Ambient-temperature synthesis, evolution, and characterization of cobalt-aluminum hydrotalcite-like solids

Clays and Clay Minerals

Volumn 47, Issue 4, 1999, Pages 425-438

  Thompson, Hillary A ^a,c   Parks, George A ^a   Brown Jr , Gordon E ^a,b  

^a STANFORD UNIVERSITY   (United States)

^b SLAC NATIONAL ACCELERATOR LABORATORY   (United States)

^c LOS ALAMOS NATIONAL LABORATORY   (United States)

Author keywords

Anionic clay; Cation ordering; Coprecipitation; EXAFS; Hydrotalcite; ICP MS; Interstratification; Metal contamination; Solid solution; Solubility product; TEM

Indexed keywords

COBALT COMPOUNDS; DISSOLUTION; MOLECULAR STRUCTURE; PH EFFECTS; PRECIPITATION (CHEMICAL); SOLID SOLUTIONS; SOLUBILITY; STOICHIOMETRY; SYNTHESIS (CHEMICAL);

HYDROTALCITE; INTERSTRATIFICATION;

CLAY MINERALS;

ANION; CATION; CLAY MINERAL; HYDROXIDE; METAL; PRECIPITATION (CHEMISTRY);

EID: 0032743461     PISSN: 00098604     EISSN: None     Source Type: Journal    
DOI: 10.1346/CCMN.1999.0470405     Document Type: Article

References (50)

