Thermodynamic modeling of binary and ternary adsorption on silica gel

AIChE Journal

Volumn 47, Issue 5, 2001, Pages 1234-1246

  Steffan, Dirk G ^a   Akgerman, Aydin ^a  

^a Texas AandM University   (United States)

Author keywords

[No Author keywords available]

Indexed keywords

ADSORPTION; BENZENE; EXTRACTION; ISOTHERMS; TERNARY SYSTEMS; THERMODYNAMICS; VOLATILE ORGANIC COMPOUNDS;

MULTICOMPONENT ADSORPTION;

SILICA GEL;

BENZENE; HEXANE; SILICA GEL; TRICHLOROETHYLENE; VOLATILE ORGANIC COMPOUND; WATER;

BINARY CODE; REMEDIATION; SEPARATION; SILICA GEL; TERNARY MIXTURE; THERMODYNAMICS;

ADSORPTION KINETICS; ARTICLE; DIPOLE; ISOTHERM; MOLECULAR INTERACTION; PHYSICAL PHASE; SURFACE PROPERTY; THERMODYNAMICS; VAPOR PRESSURE;

EID: 0035334277     PISSN: 00011541     EISSN: None     Source Type: Journal    
DOI: 10.1002/aic.690470530     Document Type: Article

References (33)

