Gas-phase adsorption and desorption of single-component and binary mixtures of volatile organic contaminants on soil

Environmental Engineering Science

Volumn 15, Issue 3, 1998, Pages 203-213

  Guo, Yang ^a   Thibaud Erkey, Catherine ^a   Akgerman, Aydin ^a  

^a Texas AandM University   (United States)

Author keywords

Adsorption; Desorption; Soil remediation; Volatile organic compounds

Indexed keywords

BINARY MIXTURES; CHLORINE COMPOUNDS; COMPOSITION EFFECTS; DESORPTION; GAS ADSORPTION; IMPURITIES; METHANOL; PARAFFINS; PRESSURE EFFECTS; REMEDIATION; TOLUENE; VOLATILE ORGANIC COMPOUNDS;

CHLOROBENZENE; FRONTAL ANALYSIS CHROMATOGRAPHY; IDEAL ADSORBED SOLUTION (IAS) THEORY; SOIL REMEDIATION;

SOIL POLLUTION CONTROL;

CHLOROBENZENE; HEXANE; METHANOL; TOLUENE; VOLATILE ORGANIC COMPOUND;

ADSORPTION; POLLUTANT; SOIL CHEMISTRY; VOLATILE ORGANIC COMPOUND;

ARTICLE; CHEMICAL ANALYSIS; DRUG ADSORPTION; SOIL POLLUTION; SOIL TREATMENT;

EID: 0031695481     PISSN: 10928758     EISSN: None     Source Type: Journal    
DOI: 10.1089/ees.1998.15.203     Document Type: Article

References (32)

