Equilibrium in the clinoptilolite-H2O system

American Mineralogist

Volumn 81, Issue 7-8, 1996, Pages 952-962

  Carey, J William ^a   Bish, David L ^a  

^a LOS ALAMOS NATIONAL LABORATORY   (United States)

Author keywords

[No Author keywords available]

Indexed keywords

FREE ENERGY; GIBBS FREE ENERGY; HYDRATION; HYDROSTATIC PRESSURE; ION EXCHANGE; THERMOGRAVIMETRIC ANALYSIS;

ANHYDROUS MINERALS; EQUILIBRIUM DATA; FREE ENERGY OF HYDRATION; MIXING PARAMETERS; NATURAL CLINOPTILOLITE; TEMPERATURE AND PRESSURES; THERMODYNAMIC FORMULATION; YUCCA MOUNTAIN , NEVADA;

ZEOLITES;

CLINOPTILOLITE; EQUILIBRIUM; SORPTION; THERMODYNAMICS; WATER;

USA, NEVADA, FISH CREEK MOUNTAINS;

EID: 0030464518     PISSN: 0003004X     EISSN: None     Source Type: Journal    
DOI: 10.2138/am-1996-7-817     Document Type: Review

References (21)

1. Alberti, A. (1975) The crystal structure of two clinoptilolites. Tschermaks Mineralogische und Petrographische Mitteilungen, 22, 25-37.
2. Armbruster, T., and Gunter, M.E. (1991) Stepwise dehydration of heulandite-clinoptilolite from Succor Creek, Oregon, U.S.A.: A single-crystal X-ray study at 100 K. American Mineralogist, 76, 1872-1883.
3. Barrer, R.M. (1978) Zeolites and clay minerals as sorbents and molecular sieves, 497 p. Academic, London, U.K.
4. Barrer, R.M., and Fender, B.E.F. (1961) The diffusion and sorption of water in zeolites: II. Sorption. Journal of the Physics and Chemistry of Solids, 21, 1-11.
5. Barrer, R.M., and Davies, J.A. (1970) Sorption in decationated zeolites: I. Gases in hydrogen chabazite. Proceedings of the Royal Society of London, A320, 289-308.
6. Barrer, R.M., and Cram, P.J. (1971) Heats of immersion of outgassed and ion-exchanged zeolites. In E.M. Flanigen and L.B. Sand, Eds., Molecular sieve zeolites (vol. II), p. 105-131. American Chemical Society, Washington, DC.
7. Bish, D.L. (1984) Effects of exchangeable cation composition on the thermal expansion/contraction of clinoptilolite. Clays and Clay Minerals, 32, 444-452.
8. _ (1990) Long-term thermal stability of clinoptilolite: The development of a "B" phase. European Journal of Mineralogy, 2, 771-777.
9. Carey, J.W. (1993) The heat capacity of hydrous cordierite above 295 K. Physics and Chemistry of Minerals, 19, 578-583.
10. _ (1995) A thermodynamic formulation of hydrous cordierite. Contributions to Mineralogy and Petrology, 119, 155-165.
11. Carey, J.W., and Navrotsky, A. (1992) The molar enthalpy of dehydration of cordierite. American Mineralogist, 77, 930-936.
12. Chipera, S.J., Guthrie, G.D., Jr., and Bish, D.L. (1993) Preparation and purification of mineral dusts. In G.D. Guthrie, Jr. and B.T. Mossman, Eds., Health effects of mineral dusts, p. 235-249. Mineralogical Society of America, Washington, DC.
13. Gottardi, G., and Galli, E. (1985) Natural zeolites, 409 p. Springer-Verlag, Berlin.
14. Haar, L., Gallagher, J.S., and Kell, G.S. (1984) NBS/NRC steam tables: Thermodynamic and transport properties and computer programs for vapor and liquid states of water in SI units, 320 p. Hemisphere Publishing, Washington, DC.
15. Johnson, G.K., Flotow, H.E., O'Hare, P.A.G., and Wise, W.S. (1982) Thermodynamic studies of zeolites: Analcime and dehydrated analcime. American Mineralogist 67, 736-748.
16. Johnson, G.K., Tasker, I.R., Jurgens, R., and O'Hare, P.A.G. (1991) Thermodynamic studies of zeolites: Clinoptilolite. Journal of Chemical Thermodynamics, 23, 475-484.
17. Johnson, G.K., Tasker, I.R., Flotow, H.E., O'Hare, P.A.G., and Wise, W.S. (1992) Thermodynamic studies of mordenite, dehydrated mordenite, and gibbsite. American Mineralogist, 77, 85-93.
18. 5 Pascals) pressure and at higher temperature, 456 p. U.S. Geological Survey Bulletin, 1452.
19. Simonot-Grange, M.H. (1979) Thermodynamic and structural features of water sorption in zeolites. Clays and Clay Minerals, 27, 423-428.
20. Thompson, J.B., Jr. (1967) Thermodynamic properties of simple solutions. In P.H. Abelson, Ed., Researches in geochemistry (vol. II), p. 340-361. Wiley, New York.
21. Yamanaka, S., Malla, P.B., and Komameni, S. (1989) Water sorption and desorption isotherms of some naturally occurring zeolites. Zeolites, 9, 18-22.