Elucidating the fundamental chemistry of soils: Past and recent achievements and future frontiers

Geoderma

Volumn 100, Issue 3-4, 2001, Pages 303-319

  Sparks, Donald L ^a  

^a UNIVERSITY OF DELAWARE   (United States)

Author keywords

Frontiers in soil chemistry; History of soil chemistry

Indexed keywords

HISTORICAL PERSPECTIVE; SOIL CHEMISTRY;

EID: 0034987859     PISSN: 00167061     EISSN: None     Source Type: Journal    
DOI: 10.1016/S0016-7061(01)00026-X     Document Type: Article

References (125)

1. Cobalt, cadmium, and lead sorption to hydrous iron oxide: Residence time effect
2. Methods of obtaining and analyzing kinetic data
3. Thermodynamics and ion exchange phenomena
4. Long-term sorption of halogenated organic chemicals by aquifer material: 1. Equilibrium
5. Aluminum
6. Testing a mechanistic model: II. The effects of time and temperature on the reaction of zinc with a soil
7. Effects of time and temperature on the sorption of cadmium, zinc, cobalt, and nickel by a soil
8. An objective method for fitting models of ion adsorption on variable charge surfaces
9. Describing the adsorption of copper, zinc and lead on a variable charge mineral surface
10. Reaction kinetics of the adsorption and desorption of nickel, zinc and cadmium by goethite: II. Modeling the extent and rate of reaction
11. Behavior of chromium in soils: III. Oxidation
12. Redox chemistry of soils
13. Speciation, spatial distribution and phase association of chemical contaminants
14. Kinetics of dissolution of oxide and primary silicate minerals
15. Ion adsorption on inorganic variable charge constituents
16. Ionic adsorption on variable charge mineral surfaces. Theoretical charge development and titration curves
17. Describing the adsorption of phosphate, citrate and selenite on a variable charge mineral surface
18. The exchange adsorption of ions from aqueous solutions by organic zeolites: II. Kinetics
19. Reaction kinetics of the adsorption and desorption of nickel, zinc and cadmium by goethite: I. Adsorption and diffusion of metals
20. X-ray absorption spectroscopic study of the sorption of Cr(III) at the oxide-water interface: II. Adsorption, coprecipitation and surface precipitation on ferric hydrous oxides
21. Evidence for multinuclear metal-ion complexes at solid/water interfaces from X-ray absorption spectroscopy
22. 3/water interface
23. Surface complexation modeling in aqueous geochemistry
24. Surface ionization and complexation at the oxide/water interface: II. Surface properties of amorphous iron oxyhyroxide and adsorption of metal ions
25. Surface ionization and complexation at the oxide/water interface: III. Adsorption of anions
26. Surface complexation modeling
27. A surface precipitation model for the sorption of cations on metal oxides
28. 2: I. Characterization
29. 2
30. Applications of X-ray absorption fine structure spectroscopy to soils
31. Mechanisms of chromium (III) sorption on silica: 1. Cr(III) surface structure derived by extended X-ray absorption fine structure spectroscopy
32. Arsenate and chromate retention mechanisms on goethite: 1. Surface structure
33. The nature of Zn precipitates formed in the presence of pyrophyllite
34. The link between clay mineral weathering and the stabilization of Ni surface precipitates
35. Adsorption studies on clay minerals: II. A formation of the thermodynamics of exchange adsorption
36. Macromolecular structure of humic substances
37. Use of surface complexation models in soil chemical systems
38. A chemical model of phosphate adsorption by soils: I. Reference oxide minerals
39. A chemical model of phosphate adsorption by soils: II. Noncalcareous soils
40. Arsenate and chromate retention mechanisms on goethite: 2. Kinetic evaluation using a pressure-jump relaxation technique
41. Application and misapplications of the Langmuir equation to soil adsorption phenomena
42. Langmuir equation and alternate methods of studying "adsorption" reactions in soils
43. In situ X-ray absorption study of surface complexes: Selenium oxyanions on a-FeOOH
44. Ion exchange kinetics: III. Experimental test of the theory of particle-diffusion controlled ion exchange
45. NMR in soil science
46. Proton adsorption mechanism at the gibbsite and aluminum oxide solid/solution interface
47. 3
48. Kinetics of redox reactions on manganese oxides and its impact on environmental quality
49. In situ Fourier transform infrared measurements of sulfate adsorption on hematite in aqueous solutions
50. In situ measurements of tetraphenylboron degradation kinetics on clay mineral surfaces by FTIR
51. Redox phenomena
52. Reflections on the soil acidity merry-go-round
53. Sorption of hydrophobic pollutants on natural sediments
54. Surface complexation modeling: I. Strategy for modeling monomer complex formation at moderate surface coverage
