitz, A. Zapata, Synthesis 1981, 557.
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    • For the reaction of α-silylalkylmetals with acyl chloride, see a) F. C. Whitmore, L. H. Sommer, J. Gold. R. E. V. Strien. J. Am. Chem. Soc. 1947, 69, 1551; b) T. H. Chan, E. Chang, E. Vinokur, Tetrahedron Lett. 1970, 1137; c) D. E. Seitz, A. Zapata, Synthesis 1981, 557.
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    • For the reaction of α-silylalkylmetals with acyl chloride, see a) F. C. Whitmore, L. H. Sommer, J. Gold. R. E. V. Strien. J. Am. Chem. Soc. 1947, 69, 1551; b) T. H. Chan, E. Chang, E. Vinokur, Tetrahedron Lett. 1970, 1137; c) D. E. Seitz, A. Zapata, Synthesis 1981, 557.
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