1. AMALI, S., PETERSEN, L.W., and ROLSTON, D.E. (1994). Modeling multicomponent volatile organic and water vapor adsorption on soils. J. Hazard. Mater. 36, 89.
2. BARTON, A.F.M. (1975). Solubility parameters. Chem. Rev. 75, 731.
3. BRUNAUER, S., EMMETT, P.H., and TELLER, E.J. (1938). Adsorption of gases in multimolecular layers. J. Am. Chem. Soc. 60, 309.
4. BRUNAUER, S., DEMING, L.S., DEMING, W.E., and TELLER, E.J. (1940). On a theory of the van der Waals adsorption of gases. J. Am. Chem. Soc. 62, 1723.
5. CHIOU, C.T., KILE, D.E., and MALCOLM, R.L. (1988). Sorption of vapors of some organic liquids on soil humic acid and its relation to partitioning of organic components in soil organic matter. Environ. Sci. Technol. 22, 298.
6. FARRELL, J. and REINHARD, M. (1994a). Desorption of halogenated organics from model solids, sediments, and soil under unsaturated conditions. 2. Kinetics. Environ. Sci. Technol. 28, 63-72.
7. FARRELL, J. and REINHARD, H. (1994b). Desorption of halogenated organics from model solids, sediments, and soil under unsaturated conditions. 1. Isotherm. Environ. Sci. Technol. 28, 53-62.
8. GOSS, K.W. (1992). Effects of temperature and relative humidity on the sorption of organic vapors on quartz sands. Environ. Sci. Technol. 26, 2287.
9. GOSS, K.W. (1993). Effects of temperature and relative humidity on the sorption of organic vapors on clay minerals. Environ. Sci. Technol. 27, 2127.
10. LIN, T.F., LITTLE, J.C., and NAZAROFF, W.W. (1994). Transport and sorption of volatile organic compounds and water vapor within dry soil grains. Environ. Sci. Technol. 28, 322-330.
11. LIU, H., ZHANG, L., and SEATON, N.A. (1993a). Sorption hysteresis as a probe of pore structure. Langmuir 9, 2576-2582.
12. LIU, H., ZHANG, L., and SEATON, N.A. (1993b). Analysis of sorption hysteresis in mesoporous solids using a pore network model. J. Colloid Interface Sci. 156, 285-293.
13. O'NEILL, M.W., SYMONS, J.M., LAZARIDOU, M.E., and PARK, J.B. (1993). In situ treatment of soil for the extraction of organic contaminants. Environ. Prog. 12, 12.
14. ONG, S.K. and LION, L.W. (1991). Mechanisms for trichloroethylene vapor sorption onto soil minerals. J. Environ. Qual. 20, 180.
15. ORCHISTON, H.D. (1954). Adsorption of water vapors: II. Clays at 25°C. Soil Sci. 78, 463.
16. PENNELL, K.D., RHUE, R.D., RAO, P.S.C., and JOHNSTON, C.T. (1992a). Vapor-phase sorption of p-xylene and water on soils and clay minerals. Environ. Sci. Technol. 26, 756.
17. PENNELL, K.D., RHUE, R.D., and HORNSBY, A.G. (1992b). Competitive adsorption of para-xylene and water vapors on calcium, sodium, and lithium-saturated kaolinite. J. Environ. Qual. 21, 419.
18. PRAUSNITZ, J.M. and MYERS, A.L. (1965). Thermodynamics of mixed-gas adsorption. AIChE J. 11, 121.
19. RAJNIAK, P. and YANG, R.T. (1993). A simple model and experiments for adsorption-desorption hysteresis: Water vapor on silica gel. AIChE J. 39, 774-786.
20. RAO, K.S. (1941a). Hysteresis in sorption II. Scanning of the hysteresis loop: Titania gel-water system, J. Phys. Chem. 45, 506-512.
21. RAO, K.S. (1941b). Hysteresis in sorption III. Permanerce and scanning of the hysteresis loop: Silica gel-water system. J. Phys. Chem. 45, 513-517.
22. RAO, K.S. (1941c). Hysteresis in sorption IV. Disappearance of the hysteresis loop: Titania gel-water system. J. Phys. Chem. 45, 531-539.
23. RAO, K.S. (1941d). J. Phys. Chem. 45, 517-521.
24. RHUE, R.D., PENNELL, K.D., RAO, P.S.C., and REVE, W.H. (1989). Competitive adsorption of alkylbenzene and water vapors on predominantly mineral surfaces. Chemosphere 18, 1971.
25. RHUE, R.D., PENNELL, K.D., REVE, W.H., and HORNSBY, A.G. (1993). Sorption of para-xylene vapors on salt-treated soils measured by flow-equilibration and gas chromatography methods. J. Environ. Qual. 22, 521.
26. RITTER, J.A. and YANG, R.T. (1991). Equilibrium theory for hysteresis-dependent fixed-bed desorption. Chem. Eng. Sci. 46, 563-574.
27. THIBAUD, C., ERKEY, C., and AKGERMAN, A. (1992). Investigation of adsorption equilibria of volatile organics on soil by frontal analysis chromatography. Environ. Sci. Technol. 26, 1159.
28. THIBAUD, C., ERKEY, C., and AKGERMAN, A. (1993). Investigation of the effect of moisture on the sorption and desorption of chlorobenzene and toluene from soil. Environ. Sci. Technol. 27, 2373-2380.
29. THIBAUD-ERKEY, C., CAMPAGNOLO, J.F., and AKGERMAN, A. (1995). Adsorption of volatile organic contaminants on soil and soil constituents. Separat. Purificat. 24, 129-194.
30. THIBAUD-ERKEY, C., GUO, Y., ERKEY, C., and AKGERMAN, A. (1996). Mathematical modeling of adsorption and desorption of volatile contaminants from soil: Influence of isotherm shape on adsorption and desorption profiles. Environ. Sci. Technol. 30, 2127-2134.
31. THIBODEAUX, L.J., NADLER, K.C., VALSARAJ, K.T., and REIBLE, D.D. (1991). The effect of moisture on volatile organic chemical gas-to-particle partitioning with atmospheric aerosols-competitive adsorption theory predictions. Atmospheric Environ. 25A, 1649.
32. THOMS, S.R. and LION, L.W. (1992). Competition and enhancement of VOC sorption at low sorbent moisture contents. Chemosphere 25, 1707.