메뉴 건너뛰기




Volumn 86, Issue 4, 2001, Pages 438-447

Thermodynamics of ion-exchange and natural clinoptilolite

Author keywords

[No Author keywords available]

Indexed keywords

ATOMS; CALORIMETRY; DEHYDRATION; ENTHALPY; FREE ENERGY; HIGH TEMPERATURE EFFECTS; HYDRATION; POSITIVE IONS; ZEOLITES;

EID: 0034996490     PISSN: 0003004X     EISSN: None     Source Type: Journal    
DOI: 10.2138/am-2001-0407     Document Type: Article
Times cited : (28)

References (56)
  • 3
    • 0001387860 scopus 로고
    • Polymorphism and crystal-chemistry of heulandites and clinoptilolites
    • Alietti, A. (1972) Polymorphism and crystal-chemistry of heulandites and clinoptilolites. American Mineralogist, 57, 1448-1462.
    • (1972) American Mineralogist , vol.57 , pp. 1448-1462
    • Alietti, A.1
  • 4
    • 0027470602 scopus 로고
    • Dehydration mechanism of clinoptilolite and heulandite: Single crystal X-ray study of Na-poor, Ca-, K-, Mg-rich clinoptilolite at 100 K
    • Armbruster, T. (1993) Dehydration mechanism of clinoptilolite and heulandite: Single crystal X-ray study of Na-poor, Ca-, K-, Mg-rich clinoptilolite at 100 K. American Mineralogist, 78, 260-264.
    • (1993) American Mineralogist , vol.78 , pp. 260-264
    • Armbruster, T.1
  • 5
    • 0026306799 scopus 로고
    • Stepwise dehydration of heulandite-clinoptilolite from Succor Creek, Oregon, U.S.A.: A single-crystal x-ray study at 100 K
    • Armbruster, T. and Gunter, M.E. (1991) Stepwise dehydration of heulandite-clinoptilolite from Succor Creek, Oregon, U.S.A.: a single-crystal x-ray study at 100 K. American Mineralogist, 76, 1872-1883.
    • (1991) American Mineralogist , vol.76 , pp. 1872-1883
    • Armbruster, T.1    Gunter, M.E.2
  • 6
    • 0004833235 scopus 로고
    • Heats of immersion of outgassed and ion-exchanged zeolites
    • E.M.Flanigen and L.B. Sand, Eds. American Chemistry Society, Washington, D.C.
    • Barrer, R.M. and Cram, P.J. (1971) Heats of immersion of outgassed and ion-exchanged zeolites. In E.M.Flanigen and L.B. Sand, Eds., Molecular sieve zeolites - II, p. 105-131. American Chemistry Society, Washington, D.C.
    • (1971) Molecular Sieve Zeolites - II , pp. 105-131
    • Barrer, R.M.1    Cram, P.J.2
  • 7
    • 0034054052 scopus 로고    scopus 로고
    • Solubility and stability of zeolites in aqueous solution: II. Calcic clinoptilolite and mordenite
    • Benning, L.G., Wilkin, R.T., and Barnes, H.L. (2000) Solubility and stability of zeolites in aqueous solution: II. Calcic clinoptilolite and mordenite. American Mineralogist, 85, 495-508.
    • (2000) American Mineralogist , vol.85 , pp. 495-508
    • Benning, L.G.1    Wilkin, R.T.2    Barnes, H.L.3
  • 8
    • 0000481128 scopus 로고
    • Composition, optical properties, cell dimensions, and thermal stability of some heulandite group zeolites
    • Boles, J.R. (1972) Composition, optical properties, cell dimensions, and thermal stability of some heulandite group zeolites. American Mineralogist, 57, 1463-1493.
    • (1972) American Mineralogist , vol.57 , pp. 1463-1493
    • Boles, J.R.1
  • 9
    • 0025692838 scopus 로고
    • Activity diagrams for clinoptilolite: Susceptibility of this zeolite to further diagenetic reactions
    • Bowers, T.S. and Burns, R.G. (1990) Activity diagrams for clinoptilolite: Susceptibility of this zeolite to further diagenetic reactions. American Mineralogist, 75, 601-619.
    • (1990) American Mineralogist , vol.75 , pp. 601-619
    • Bowers, T.S.1    Burns, R.G.2
  • 11
    • 0031433802 scopus 로고    scopus 로고
    • Calorimetric measurement of the enthalpy of hydration of clinoptilolite
    • _ (1997) Calorimetric measurement of the enthalpy of hydration of clinoptilolite. Clays and Clay Minerals, 45(6), 826-833.