1. Allmann, R. (1968) The crystal structure of pyroaurite. Acta Crystallographica, B24, 972-977.
2. K+. Chimia, 24, 99-108.
3. Allmann, R. and Jepsen, H.P. (1969) Die Struktur des hydrotalkits. Neues Jahrbuch für Mineralogie Monatshefte, 544-551.
4. Baes, C.F., Jr. and Mesmer, R.E. (1986) The Hydrolysis of Cations. John Wiley & Sons, New York, 489 pp.
5. 2+, and anion type on the aging of iron(III) hydroxide precipitates. Environmental Science & Technology, 31, 1024-1032.
6. Bennett, D.G., Read, D., Atkins, M., and Glasser, F.P. (1992) A thermodynamic model for blended cements. II. Cement hydrate phases: Thermodynamic values and modelling studies. Journal of Nuclear Materials, 190, 315-325.
7. Bish, D.L. (1980) Anion-exchange in takovite: Applications to other hydroxide minerals. Bulletin de Mineralogie, 103, 170-175.
8. Boclair, J.W. and Braterman, P.S. (1999) Layered double hydroxide stability. Part I: Relative stabilities of layered double hydroxides and their simple counterparts. Chemistry of Materials, 11, 298-302.
9. Boclair, J.W., Braterman, P.S., Jiang, J., Lou, S., and Yarberry, F. (1999) Layered double hydroxide stability. Part II: Formation of Cr(III)-containing layered double hydroxides directly from solution. Chemistry of Materials, 11, 303-307.
10. Brindley, G.W. and Kikkawa, S. (1979) A crystal-chemical study of Mg.Al and Ni,Al hydroxy-perchlorates and hydroxy-carbonates. American Mineralogist, 64, 836-843.
11. Bruno, J., Duro, L., de Pablo, J., Casas, I., Ayora, C., Delgado, J., Gimeno, M.J., Pena, J., Linklater, C., Ferez del Villar, L., and Gomez, P. (1998) Estimation of the concentrations of trace metals in natural systems. The application of codissolution and coprecipitation approaches to El Berrocal (Spain) and Pocos de Caldas (Brazil). Chemical Geology, 151, 277-291.
12. Busca, G., Lorenzelli, V., and Bolis, V. (1992) Preparation, bulk characterization and surface chemistry of high-surface-area cobalt aluminate. Materials Chemistry and Physics, 31, 221-228.
13. Cavani, F., Trifiro, F., and Vaccari, A. (1991) Hydrotalcitetype anionic clays: Preparation, properties and applications. Catalysis Today, 11, 173-301.
14. Crovisier, J.L., Fritz, B., Grambow, B., and Eberhart, J.P. (1986) Dissolution of basaltic glass in seawater: Experiments and thermodynamic modelling. In Scientific Basis for Nuclear Waste Management, Volume 50, L.O. Werme, ed., Materials Research Society, Pittsburgh, 273-280.
15. d'Espinose de la Caillerie, J.-B., Kermarec, M., and Clause, O. (1995) Impregnation of γ-alumina with Ni(II) or Co(II) ions at neutral pH: Hydrotalcite-type coprecipitate formation and characterization. Journal of the American Chemical Society, 117, 11471-11481.
16. Parley, K.J., Dzombak, D.A., and Morel, F.M.M. (1985) A surface precipitation model for the sorption of cations on metal oxides. Journal of Colloid and Interface Science, 106, 226-242.
17. Feitknecht, W. (1942) Uber die bildung von doppelhydroxyden zwischen zwei-und dreiwertigen metallen. Helvetica Chimica Acta, 25, 555-569.
18. George, G.N. and Pickering, I.J. (1995) EXAFSPAK: A suite of computer programs for analysis of x-ray absorption spectra. Stanford Synchrotron Radiation Laboratory. Stanford, 63 pp.
19. Guerlou-Demourgues, L., Denage, C., and Delmas, C. (1994) New manganese-substituted nickel hydroxides. Part 1. Crystal chemistry and physical characterization. Journal of Power Sources, 52, 269-274.
20. 3 surface. 2. Kinetic study by means of pressure-jump technique. Journal of Physical Chemistry, 88, 27-31.
21. Hansen, H.C.B., Kock, C.B., and Taylor, R.M. (1994) Synthesis and characterization of cobalt(II)-iron(III) hydroxide carbonate, a layered double hydroxide belonging to the pyroaurite group. Journal of Solid State Chemistry, 113, 46-53.
22. Hemingway, B.S. and Sposito, G. (1996) Inorganic aluminum-bearing solid phases. In The Environmental Chemistry of Aluminum, G. Sposito, ed., CRC Lewis, Boca Raton, 81-116.
23. Lotmar, W. and Feitknecht, W. (1936) Uber anderungen der ionenabstande in hydroxyd-schichtengittern. Zeitschrift für Kristallographie, A93, 368-378.
24. Miyata, S. (1983) Anion-exchange properties of hydrotalcitelike compounds. Clays and Clay Minerals, 31, 305-311.
