Time-resolved thermodynamic profile upon photoexcitation of a nitrospiropyran in cycloalkanes and of the corresponding merocyanine in aqueous solutions

Helvetica Chimica Acta

Volumn 84, Issue 9, 2001, Pages 2557-2576

  Williams, René M ^a,b   Klihm, Gudrun ^a   Braslavsky, Silvia E ^a  

^a MAX PLANCK INSTITUTE FOR CHEMICAL ENERGY CONVERSION   (Germany)

^b UNIVERSITY OF AMSTERDAM   (Netherlands)

Author keywords

[No Author keywords available]

Indexed keywords

ELECTROSTRICTION; ENTHALPY; NEGATIVE IONS; OXYGEN; PHOTOACOUSTIC SPECTROSCOPY; PROTONS; THERMODYNAMICS;

PHOTOEXCITATION;

PARAFFINS;

CYCLOALKANE; CYCLOHEXANE; CYCLOPENTANE; DECALIN; MEROCYANINE; NITROSPIROPYRAN; PYRAN DERIVATIVE; UNCLASSIFIED DRUG;

ARTICLE; ENERGY; ENTHALPY; ENTROPY; INFRARED RADIATION; PHOTOCHEMISTRY; PROTON TRANSPORT; REACTION ANALYSIS; STEADY STATE; THERMODYNAMICS;

EID: 0034753567     PISSN: 0018019X     EISSN: None     Source Type: Journal    
DOI: 10.1002/1522-2675(20010919)84:9<2557::AID-HLCA2557>3.0.CO;2-U     Document Type: Article

References (58)

