메뉴 건너뛰기




Volumn 114, Issue 1, 2001, Pages 250-261

Spectroscopic signatures of bond-breaking internal rotation. I. Saddle point induced polyad breakdown

Author keywords

[No Author keywords available]

Indexed keywords

ISOMERIZATION; MOLECULAR SPECTROSCOPY; MOLECULAR VIBRATIONS; QUANTUM THEORY;

EID: 0035148674     PISSN: 00219606     EISSN: None     Source Type: Journal    
DOI: 10.1063/1.1330238     Document Type: Article
Times cited : (23)

References (49)
  • 29
    • 0343745728 scopus 로고    scopus 로고
    • note
    • A semiclassical treatment of barrier tunneling (EB) provides a somewhat more sophisticated means of quantifying the "isomerization rate" for the zero-order basis functions and eigenstates. We have pursued such an approach but do not report it here, however, because the transmission probability of a wave approaching the barrier rises very rapidly from 0 to 1 at E≈B.
  • 31
    • 0004190360 scopus 로고
    • Princeton University Press, Princeton, New Jersey
    • J. Milnor, Morse Theory (Princeton University Press, Princeton, New Jersey, 1963).
    • (1963) Morse Theory
    • Milnor, J.1
  • 42
    • 0342440476 scopus 로고    scopus 로고
    • note
    • φ does not enter into the Hamiltonian at all. Here we focus exclusively on k = 0.
  • 43
    • 0342874987 scopus 로고    scopus 로고
    • note
    • b.
  • 46
    • 0342440474 scopus 로고    scopus 로고
    • note
    • 2,0) and were originally, erroneously, thought to be "pure bending" eigenstates (Ref. 23).
  • 48
    • 0343310052 scopus 로고    scopus 로고
    • note
    • 1.


* 이 정보는 Elsevier사의 SCOPUS DB에서 KISTI가 분석하여 추출한 것입니다.