Novel fluorination reagent: IF5/Et3N-3HF

Chemistry Letters

Volumn , Issue 3, 2001, Pages 222-223

  Yoneda, Norihiko ^a   Fukuhara, Tsuyoshi ^a  

^a HOKKAIDO UNIVERSITY   (Japan)

Author keywords

[No Author keywords available]

Indexed keywords

EID: 0035532104     PISSN: 03667022     EISSN: None     Source Type: Journal    
DOI: 10.1246/cl.2001.222     Document Type: Article

References (14)

1. S. D. Taylor, C. C. Kotoris, and G. Hum, Tetrahedron, 55, 12431 (1999).
2. a) "New Fluorinating Agents in Organic Synthesis," ed. by L. German and S. Zemskov, Springer-Verlag Tokyo (1989).
3. b) Y. Katsuhara and D. DesMarteau, J. Am. Chem. Soc., 102, 2681 (1980).
4. a) S. Rozen and M. Brand, J. Org. Chem., 50, 3342 (1980).
5. b) "The Merck Index," 12th ed., Merck & Co., Inc., Whitehouse Station, NJ (1996) p.861.
6. 5 is industrially produced for the production of surfactant and textile chemicals. H. C. Fielding, "Organofluorine Chemicals and Their Industrial Applications," ed. by R. E. Banks, Ellis Harwood Publishers, Chichester (1979), Chap. 11.
7. b) M. Schmeisser, P. Sartoi, and D. Naumann, Chem. Ber., 103, 880 (1970).
8. a) E. W. Osborne, F. Schreiner, and H. Selig, J. Chem. Phys., 54, 3790 (1971).
9. b) M. T. Rogers, J. L. Speirs, H. B. Thompson, and M. B. Panish, J. Am. Chem. Soc., 76, 4843 (1954).
10. 3N. This reagent can be stored in PFA bottle for several months on a laboratory table without any particular caution and without any deterioration of fluorination activity.
11. 3N was carried out according to the technique described in ref 5b.
12. R. D. Burbank and G. R. Jones, Inorg. Chem., 13, 1071 (1974).
13. Tetrafluoroethylene-perfluoroalkylvinyl-ether co-polymer.
14. N. Yoneda, Tetrahedron, 47, 5329 (1991).