1. a) T. Asano, W. J. le Noble, Chem. Rev. 1978, 78, 407;
2. b) R. van Eldik, T. Asano, W. J. le Noble, Chem. Rev. 1989, 89, 549;
3. c) A. Drijaca, D. C Hubbard, R. van Eldik, T. Asano, M. V. Basilevsky, W. J. le Noble, Chem. Rev. 1998, 95, 2167.
4. K. Uchino, Mater. Res. Innovations 1997, 1, 163.
5. a) P.J. Schulenberg, S.E. Braslavsky, in 'Progress in Photothermal and Photoacoustic Science and Technology, Vol. 3: Life and Earth Sciences', Eds. A. Mandelis, P. Hess, SPIE Press: Bellingham, WA. 1997, p. 57-81;
6. b) A. Losi, A. A. Wegener, M. Engelhard, S. E. Braslavsky, J. Am. Chem. Soc. 2001, 123, 1766 and refs. cit. therein.
7. S. E. Braslavsky, G. E. Heibel, Chem. Rev. 1992, 92, 1381.
8. C. D. Borsarelli, S. E. Braslavsky, J. Phys. Chem. B 1998, 102, 6231.
9. a) J.-L. Habib Jiwan, B. Wegewijs, M. T. Indelli, F. Scandola, S. E. Braslavsky, Recl. Trav. Chim. Pays-Bas 1995, 114, 542;
10. b) C. D. Borsarelli, S. E. Braslavsky, J. Phys. Chem. B 1997, 101, 6036.
11. C. D. Borsarelli, S. E. Braslavsky, J. Phys. Chem. A 1999, 103, 1719.
12. M. A. Rodríguez, S. E. Braslavsky, J. Phys. Chem. A 1999, 103, 6295.
13. B. Wegewijs, J. W. Verhoeven, S. E. Braslavsky, J. Phys. Chem. 1996, 100, 8890.
14. B. Wegewijs, M. N. Paddon-Row, S. E. Braslavsky, J. Phys. Chem. A 1998, 102, 8812.
15. R. M. Williams, A. F. McDonagh, S. E. Braslavsky, Photochem. Photobiol. 1998, 68, 433.
16. a) R. C. Bertelson, in 'Photochromism', Ed. G. H. Brown, Wiley, New York, 1971, Chapt. 3;
17. b) R. Guglielmetti, in 'Photochromism: Molecules and Systems', Eds. H. Dürr, H. Bouas-Laurent, Elsevier, Amsterdam, 1990, p. 314-466;
18. c) R. C. Bertelson, in 'Organic Photochromic and Thermochromic Compounds', Vol. 1, Eds. J. C. Crano, R. Guglielmetti, Kluwer Academic Publishers, New York, 1999, Vol. 1, p. 11-83;
19. d) J. Saltiel, Y.-P. Sun, in 'Photochromism: Molecules and Systems', Eds. H. Dürr, H. Bouas-Laurent, Elsevier, Amsterdam, 1990, p. 645.
20. H. Görner, Chem. Phys. 1997, 222, 315.
21. a) A. K. Chibisov, H. Görner, J. Phys. Chem. A 1997, 101, 4305;
22. b) A. K. Chibisov, H. Görner, J. Photochem. Photobiol. A: Chemistry 1997, 105, 261.
23. H. Görner, Chem. Phys. Lett. 1998, 252, 381.
24. P. Allegrini, V. Malatesta, Mol. Chryst. Liq. Cryst. 1994, 246, 25.
25. C. J. Drummond, D. N. Furlong, J. Chem. Soc., Faraday Trans. 1990, 86, 3613.
26. C. A. Heller, D. A. Fine, R. A. Henry, J. Am. Chem. Soc. 1961, 65, 1908.
27. I. Shimizu, H. Kokado, E. Inoue, Bull. Chem. Soc. Jpn. 1969, 42, 1726.
28. R. P. Herbrich, R. Schmidt, J. Photochem. Photobiol. A: Chemistry 2000, 133, 149.
29. D. F. Eaton, Pure Appl. Chem. 1988, 60, 1107.
30. T. Gensch, M. S. Churio, S. E. Braslavsky, K. Schaffner, Photochem. Photobiol. 1996, 63, 719.
31. M. van Brederode, T. Gensch, W. Hoff, K. J. Hellingwerf, S. E. Braslavsky, Biophys. J. 1995, 68, 1101.
32. J. Rudzki-Small, L. J. Libertini, E. W. Small, Biophys. Chem. 1992, 41, 29.
33. J. A. Riddick, W. B. Bunger, T. K. Sakano, 'Organic Solvents', Wiley, New York, 1986.
34. R. R. Hung, J. J. Grabowski, J. Am. Chem. Soc. 1992, 114, 351.
35. F. R. Gilmore, J. Quant. Spectr. Radiative Transfer 1965, 5, 369.
36. a) K. I. Salokhiddinov, I. M. Byteva, G. P. Gurinovich, J. Appl. Spectr. 1981, 34, 561;
37. b) F. Wilkinson, W. P. Helman, A. B. Ross, J. Phys. Chem. Ref. Data 1995, 24, 663.
38. a) P. Pollmann, D. Rehm, A. Weller, Ber. Bunsen-Ges. Phys. Chem. 1975, 79, 692;
39. b) S. D. Hamann, Rev. Phys. Chem. Jpn. 1980, 50, 147.
40. M. Levitus, G. Glasser, D. Neher, P. F. Aramendia, Chem. Phys. Lett. 1997, 277, 118.
41. C. D. Borsarelli, S. E. Braslavsky, J. Photochem. Photobiol. B: Biol. 1998, 43, 222, and refs. therein.
42. H. Høiland, J. Chem. Soc., Faraday 1, 1975, 797.
43. a) R. C. Muñoz, R. A. Holroyd, K. Itoh, K. Nakagawa, M. Nishikawa, K. Fueki, J. Phys. Chem. 1987, 91, 4639;
44. b) H. A. Schwarz, J. Phys. Chem. 1993, 97, 12954.
45. Y. Marcus, G. T. Hefter, J. Mol. Liq. 1997, 73/74, 61.
46. a) Y. Sueishi, M. Ohcho, N. Nishimura, Bull. Chem. Soc. Jpn. 1985, 58, 2608;
47. b) Y. Sueishi, M. Ohcho, S. Yamamoto, N. Nishimura, Bull. Chem. Soc. Jpn. 1986, 59, 3666;
48. c) N. Nishimura, J. Miyake, Y. Sueishi, Bull. Chem. Soc. Jpn. 1989, 62, 1777.
49. J. B. Flannery Jr., J. Am. Chem. Soc. 1968, 90, 5660.
50. Y. Hirschberg, E. Fischer, J. Chem. Soc. 1954, 3129.
51. a) T. Okazaki, N. Hirota, M. Terazima, J. Photochem. Photobiol. A 1996, 99, 155;
52. b) Y. Li, J. Zhou, Y. Wang, F. Zhang, X. Song, J. Photochem. Photobiol. A 1998, 113, 65;
53. c) V. A. Krongauz, E. S. Goldburt, Nature 1978, 271, 43.
54. a) M. B. Zimmt, P. A. Vath, Photochem. Photobiol. 1997, 65, 10;
55. b) J. Morais, M. B. Zimmt, J. Phys. Chem. 1995, 99, 8863.
56. G. Martínez, S. G. Bertolotti, O. E. Zimerman, D. O. Mártire, S. E. Braslavsky, N. A. García, J. Photochem. Photobiol. B 1993, 17, 247.
57. C. Martí, O. Jürgens, O. Cuenca, M. Casals, S. Nonell, J. Photochem. Photobiol. A 1996, 97, 11.
58. T. Gensch, C. Viappiani, S. E. Braslavsky, J. Am. Chem. Soc. 1999, 121, 10573.