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[1b] A. J. Buglass, J. G. Tillett, in The Chemistry of Sulfonic Acids, Esters and their Derivatives (Eds.: S. Patai, Z. Rappoport), Wiley, New York, 1991, pp. 789-878.
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For reviews on a related sequence involving intramolecular Diets-Alder reaction of silicon-tethered trienes and subsequent desilylation, see: [2a] D. R. Gauthier, Jr., K. S. Zandi, K. J. Shea, Tetrahedron 1998, 54, 2289-2338.
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[3a] P. Metz, M. Fleischer, R. Fröhlich, Tetrahedron 1995, 51, 711-732.
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9
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0002018106
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A related intermediate featuring a carbanionic center in the endocyclic β-position to the sulfur atom is probably formed in the final step of our sultone route to nonactic acid, see: [4a] U. Meiners, E. Cramer, R. Fröhlich, B. Wibbeling, P. Metz, Eur. J. Org. Chem. 1998, 2073-2078.
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[4b] P. Metz, U. Meiners, E. Cramer, R. Fröhlich, B. Wibbeling, Chem. Commun. 1996, 431-432.
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P. Metz, D. Seng, B. Plietker, Tetrahedron Lett. 1996, 37, 3841-3844.
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13
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0003206168
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note
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-3, hydrogen atoms calculated and refined riding, two independent molecules in the asymmetric unit being enantiomers. Crystallographic data (excluding structure factors) for the structure reported in this paper have been deposited with the Cambridge Crystallographic Data Centre as supplementary publication no. CCDC-161616. Copies of the data can be obtained free of charge on application to CCDC, 12 Union Road, Cambridge CB2 1EZ, UK [Fax: (internat.) + 44-1223/336-033; E-mail: deposit@ccdc.cam.ac.uk].
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P. Metz, J. Stölting, M. Läge, B. Krebs, Angew. Chem. 1994, 106, 2275-2276;
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