    • (1997) Clays and Clay Minerals , vol.45 , Issue.6 , pp. 826-833
  • 12
    • 0024879754 scopus 로고
    • 0) of silicate minerals at 298 K from the sum of polyhedral contributions
    • 0) of silicate minerals at 298 K from the sum of polyhedral contributions. American Mineralogist, 74, 1023-1031.
    • (1989) American Mineralogist , vol.74 , pp. 1023-1031
    • Chermak, J.A.1    Rimstidt, J.D.2
  • 13
    • 0020646713 scopus 로고
    • Synthesis of Na- and K-clinoptilolite end members
    • Chi, C. and Sand, L.B. (1983) Synthesis of Na- and K-clinoptilolite end members. Nature, 304, 255-257.
    • (1983) Nature , vol.304 , pp. 255-257
    • Chi, C.1    Sand, L.B.2
  • 14
    • 0031122680 scopus 로고    scopus 로고
    • Equilibrium modeling of clinoptilolite-analcime equilibria at Yucca Mountain, Nevada, USA
    • Chipera, S.J. and Bish, D.L. (1997) Equilibrium modeling of clinoptilolite-analcime equilibria at Yucca Mountain, Nevada, USA. Clays and Clay Minerals, 45(2), 226-239.
    • (1997) Clays and Clay Minerals , vol.45 , Issue.2 , pp. 226-239
    • Chipera, S.J.1    Bish, D.L.2
  • 17
    • 0001566583 scopus 로고    scopus 로고
    • Cation diffusion in the natural zeolite clinoptilolite
    • Dyer, A. and White, K.J. (1999) Cation diffusion in the natural zeolite clinoptilolite. Thermochimica Acta, 340-341, 341-348.
    • (1999) Thermochimica Acta , vol.340-341 , pp. 341-348
    • Dyer, A.1    White, K.J.2
  • 18
    • 0028197845 scopus 로고
    • Testing long-term predictions from hydro-geochemical models
    • Scientific Basis for Nuclear Waste Management XVII
    • Glassley, W.E., Bruton, C.J., and Bourcier, W.L. (1994) Testing long-term predictions from hydro-geochemical models. Materials Research Society symposium proceedings, 333 (Scientific Basis for Nuclear Waste Management XVII), 805-810.
    • (1994) Materials Research Society Symposium Proceedings , vol.333 , pp. 805-810
    • Glassley, W.E.1    Bruton, C.J.2    Bourcier, W.L.3
  • 20
    • 0021476654 scopus 로고
    • Neutron diffraction studies on natural heulandite and partially dehydrated heulandite
    • Hambley, T.W. and Taylor, J.C. (1984) Neutron diffraction studies on natural heulandite and partially dehydrated heulandite. Journal of Solid State Chemistry, 54, 1-9.
    • (1984) Journal of Solid State Chemistry , vol.54 , pp. 1-9
    • Hambley, T.W.1    Taylor, J.C.2
  • 21
    • 0021460501 scopus 로고
    • Thermodynamics properties of zeolites: Low temperature heat capacities and thermodynamic functions of phillipsite and clinoptilolite. Estimates of the thermodynamical properties of zeolitic water at low temperature
    • Hemingway, B.S. and Robie, R.A. (1984) Thermodynamics properties of zeolites: Low temperature heat capacities and thermodynamic functions of phillipsite and clinoptilolite. Estimates of the thermodynamical properties of zeolitic water at low temperature. American Mineralogist, 69, 692-700.
    • (1984) American Mineralogist , vol.69 , pp. 692-700
    • Hemingway, B.S.1    Robie, R.A.2
  • 24
    • 0034724724 scopus 로고    scopus 로고
    • Nuclear waste disposal: Science and policy clash at Yucca Mountain
    • Kerr, R. A. (2000) Nuclear waste disposal: Science and policy clash at Yucca Mountain. Science, 288, 602.
    • (2000) Science , vol.288 , pp. 602
    • Kerr, R.A.1
  • 26
    • 0030479403 scopus 로고    scopus 로고
    • Thermochemistry and phase equilibria of natural potassium sodium calcium leonhardite and its cation-exchanged forms
    • _ (1996b) Thermochemistry and phase equilibria of natural potassium sodium calcium leonhardite and its cation-exchanged forms. American Mineralogist, 81, 668-675.
    • (1996) American Mineralogist , vol.81 , pp. 668-675
  • 27