1. Adamson, A. W., "Physical Adsorption of Vapors - Three Personae," Colloids Surfaces A: Physicochem. Eng. Aspects, 118, 193 (1996).
2. Brunauer, S., P. H. Emmet, and E. Teller, "Adsorption of Gases in Multimolecular Layers," J. Amer. Chem. Soc., 60, 309 (1938).
3. Brunauer, S., L. S. Deming, W. E. Deming, and E. Teller, "On a Theory of the Van der Waals Adsorption of Gases," J. Amer. Chem. Soc., 62, 1723 (1940).
4. Costa, E., J. L. Sotelo, G. Calleja, and C. Marron, "Adsorption of Binary and Ternary Hydrocarbon Gas Mixtures on Activated Carbon: Experimental Determination and Theoretical Prediction of the Ternary Equilibrium Data," AIChE J., 27, 5 (1981).
5. Eubank, P. T., "Secrets of a Reviewer of Low Pressure VLE Articles," personal correspondence, Texas A&M University (1999).
6. Gordon, P. A., and E. D. Glandt, "Adsorption of Polar Gases on Model Silica Gel," Langmuir, 13, 4659 (1997).
7. Guo, Y., C. Thibaud-Erkey, and A. Akgerman, "Gas-Phase Adsorption and Desorption of Single-Component and Binary Mixtures of Volatile Organic Contaminants on Soil," Environ. Eng. Sci., 15, 203 (1998).
8. Gusev, V., J. A. O'Brien, C. R. C. Jense, and N. A. Seaton, "Theory for Multicomponent Adsorption Equilibrium: Multispace Adsorption Model," AIChE J., 42, 2773 (1996).
9. Hoppe, H., and E. Worch, "The Calculation of the Non-Ideal Mixture Adsorption Equilibria of Benzene-Isopropanol-Activated Charcoal-B4 Using Experimentally Determined Activity Coefficients," Z. Phys. Chem.-Leipzig, 263, 1169 (1982).
10. Huyskens, P. L., W. A. P. Luck, and T. Zeegers-Huyskens, Intermolecular Forces - An Introduction to Modern Methods and Results, Springer Verlag, Berlin (1991).
11. Israelachvili, J. N., Intermolecular and Surface Forces, First ed., Academic Press, London (1984).
12. Jensen, C. R. C., N. A. Seaton, V. Gusev, and J. A. O'Brien, "Prediction of Multicomponent Adsorption Equilibrium Using a New Model of Adsorption Phase Nonuniformity," Langmuir, 13, 1205 (1997).
13. Kast, W., Adsorption aus der Gasphase: ingenieurwiss. Grundlagen und techn. Verfahren, VCH, Weinheim, Germany (1988).
14. Kruk, M., A. Patrykiejew, and S. Sokolowski, "Multilayer Adsorption of Binary Mixtures: Mean-Field Theory and Monte Carlo Simulation," Surface Sci., 340, 179 (1995).
15. Miller, G. W., K. S. Knaebel, and K. G. Ikels, "Equilibria of Nitrogen, Oxygen, Argon and Air in Molecular Sieve-5A," AIChE J., 33, 194 (1987).
16. Myers, A. L., C. Minka, and J. D. Y. Ou, "Thermodynamic Properties of Adsorbed Mixtures of Benzene and Cyclohexane on Graphitized Carbon and Activated-Charocal at 30°C," AIChE J., 28, 97 (1982).
17. Myers, A. L., and J. M. Prausnitz, "Thermodynamics of Mixture-Gas Adsorption," AIChE J., 11, 121 (1965).
18. Myers, A. L., "Activity Coefficients of Mixtures Adsorbed on Heterogeneous Surfaces," AIChE J., 29, 691 (1983).
19. Myers, A. L., "New Technique for Rapid Measurements of Equilibrium Adsorption from Binary Gas Mixtures," Proc. World Cong. III Chem. Eng. (Sept., 1986).
20. Myers, A. L., Personal Correspondence between M. Sakuth and A. L. Myers (Personal Collection, D. Steffan) (1993).
21. Nye, P. H., Z. Gerstl, and Tz. Galin, "Prediction of Sorption by Soils of Volatile Hydrocarbon Mixtures," J. Environ. Qual., 23, 1031 (1994).
22. Sakuth, M., "Messung und Modellierung binaerer Adsorptionsgleichgewichte andealuminierten Y-Zeolithen," PhD Diss., University of Oldenburg, Germany (1993).
23. Steffan, D. G., and A. Akgerman, "Single-Component and Binary-Mixture Adsorption of Volatile Organic Contaminants on Silica Gel," Environm. Eng. Sci., 15, 191 (1998).
24. Steffan, D. G., "Multilayer Adsorption Equilibria of Volatile Organic Compound Mixtures and Water on Silica Gel," PhD Diss., Texas A&M Univ. (1999).
25. Talu, O., "Thermodynamics of Multicomponent Gas Adsorption Equilibria of Non-Ideal Mixtures," Diss., Arizona State Univ. (1984).
26. Talu, O., and I. Zwiebel, "Multicomponent Adsorption Equilibria of Nonideal Mixtures," AIChE J., 32, 1263 (1986).
27. Talu, O., and I. Zwiebel, "Spreading Pressure Dependent Equation for Adsorbate Phase Activity Coefficients," Reactive Poly., 5, 81 (1987).
28. Talu, O., and A. L. Myers, "Rigorous Thermodynamic Treatment of Gas Adsorption," AIChE J., 34, 1887 (1988).
29. Thibaud, C., C. Erkey, and A. Akgerman, "Investigation of Adsorption Equilibria of Volatile Organics on Soil by Frontal Analysis Chromatography," Environ. Sci. Technol., 26, 1189 (1992).
30. Thibaud, C., C. Erkey, and A. Akgerman, "Investigation of the Effect of Moisture on the Adsorption and Desorption of Chlorobenzene and Toluene from Soil," Environ. Sci. Technol., 27, 2373 (1993).
31. Trubnikov, I. B., and A. M. Tolmachev, "Sorption Thermodynamics - The Adsorption of Binary Mixtures of Hydrocarbon Vapors on NaX-Zeolites," Russ. J. Phys. Chem., 56, 189 (1982).
32. Worch, E., "Mixture Adsorption of Benzene and n-Hexane Vapors on Active Carbon," Chem. Techn., 34, 474 (1982).
33. Valenzuela, D. P., and A. L. Myers, Adsorption Equilibrium Data Handbook, Prentice Hall, Englewood Cliffs, NJ (1989).