Kinetics and mechanism of water substitution at half-sandwich iridium(III) aqua cations Cp*Ir(A-B)(H2O)2+/+ in aqueous solution (Cp* = η5-pentamethylcyclopentadienyl anion; A-B = bidentate N9N or N,O ligand)

European Journal of Inorganic Chemistry

Volumn , Issue 5, 2001, Pages 1361-1369

  Poth, Tilo ^a   Paulus, Helmut ^a   Elias, Horst ^a   Dücker Benfer, Carlos ^b   Van Eldik, Rudi ^b  

^a DARMSTADT UNIVERSITY OF TECHNOLOGY   (Germany)

^b UNIVERSITY OF ERLANGEN NUREMBERG   (Germany)

Author keywords

Iridium; Kinetics; N ligands; Reaction mechanisms; Sandwich complexes

Indexed keywords

DISSOCIATION; INORGANIC COMPOUNDS; IRIDIUM; IRIDIUM COMPOUNDS; KINETICS; LIGANDS; PYRIDINE; REACTION KINETICS; SULFUR COMPOUNDS;

ACID ANIONS; BIPYRIDINES; HALF-SANDWICH; N LIGANDS; N-LIGANDS; PENTAMETHYLCYCLOPENTADIENYL; PICOLINIC ACID; REACTION MECHANISM; SANDWICH COMPLEXES; X RAY STRUCTURE ANALYSIS; COORDINATED WATER;

POSITIVE IONS;

ANION; IRIDIUM; LIGAND; NITROGEN; PERCHLORATE; WATER;

AQUEOUS SOLUTION; ARTICLE; CHEMICAL REACTION KINETICS; CHEMICAL STRUCTURE; COMPLEX FORMATION; DISSOCIATION; GEOMETRY; MATHEMATICAL ANALYSIS; STRUCTURE ANALYSIS; X RAY ANALYSIS;

EID: 0035041833     PISSN: 14341948     EISSN: None     Source Type: Journal    
DOI: 10.1002/1099-0682(200105)2001:5<1361::AID-EJIC1361>3.0.CO;2-M     Document Type: Article

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