    • 0035006217 scopus 로고    scopus 로고
    • Thermochemical study of calcium zeolites - Heulandite and stilbite
    • _ (2000) Thermochemical study of calcium zeolites - heulandite and stilbite. American Mineralogist, 86, 448-455.
    • (2000) American Mineralogist , vol.86 , pp. 448-455
  • 28
    • 84955870048 scopus 로고
    • Clinoptilolite: The distribution of potassium atoms and its role in thermal stability
    • Koyama, K. and Takéuchi., Y. (1977) Clinoptilolite: The distribution of potassium atoms and its role in thermal stability. Zeitschrift für Kristallographie, 145, 216-239.
    • (1977) Zeitschrift für Kristallographie , vol.145 , pp. 216-239
    • Koyama, K.1    Takéuchi, Y.2
  • 29
    • 0024928141 scopus 로고
    • Hydration and dehydration of zeolitic tuff from Yucca Mountain, Nevada
    • Kranz, R.L., Bish, D.L., and Blacic J.D. (1989) Hydration and dehydration of zeolitic tuff from Yucca Mountain, Nevada. Geophysical Research Letters, 16(10), 1113-1116.
    • (1989) Geophysical Research Letters , vol.16 , Issue.10 , pp. 1113-1116
    • Kranz, R.L.1    Bish, D.L.2    Blacic, J.D.3
  • 30
    • 0038934698 scopus 로고
    • A method of estimating the Gibbs energies of formation of zeolites
    • La Iglesia, A. and Aznar, A. J. (1986) A method of estimating the Gibbs energies of formation of zeolites. Zeolites, 6, 26-29.
    • (1986) Zeolites , vol.6 , pp. 26-29
    • La Iglesia, A.1    Aznar, A.J.2
  • 31
    • 0010628663 scopus 로고
    • Clinoptilolite from Patagonia: The relationship between clinoptilolite and heulandite
    • Mason, B. and Sand, L.B. (1960) Clinoptilolite from Patagonia: The relationship between clinoptilolite and heulandite. American Mineralogist, 45, 341-350.
    • (1960) American Mineralogist , vol.45 , pp. 341-350
    • Mason, B.1    Sand, L.B.2
  • 32
    • 0032715613 scopus 로고    scopus 로고
    • Estimating the standard free energy of formation of zeolites using the polymer model
    • Mattigod, S.V. and McGrail, B.P. (1999) Estimating the standard free energy of formation of zeolites using the polymer model. Microporous Mesoporous Materials, 27, 41-47.
    • (1999) Microporous Mesoporous Materials , vol.27 , pp. 41-47
    • Mattigod, S.V.1    McGrail, B.P.2
  • 33
    • 0000424445 scopus 로고
    • Determination and refinement of the structure of heulandite
    • Merkle, A.B. and Slaughter, M. (1968) Determination and refinement of the structure of heulandite. American Mineralogist, 53, 1120-1138.
    • (1968) American Mineralogist , vol.53 , pp. 1120-1138
    • Merkle, A.B.1    Slaughter, M.2
  • 34
    • 0000271125 scopus 로고
    • Clinoptilolite redefined
    • Mumpton, F.A. (1960) Clinoptilolite redefined. American Mineralogist, 45, 351-369.
    • (1960) American Mineralogist , vol.45 , pp. 351-369
    • Mumpton, F.A.1
  • 35
    • 0001635805 scopus 로고    scopus 로고
    • Reaction kinetics and thermodynamics of aqueous dissolution and growth of analcime and Na-clinoptilolite at 25 °C
    • Murphy, W.M., Pabalan, R.T., Prikryl, J.D., and Goulei, C.J. (1996) Reaction kinetics and thermodynamics of aqueous dissolution and growth of analcime and Na-clinoptilolite at 25 °C. American Journal of Science, 296, 128-186.
    • (1996) American Journal of Science , vol.296 , pp. 128-186
    • Murphy, W.M.1    Pabalan, R.T.2    Prikryl, J.D.3    Goulei, C.J.4
  • 36
    • 0028668404 scopus 로고
    • Repeating patterns in mineral energetics
    • Navrotsky, A. (1994) Repeating patterns in mineral energetics. American Mineralogist, 791, 589-605.
    • (1994) American Mineralogist , vol.791 , pp. 589-605
    • Navrotsky, A.1
  • 37
    • 0030772474 scopus 로고    scopus 로고
    • Progress and new directions in high temperature calorimetry revisited
