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14344269448
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See Supporting Information for full experimental details
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See Supporting Information for full experimental details.
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37
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14344267665
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note
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This might also explain the rather polydisperse particle size distribution observed in this particular experiment.
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38
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14344278064
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note
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2/g) because of the low median pore diameter (40 nm).
-
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39
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14344284637
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note
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2 pressure is increased, as evident from the variation in pore size in samples 3-5. Thus, the molar ratio of monomer to porogen varies significantly from experiment to experiment while the volumetric ratio does not because the reactions are carried out in a sealed vessel of fixed volume. This is an unusual feature of polymerization reactions conducted using compressible supercritical fluid solvents.
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