55. Surface complexation modeling: II. Strategy for modeling polymer and precipitation reactions at high surface coverage
56. Cation exchange in soils
57. The mechanism of selenate adsorption on goethite and hydrous ferric oxide
58. Quantitative Zn speciation in smelter-contaminated soils by EXAFS spectroscopy
59. The sorption of cobalt by manganese minerals in soils
60. Kinetics of potassium release from biotite
61. Release of fixed potassium as a diffusion-controlled process
62. Imaging of humic substance macromolecular structures in water
63. Contaminants and the soil environment
64. Biogeochemistry of isotopes in soil environments: Theory and application
65. X-ray absorption spectroscopy of cobalt (II) multinuclear surface complexes and surface precipitates on kaolinite
66. Molecular structure and binding sites of cobalt(II) surface complexes on kaolinite from X-ray absorption spectroscopy
67. The oxidation of arsenite by aquatic sediments
68. Kinetics of oxidation of arsenite by various manganese dioxides
69. An in-situ ATR-FTIR investigation of sulfate bonding mechanisms on goethite
70. The measurement and interpretation of sorption and desorption rates for organic compounds in soil media
71. Sorptive reversibility of atrazine and metolachlor residues in field soil samples
72. The chemistry of submerged soils
73. Diagnosis and improvement of saline and sodic soils
74. Kinetics of mixed Ni-Al precipitate formation on a soil clay fraction
75. Zinc speciation in smelter-contaminated soils in the vicinity of the historic Palmerton smelter: A multi-analytical approach
76. Stability of layered Ni hydroxide surface precipitates - A dissolution kinetics study
77. Dissolution kinetics of Ni surface precipitates on clay mineral and oxide surfaces
78. Kinetics of the formation and the dissolution of nickel surface precipitates on pyrophyllite
79. Spectroscopic evidence for the formation of mixed-cation, hydroxide phases upon metal sorption on clays and aluminum oxides
80. The kinetics of mixed Ni-Al hydroxide formation on clay and aluminum oxide minerals: A time-resolved XAFS study
81. The role of Al in the formation of secondary Ni precipitates on pyrophyllite, gibbsite, talc, and amorphous silica: A DRS Study
82. 2 suspensions
83. 2+
84. A lifetime perspective on the chemistry of soil organic matter
85. Analysis of organic matter in soil extracts and whole soils by pyrolysis-mass spectrometry
86. A few aspects of 50 years of soil chemistry
87. A state of the art structural concept for humic substances
88. Synchrotron X-ray techniques in soil, plant, and environmental research
89. Impact of physico-chemistry on the study, design, and optimization of processes in natural porous media
90. Chemical extraction of potassium from soils and micaceous minerals with solution containing sodium tetraphenylboron: II. Biotite
91. Susceptibility of interlayer potassium in micas to exchange with sodium
92. Visible changes in macro mica particles that occur with potassium depletion
93. Desorption and bioavailability of aged simazine residues in soil from a continuous corn field
94. Mechanisms of ion transport in soils
95. Environmental soil chemistry
96. Kinetics of soil chemical phenomena: Future directions
97. Kinetics and mechanisms of soil chemical reactions
98. Rates of soil chemical processes
99. Relaxation methods for studying kinetics of soil chemical phenomena
100. Kinetic methods and measurements
101. Cation exchange in soils: A historical and theoretical perspective
102. Distinguishing adsorption from surface precipitation
103. Ion exchange phenomena
104. Ideal behavior in Na-trace metal cation exchange on Camp Berteau montmorillonite
105. Persistence of 1,2 dibromoethane in soils: Entrapment in intra particle micropores
106. The use of XAFS to distinguish between inner- and outer-sphere lead adsorption complexes on montmorillonite
107. Effects of soil organic matter on the kinetics and mechanisms of Pb(II) sorption and desorption in soil
108. Kinetics and mechanisms of Pb(II) sorption and desorption at the aluminum oxide-water interface
109. Interaction of metal ions with htdrous oxide surfaces
110. A ligand exchange model for the adsorption of inorganic and organic ligands at hydrous oxide interfaces
111. Historical developments in soil chemistry: Ion exchange
112. Ambient-temperature synthesis, evolution, and characterization of cobalt-aluminum hydrotalcite-like solids
113. Microorganisms, organic contaminants, and plant-metal interactions
114. 3
115. Equilibria of the base exchange reactions of bentonites, permutites, soil colloids, and zeolites
116. On the use of the Langmuir equation in the interpretation of "adsorption" phenomena
117. A comparison of electrostatic models for the oxide/solution interface