    • _ (1997) Progress and new directions in high temperature calorimetry revisited. Physics and Chemistry of Minerals, 24, 222-241.
    • (1997) Physics and Chemistry of Minerals , vol.24 , pp. 222-241
  • 39
    • 0019923370 scopus 로고
    • A thermodynamical study of glasses along the joins silica-calcium aluminate and silica-sodium aluminate
    • Navrotsky, A., Peraudeau, G., McMillan, P., and Coutures, J.P. (1982) A thermodynamical study of glasses along the joins silica-calcium aluminate and silica-sodium aluminate. Geochimica et Cosmochimica Acta, 46, 2039-2047.
    • (1982) Geochimica et Cosmochimica Acta , vol.46 , pp. 2039-2047
    • Navrotsky, A.1    Peraudeau, G.2    McMillan, P.3    Coutures, J.P.4
  • 40
    • 0001034383 scopus 로고
    • Thermodynamical approximations for clay minerals
    • Nriagu, J.O. (1975) Thermodynamical approximations for clay minerals. American Mineralogist, 60, 834-839.
    • (1975) American Mineralogist , vol.60 , pp. 834-839
    • Nriagu, J.O.1
  • 41
    • 0033112557 scopus 로고    scopus 로고
    • Experimental and modeling study of ion exchange between aqueous solutions and the zeolite mineral clinoptilolite
    • Pabalan, R.T. and Bertetti, F.P. (1999) Experimental and modeling study of ion exchange between aqueous solutions and the zeolite mineral clinoptilolite. Journal of Solution Chemistry, 28(4), 367-393.
    • (1999) Journal of Solution Chemistry , vol.28 , Issue.4 , pp. 367-393
    • Pabalan, R.T.1    Bertetti, F.P.2
  • 42
    • 0029203887 scopus 로고
    • Heats of immersion of clinoptilolite and its ion-exchanged forms: A calorimetric study
    • Petrova, N. and Kirov, D. (1995) Heats of immersion of clinoptilolite and its ion-exchanged forms: A calorimetric study. Journal of Thermal Analysis, 43, 323-328.
    • (1995) Journal of Thermal Analysis , vol.43 , pp. 323-328
    • Petrova, N.1    Kirov, D.2
  • 43
    • 0031099567 scopus 로고    scopus 로고
    • Thermochemistry of Na-faujasites with varying Si/Al ratios
    • Petrovic, I. and Navrotsky, A. (1997) Thermochemistry of Na-faujasites with varying Si/Al ratios. Microporous Materials, 9, 1-12.
    • (1997) Microporous Materials , vol.9 , pp. 1-12
    • Petrovic, I.1    Navrotsky, A.2
  • 44
    • 0029512134 scopus 로고
    • Thermodynamics properties of minerals and related substances at 298.15K and 1 bar (105 pascals) pressure and at higher temperatures
    • Robie, R. A. and Hemingway, B.S. (1995) Thermodynamics properties of minerals and related substances at 298.15K and 1 bar (105 pascals) pressure and at higher temperatures. U.S. Geological Survey Bulletin, 2131.
    • (1995) U.S. Geological Survey Bulletin , pp. 2131
    • Robie, R.A.1    Hemingway, B.S.2
  • 45
    • 0030736186 scopus 로고    scopus 로고
    • Crystallization of single phase (K, Na)-clinoptilolite
    • Satokawa, S. and Itabashi, K. (1997) Crystallization of single phase (K, Na)-clinoptilolite. Microporous Materials, 8, 49-55.
    • (1997) Microporous Materials , vol.8 , pp. 49-55
    • Satokawa, S.1    Itabashi, K.2
  • 46
    • 0028669516 scopus 로고
    • A calorimetric study of synthetic amphiboles along the tremolite-tschermakite join and the heats of formation of magnesio-hornblende and tschermakite
    • Smelik, E.A., Jenkins, D.M., and Navrotsky, A. (1994) A calorimetric study of synthetic amphiboles along the tremolite-tschermakite join and the heats of formation of magnesio-hornblende and tschermakite. American Mineralogist, 79, 1110-1122.
    • (1994) American Mineralogist , vol.79 , pp. 1110-1122
    • Smelik, E.A.1    Jenkins, D.M.2    Navrotsky, A.3
  • 47
    • 0033367583 scopus 로고    scopus 로고
    • Chabazite: Energetics of hydration, enthalpy of formation, and effect of cations on stability