25. Myneni, S.C.B., Tokunaga, T.K., and Brown, G.E., Jr. (1997) Abiotic selenium redox transformations in the presence of Fe(II,III) oxides. Science, 278, 1106-1109.
26. Naumov, G.B., Ryzhenko, B.N., and Khodakovsky, I.L. (1974) Handbook of Thermodynamic Data. USGS, USGS-WRD-74-001, Menlo Park, 328 pp.
27. Navrotsky, A. (1994) Physics and Chemistry of Earth Materials. Cambridge University Press, Cambridge, 417 pp.
28. Nordstrom, D.K. and May, H.M. (1996) Aqueous equilibrium data for mononuclear aluminum species. In The Environmental Chemistry of Aluminum, G. Sposito, ed., CRC Lewis, Boca Raton, 39-80.
29. Nordstrom, D.K. and Munoz, J.L. (1994) Geochemical Thermodynamics. Blackwell, Boston, 493 pp.
30. Papelis, C., Hayes, K.F., and Leckie, J.O. (1988) HYDRAQL: A program for the computation of chemical equilibrium composition of aqueous batch systems including surface-complexation modeling of ion adsorption at the oxide/solution interface. Stanford University, Technical Report #306, Stanford, 130 pp.
31. Refait, P. and Genin, J.-M.R. (1997) Mechanisms of oxidation of Ni(II)-Fe(II) hydroxides in chloride-containing aqueous media: Role of the pyroaurite-type Ni-Fe hydroxychlorides. Clay Minerals, 32, 597-613.
32. Rehr, J.J., Mustre de Leon, J., Zabinsky, S.I., and Albers, R.C. (1991) Theoretical x-ray absorption fine structure standards. Journal of the American Chemical Society, 113, 5135-5140.
33. Reichle, W.T. (1985) Catalytic reactions by thermally activated, synthetic, anionic-clay minerals. Journal of Catalysis, 94, 547-557.
34. 4. Acta Crystallographica, 19, 381-389.
35. Scheidegger, A.M., Fendorf, M., and Sparks, D.L. (1996) Mechanisms of nickel sorption on pyrophyllite: Macroscopic and microscopic approaches. Soil Science Society of America Journal, 60, 1763-1772.
36. Scheidegger, A.M., Lamble, G.M., and Sparks, D.L. (1997) Spectroscopic evidence for the formation of mixed-cation hydroxide phases upon metal sorption on clays and aluminum oxides. Journal of Colloid and Interface Science, 186, 118-128.
37. Scheidegger, A.M., Strawn, D.O., Lamble, G.M., and Sparks, D.L. (1998) The kinetics of mixed Ni-Al hydroxide formation on clay and aluminum oxide minerals: A time-resolved XAFS study. Geochimica et Cosmochimica Acta, 62, 2233-2245.
38. Schindler, P.W., Liechti, P., and Westall, J.C. (1987) Adsorption of copper, cadmium, and lead from aqueous solution to the kaolinite/water interface. Netherlands Journal of Agricultural Science, 35, 219-230.
39. Schutz, A. and Biloen, P. (1987) Interlamellar chemistry of hydrotalcites. Journal of Solid State Chemistry, 68, 360-368.
40. Shannon, R.D. and Prewitt, C.T. (1969) Effective ionic radii in oxides and fluorides. Acta Crystallographica, B25, 925-946.
41. Smith, R.M. and Martell, A.E. (1997) NIST Critical Stability Constants of Metal Complexes Database. NIST, Gaithersburg, Maryland.
42. Subramanian, V. (1973) Mechanisms of fixation of the trace metals manganese and nickel by ferric hydroxide. Ph.D. thesis, Northwestern University, Evanston, Illinois, 89 pp.
43. Taylor, R.M. (1984) The rapid formation of crystalline double hydroxy salts and other compounds by controlled hydrolysis. Clay Minerals, 19, 591-603.
44. Thompson, H.A. (1998) Dynamic ion partitioning among dissolved, adsorbed, and precipitated phases in aging cobalt(II)/kaolinite/water systems. Ph.D. thesis, Stanford University, Stanford, California, 117 pp.
45. Thompson, H.A., Brown, G.E., Jr., and Parks, G.A. (1997) XAFS spectroscopic study of uranyl coordination in solids and aqueous solution. American Mineralogist, 82, 483-496.
46. Thompson, H.A., Parks, G.A., and Brown, G.E., Jr. (1999) Dynamic interactions of dissolution, surface adsorption, and precipitation in an aging cobalt(II)-clay-water system. Geochimica et Cosmochimica Acta, in press.
47. 3. Journal of Colloid and Interface Science, 187, 62-82.
48. Vucelic, M., Jones, W., and Moggridge, G.D. (1997) Cation ordering in synthetic layered double hydroxides. Clays and Clay Minerals, 45, 803-813.
49. Yun, S.K. and Pinnavaia, T.J. (1995) Water content and particle texture of synthetic hydrotalcite-like layered double hydroxides. Chemistry of Materials, 7, 348-354.
50. Zachara, J.M., Cowan, C.E., and Resch, C.T. (1991) Sorption of divalent metals on calcite. Geochimica et Cosmochimica Acta, 55, 1549-1562.