    • Shim, S.H., Navrotsky, A., Gaffney, T.R., and MacDougall, J.E. (1999) Chabazite: Energetics of hydration, enthalpy of formation, and effect of cations on stability. American Mineralogist, 84, 1870-1882.
    • (1999) American Mineralogist , vol.84 , pp. 1870-1882
    • Shim, S.H.1    Navrotsky, A.2    Gaffney, T.R.3    MacDougall, J.E.4
  • 48
    • 0001445848 scopus 로고
    • A method of estimating the Gibbs energies of formation of layer silicates
    • Tardy, Y. and Garrels, R.M. (1974) ) A method of estimating the Gibbs energies of formation of layer silicates. Geochimica et Cosmochimica Acta, 38, 1101-1116.
    • (1974) Geochimica et Cosmochimica Acta , vol.38 , pp. 1101-1116
    • Tardy, Y.1    Garrels, R.M.2
  • 49
    • 0029536961 scopus 로고
    • Dehydration behavior of heulandite-group zeolites as a function of their chemical composition
    • Valueva, G. (1995) Dehydration behavior of heulandite-group zeolites as a function of their chemical composition. European Journal of Mineralogy, 7(6), 1411-1420.
    • (1995) European Journal of Mineralogy , vol.7 , Issue.6 , pp. 1411-1420
    • Valueva, G.1
  • 50
    • 0031798164 scopus 로고    scopus 로고
    • Solubility and stability of zeolites in aqueous solution: I. Analcime, Na-, and K-clinoptilolite
    • Wilkin, R.T. and Barnes H.L. (1998) Solubility and stability of zeolites in aqueous solution: I. Analcime, Na-, and K-clinoptilolite. American Mineralogist, 83, 746-761.
    • (1998) American Mineralogist , vol.83 , pp. 746-761
    • Wilkin, R.T.1    Barnes, H.L.2
  • 51
    • 0032707569 scopus 로고    scopus 로고
    • Thermodynamics of hydration of Na- and K-clinoptilolite to 300 °C
    • _ (1999) Thermodynamics of hydration of Na- and K-clinoptilolite to 300 °C. Physics and Chemistry of Minerals, 26, 468-476.
    • (1999) Physics and Chemistry of Minerals , vol.26 , pp. 468-476
  • 52
    • 0000114244 scopus 로고    scopus 로고
    • Na, K, Rb, and Cs exchange in heulandite single-crystals: X-ray structure refinements at 100 K
    • Yang, P. and Armbruster, T. (1996) Na, K, Rb, and Cs exchange in heulandite single-crystals: X-ray structure refinements at 100 K. Journal of Solid State Chemistry, 123, 140-149.
    • (1996) Journal of Solid State Chemistry , vol.123 , pp. 140-149
    • Yang, P.1    Armbruster, T.2
  • 53
    • 0030778581 scopus 로고    scopus 로고
    • Na, K, Rb, and Cs exchange in heulandite single-crystals: Diffusion kinetics
    • Yang, P., Stolz, J., Armbruster, T., and Gunter, M.E. (1997) Na, K, Rb, and Cs exchange in heulandite single-crystals: Diffusion kinetics. American Mineralogist, 82, 517-525.
    • (1997) American Mineralogist , vol.82 , pp. 517-525
    • Yang, P.1    Stolz, J.2    Armbruster, T.3    Gunter, M.E.4
  • 54
    • 0034079441 scopus 로고    scopus 로고
    • Energetics of formation and hydration of ion exchanged zeolite Y
    • Yang, S. and Navrotsky, A. (2000) Energetics of Formation and Hydration of Ion Exchanged Zeolite Y. Microporous and Mesoporous Materials, 37, 175-186.
    • (2000) Microporous and Mesoporous Materials , vol.37 , pp. 175-186
    • Yang, S.1    Navrotsky, A.2
  • 55
    • 0031551256 scopus 로고    scopus 로고
    • Electron spin resonance and electron spin echo modulation spectroscopic studies of cupric ion-adsorbate interactions in synthetic clinoptilolite
    • Zhao, D., Szostak, R., and Kevan, L. (1997) Electron Spin Resonance and Electron Spin Echo Modulation Spectroscopic Studies of Cupric Ion-Adsorbate Interactions in Synthetic Clinoptilolite. The Journal of Physical Chemistry B, 101, 5382-5390.
    • (1997) The Journal of Physical Chemistry B , vol.101 , pp. 5382-5390
    • Zhao, D.1    Szostak, R.2    Kevan, L.3


* 이 정보는 Elsevier사의 SCOPUS DB에서 KISTI가 분석하여 추출한 것입니다.